Abstract: A method including contacting a ligand complex, a metalation compound, and a metal carbonyl in a mixture to form a catalyst. The ligand complex includes one or more of phosphine, imine, and/or hydroxyl groups bound to one or more cyclic structures. The method includes separating the catalyst from the mixture. Contacting the ligand complex with a metalation compound and the metal carbonyl in the mixture to form a catalyst is conducted without isolating any intermediates, performed within a single vessel, and/or performed in a moisture, oxygen, and/or air free environment.

Abstract: A composition, comprising: a metal carbonyl anion; and a cation ionically bonded to the metal carbonyl anion. The cation includes a ligand and a metal centered compound. The ligand includes two residues of 3,5-substituted salicylaldehydes connected by an hydrocarbyl-diimine bridge that includes a nitrogen atom contacted with a carbon of an aldehyde residue at each of the two residues of the 3,5-substituted salicylaldehydes. Each of the residues of the 3,5-substituted salicylaldehydes are independently substituted at one or both of a 3 position and a 5 position by a hydrocarbyl group containing at least 5 carbons. The metal coordinated with the ligand at each hydroxyl residue the two residues of the 3,5-substituted salicylaldehydes at a 2 position and at each of the nitrogen atoms of the hydrocarbyl-diimine bridge. The composition includes two polar ligands coordinated with the metal.

Abstract: The lifetime and durability of artificial baits is improved by providing an integral hook holding portion. The hook holding means is a plastic or fibrous ring or a dense polymer region molded integrally with the bait.

Abstract: The invention is a soft bait composition that is loaded with a quantity of porous particles, such as calcium carbonate satu rated with aqueous based or oil based fish attractant, which is released over several hours while immersed in water. Furthermore, the porous particles can provide a wide range of sink rates in plastic fishing lures.

Abstract: A golf club having a club head with a striking plate having a thickness in the range of 0.010 to 0.250 inch is disclosed herein. The club head may be composed of three pieces, a face, a sole and a crown. Each of the pieces may be composed of a titanium material. The striking plate of the club head may have an aspect ratio less than 1.7. The striking plate may also have concentric regions of thickness with the thickness portion in the center. The club head may be composed of a titanium material, have a volume in the range of 175 cubic centimeters to 400 cubic centimeters, a weight in the range of 165 grams to 300 grams, and a striking plate surface area in the range of 4.00 square inches to 7.50 square inches. The golf club head may also have a coefficient of restitution greater than 0.8 under test conditions such as the USGA test conditions specified pursuant to Rule 4-1e, Appendix II, of the Rules of Golf for 1998-1999.

Abstract: A golf club having a club head with a striking plate having a thickness in the range of 0.010 to 0.250 inch is disclosed herein. The club head may be composed of three pieces, a face, a sole and a crown. Each of the pieces may be composed of a titanium material. The striking plate of the club head may have an aspect ratio less than 1.7. The striking plate may also have concentric regions of thickness with the thickness portion in the center. The club head may be composed of a titanium material, have a volume in the range of 175 cubic centimeters to 400 cubic centimeters, a weight in the range of 165 grams to 300 grams, and a striking plate surface area in the range of 4.00 square inches to 7.50 square inches. The golf club head may also have a coefficient of restitution greater than 0.8 under test conditions such as the USGA test conditions specified pursuant to Rule 4-1e, Appendix II, of the Rules of Golf for 1998-1999.