Patents by Inventor Ronald Joseph Pangrazi
Ronald Joseph Pangrazi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20160251801Abstract: A carpet product includes in sequence a) a primary backing material having a back side and a face side, with carpet fibers extending from the face side to form a carpet pile and also passing through the primary backing material and forming loops on the back side; b) a primary coating layer on the loops, including a vinyl acetate ethylene copolymer and present at from 542 to 1085 g/m2 (16 to 32 oz./yd2) on a dry solids basis; c) a secondary coating layer on the primary coating layer, including a styrene-butadiene copolymer; and d) a secondary backing material on the secondary coating layer and adhered thereby to the primary coating layer.Type: ApplicationFiled: October 22, 2014Publication date: September 1, 2016Applicant: WACKER CHEMICAL CORPORATIONInventors: DENNIS SAGL, RONALD JOSEPH PANGRAZI, JOHN M. MCCLURKEN
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Patent number: 9382341Abstract: An aqueous carpet coating composition includes a particulate filler, a polymeric thickener and an aqueous dispersion of a copolymer that includes vinyl acetate units and ethylene units. The dispersion stabilization system includes a) 1.5 to 3 wt % of a combination of polyvinyl alcohols including a1) one or more partially hydrolyzed polyvinyl alcohols with a degree of hydrolysis of 85 to 95 mol % and a Hoeppler viscosity of 10-33 mPa·s, and a2) one or more highly hydrolyzed polyvinyl alcohols with a degree of hydrolysis of 98 to 100 mol % and a Hoeppler viscosity of 10-33 mPa·s; and b) 1.5 to 3 wt % of an emulsifier component consisting of one or more nonionic emulsifiers and one or more anionic emulsifiers. The dispersion has a viscosity of ?1500 mPa·s and the viscosity of the coating composition is 6000 to 7000 mPa·s.Type: GrantFiled: September 27, 2012Date of Patent: July 5, 2016Assignee: WACKER CHEMICAL CORPORATIONInventors: Dennis Sagl, John McClurken, Ronald Joseph Pangrazi
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Publication number: 20140087120Abstract: An aqueous carpet coating composition includes a particulate filler, a polymeric thickener and an aqueous dispersion of a copolymer that includes vinyl acetate units and ethylene units. The dispersion stabilization system includes a) 1.5 to 3 wt % of a combination of polyvinyl alcohols including a1) one or more partially hydrolyzed polyvinyl alcohols with a degree of hydrolysis of 85 to 95 mol % and a Hoeppler viscosity of 10-33 mPa·s, and a2) one or more highly hydrolyzed polyvinyl alcohols with a degree of hydrolysis of 98 to 100 mol % and a Hoeppler viscosity of 10-33 mPa·s; and b) 1.5 to 3 wt % of an emulsifier component consisting of one or more nonionic emulsifiers and one or more anionic emulsifiers. The dispersion has a viscosity of ?1500 mPa·s and the viscosity of the coating composition is 6000 to 7000 mPa·s.Type: ApplicationFiled: September 27, 2012Publication date: March 27, 2014Applicant: Wacker Chemical CorporationInventors: Dennis Sagl, John McClurken, Ronald Joseph Pangrazi
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Patent number: 8273414Abstract: A method of improving the wet tensile strength of a cellulose-containing web includes applying to the web an aqueous binder emulsion and subsequently drying and curing the binder emulsion. The aqueous binder emulsion is prepared by emulsion-polymerizing a monomer mixture comprising vinyl acetate, ethylene, and an olefinically unsaturated crosslinking monomer in the presence of a phosphate ester surfactant wherein the at least one crosslinking monomer comprises a (meth)acrylamide moiety and a cellulose-reactive moiety. The binder emulsion may be applied to a cellulose-containing web to increase wet strength, aid in creping, or both.Type: GrantFiled: March 5, 2010Date of Patent: September 25, 2012Assignee: Wacker Chemical CorporationInventors: Christian Leonard Daniels, Ronald Joseph Pangrazi, Richard Henry Bott
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Patent number: 8012285Abstract: This invention is directed to alkylphenol ethoxylate (APE)-free polymer binders formed by aqueous free radical emulsion polymerization and having specific peel and cure properties. The APE-free polymeric binders have a peel value, when adhered to a heated metal surface, of 35% to 200% of the peel value shown by a standard APE-based polymer binder control and exhibit a cure profile such that at least 55% cure is achieved within 30 seconds at a temperature required for cure, and a wet tensile strength at 30-seconds of cure of at least 1000 g/5 cm. Wet tensile strength is used as a measure of cure. Binders having the peel and cure properties described herein can be considered for use in crepe processes, especially DRC processes.Type: GrantFiled: May 7, 2010Date of Patent: September 6, 2011Assignee: Wacker Chemical CorporationInventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20100227072Abstract: A method of improving the wet tensile strength of a cellulose-containing web includes applying to the web an aqueous binder emulsion and subsequently drying and curing the binder emulsion. The aqueous binder emulsion is prepared by emulsion-polymerizing a monomer mixture comprising vinyl acetate, ethylene, and an olefinically unsaturated crosslinking monomer in the presence of a phosphate ester surfactant wherein the at least one crosslinking monomer comprises a (meth)acrylamide moiety and a cellulose-reactive moiety. The binder emulsion may be applied to a cellulose-containing web to increase wet strength, aid in creping, or both.Type: ApplicationFiled: March 5, 2010Publication date: September 9, 2010Applicant: Wacker Chemical CorporationInventors: Christian Leonard Daniels, Ronald Joseph Pangrazi, Richard Henry Bott
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Publication number: 20100215904Abstract: This invention is directed to alkylphenol ethoxylate (APE)-free polymer binders formed by aqueous free radical emulsion polymerization and having specific peel and cure properties. The APE-free polymeric binders have a peel value, when adhered to a heated metal surface, of 35% to 200% of the peel value shown by a standard APE-based polymer binder control and exhibit a cure profile such that at least 55% cure is achieved within 30 seconds at a temperature required for cure, and a wet tensile strength at 30-seconds of cure of at least 1000 g/5 cm. Wet tensile strength is used as a measure of cure. Binders having the peel and cure properties described herein can be considered for use in crepe processes, especially DRC processes.Type: ApplicationFiled: May 7, 2010Publication date: August 26, 2010Applicant: Wacker Chemical CorporationInventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Patent number: 7297644Abstract: This invention is directed to an improved nonwoven product comprising a nonwoven web of fibers bonded together with a sufficient amount of binder comprised of a polymer comprised of vinyl acetate, ethylene, and a crosslinking monomer to form a self-sustaining web. The improvement in the nonwoven product resides in the use of a polymer having a crystalline melting point (Tm) ranging from 35 to 90° C., preferably 50 to 80° C.; measured at a heat rate of 20° C./minute. The polymer should have a crystalline heat of fusion (Hf), which typically range from about 2 to about 50 joules per gram and a low glass transition temperature (Tg), e.g., from 10 to ?40° C., typically ?15 to ?35° C.Type: GrantFiled: May 28, 2003Date of Patent: November 20, 2007Assignee: Air Products Polymers, L.P.Inventors: John Joseph Rabasco, Ronald Joseph Pangrazi, Richard Henry Bott
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Patent number: 7064091Abstract: This invention is directed to an aqueous polymeric binder composition that is useful in improving the wet strength of pre-moistened wipes. The binder composition comprises a blend or mixture of two components. One component is a water dispersible polymer capable of binding together the fibers composing a nonwoven web. The other component is an aqueous solution or dispersion of a polymer comprised predominantly of self-crosslinking monomer(s).Type: GrantFiled: January 29, 2003Date of Patent: June 20, 2006Assignee: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi, Nicola Ranieri, Christian Leonard Daniels
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Patent number: 6974520Abstract: This invention is directed to formation of a creped nonwoven web. The creped web is formed in a creping process using a polymer emulsion binder formed in an alkylphenol ethoxylate-free surfactant system. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.Type: GrantFiled: June 15, 2005Date of Patent: December 13, 2005Assignee: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Patent number: 6918305Abstract: The following method is used to measure the adhesion of a polymer binder to a heated metal surface: A metal plate is attached to a heated (350° F.; 177° C.) platform and allowed to equilibrate to the temperature of the platform. A polymer emulsion binder is applied to a substrate, such as cotton fabric, and an end of the coated substrate is attached to a tensile measuring apparatus. The coated side of the coated substrate is pressed onto the heated metal plate; e.g., using a 3-lb lab roller. After a length of time to cause drying and/or partial cure of the binder (approximately 30 seconds), the metal plate and the tensile measuring device are separated at a given uniform speed. The amount of force needed to remove the substrate from the metal plate is recorded.Type: GrantFiled: December 19, 2001Date of Patent: July 19, 2005Assignee: Air Products Polymers, L.P.Inventors: Ronald Joseph Pangrazi, Beth Rene′ Spivak, John Joseph Halat, Joel Erwin Goldstein
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Patent number: 6908524Abstract: This invention is directed to formation of a creped nonwoven web. The creped web is formed in a creping process using a polymer emulsion binder formed in an alkylphenol ethoxylate-free surfactant system. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.Type: GrantFiled: January 6, 2004Date of Patent: June 21, 2005Assignee: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20040242106Abstract: This invention is directed to an improved nonwoven product comprising a nonwoven web of fibers bonded together with a sufficient amount of binder comprised of a polymer comprised of vinyl acetate, ethylene, and a crosslinking monomer to form a self-sustaining web. The improvement in the nonwoven product resides in the use of a polymer having a crystalline melting point (Tm) ranging from 35 to 90° C., preferably 50 to 80° C.; measured at a heat rate of 20° C./minute. The polymer should have a crystalline heat of fusion (Hf), which typically range from about 2 to about 50 joules per gram and a low glass transition temperature (Tg), e.g., from 10 to −40° C., typically −15 to −35° C.Type: ApplicationFiled: May 28, 2003Publication date: December 2, 2004Inventors: John Joseph Rabasco, Ronald Joseph Pangrazi, Richard Henry Bott
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Patent number: 6824635Abstract: This invention is directed to APE-free polymer binders formed by emulsion polymerization and having specific peel and cure properties. The APE-free polymeric binders have a peel value, when adhered to a heated metal surface, of 35% to 200% of the peel value shown by a standard APE-based polymer binder control (i.e., AIRFLEX® 105 vinyl acetate-ethylene polymer emulsion) and exhibit a cure profile such that at least 55% cure is achieved within 30 seconds at a temperature required for cure. Wet tensile strength is used as a measure of cure. The peel value is determined by a modified release and adhesion test. Binders having the peel and cure properties described herein can be considered for use in crepe processes, especially DRC processes.Type: GrantFiled: December 19, 2001Date of Patent: November 30, 2004Assignee: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20040147190Abstract: This invention is directed to an aqueous polymeric binder composition that is useful in improving the wet strength of pre-moistened wipes. The binder composition comprises a blend or mixture of two components. One component is a water dispersible polymer capable of binding together the fibers composing a nonwoven web. The other component is an aqueous solution or dispersion of a polymer comprised predominantly of self-crosslinking monomer(s).Type: ApplicationFiled: January 29, 2003Publication date: July 29, 2004Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi, Nicola Ranieri, Christian Leonard Daniels
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Publication number: 20040143046Abstract: This invention is directed to formation of a creped nonwoven web. The creped web is formed in a creping process using a polymer emulsion binder formed in an alkylphenol ethoxylate-free surfactant system. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.Type: ApplicationFiled: January 6, 2004Publication date: July 22, 2004Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20030114561Abstract: This invention is directed an alkylphenol ethoxylate-free surfactant system for preparation of polymer emulsions. The surfactant system comprises a combination of a specific active anionic surfactant (sodium laureth sulfate containing 1 to 12 moles of ethylene oxide) and a specific active nonionic surfactant (a secondary alcohol ethoxylate containing 7 to 30 moles of ethylene oxide or an ethoxylated branched primary alcohol containing 3 to 30 moles of ethylene oxide.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Applicant: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20030114586Abstract: This invention is directed to APE-free polymer binders formed by emulsion polymerization and having specific peel and cure properties. The APE-free polymeric binders have a peel value, when adhered to a heated metal surface, of 35% to 200% of the peel value shown by a standard APE-based polymer binder control (i.e., AIRFLEX® 105 vinyl acetate-ethylene polymer emulsion) and exhibit a cure profile such that at least 55% cure is achieved within 30 seconds at a temperature required for cure. Wet tensile strength is used as a measure of cure. The peel value is determined by a modified release and adhesion test. Binders having the peel and cure properties described herein can be considered for use in crepe processes, especially DRC processes.Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi
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Publication number: 20030110866Abstract: The following method is used to measure the adhesion of a polymer binder to a heated metal surface:Type: ApplicationFiled: December 19, 2001Publication date: June 19, 2003Inventors: Ronald Joseph Pangrazi, Beth Rene Spivak, John Joseph Halat, Joel Erwin Goldstein
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Patent number: 6506696Abstract: A process for forming a synthetic based nonwoven web bonded with a crosslinkable polymer wherein an aqueous polymeric emulsion containing a crosslinkable polymer is applied to the synthetic based nonwoven web, the water removed, and the crosslinkable polymer crosslinked. The crosslinkable polymer incorporates acetoacetate functionality and carboxylic acid functionality; wherein crosslinking is achieved by the reaction of the acetoacetate with an effective amount of a polyaldehyde and the reaction of the carboxylic acid with an effective amount of a polyaziridine compound.Type: GrantFiled: March 26, 2001Date of Patent: January 14, 2003Assignee: Air Products Polymers, L.P.Inventors: Joel Erwin Goldstein, Ronald Joseph Pangrazi