Patents by Inventor Ronald W. Kenyon

Ronald W. Kenyon has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5616694
    Abstract: A compound of Formula (1) and salts thereof wherein the variables are as defined in the specification:Ar.sup.1 N.dbd.N-J-X-L-X-J-N.dbd.NAr.sup.2 (1)A compound of Formula (1) is suitable for use in the coloration of cellulosic substrates, such as paper, to give bright prints with good light and water fastness. It is especially suitable for use in the printing of paper by non-impact printing techniques, such as ink jet printing, especially thermal ink jet printing.
    Type: Grant
    Filed: July 12, 1995
    Date of Patent: April 1, 1997
    Assignee: Zeneca Limited
    Inventors: Ronald W. Kenyon, Prahalad M. Mistry
  • Patent number: 5473053
    Abstract: A compound of Formula (1) and salts thereof:Ar.sup.1 N.dbd.N--J--X--L--X--J--N.dbd.NAr.sup.2 (1)wherein: ##STR1## Ar.sup.1 and Ar.sup.2 are each independently aryl containing at least two carboxy groups; andL is a group of the Formula (3a) or (3b): ##STR2## in which T.sup.1 and T.sup.2 each independently is C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy or C.sub.3-4 -alkenyl;T.sup.3 and T.sup.4 each independently is H, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy or C.sub.3-4 -alkenyl provided that T.sup.3 and T.sup.4 are not both H;each X independently is a group of the Formula (4), (5) or (6): ##STR3## each Z independently is H, halogen, alkyl, NR.sup.1 R.sup.2, SR.sup.3 or 0R.sup.3 ;each Y independently is Z, SR.sup.4 or OR.sup.4 ;each E independently is Cl or CN; andR.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each as defined in the specification.A compound of Formula (1) is suitable for use in the coloration of cellulosic substrates, such as paper, to give bright prints with good light and water fastness.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: December 5, 1995
    Assignee: Zeneca Limited
    Inventors: Ronald W. Kenyon, Prahalad M. Mistry
  • Patent number: 5453495
    Abstract: A compound of Formula (1) and salts thereof: ##STR1## wherein: L is optionally substituted piperazinyl;D is optionally substituted phenylene or naphthylene;E is optionally substituted phenylene, naphthylene or quinoline;R is H or C.sub.1-4 -alkyl;Z is optionally substituted carboxyaryl; andn has a value of 0 or 1.A compound of Formula (1) is useful as a colorant for black inks suitable for ink jet printing.
    Type: Grant
    Filed: December 22, 1994
    Date of Patent: September 26, 1995
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald W. Kenyon, Prahalad M. Mistry
  • Patent number: 5383960
    Abstract: An ink containing less than 5% inorganic compounds which comprises a liquid medium and a dye of the Formula (1): ##STR1## wherein: D.sup.1 and D.sup.2 are each independently a chromophore of the azo series;R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each independently H or optionally substituted alkyl;B is a labile atom or group, hydroxy, amino or an ether, thioether or amine group; andX.sup.1 and X.sup.2 are each independently H, halo, alkyl, alkoxy, acylamino, ureido, nitro, carboxy or sulpho.The inks may be used in ink jet printing either alone or with specified xanthene dyes.
    Type: Grant
    Filed: January 26, 1993
    Date of Patent: January 24, 1995
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald W. Kenyon, Prahalad M. Mistry, John A. Taylor
  • Patent number: 5374301
    Abstract: An ink comprising a liquid medium and a compound of Formula (1) or salt thereof: ##STR1## provided (i) if the compound of Formula (1) has no --SO.sub.3 H groups then it has at least two groups selected from --COOH and --COSH; and (ii) the compound of Formula (1) has at least as many groups selected from --COOH and --COSH as --SO.sub.3 H groups. The inks are useful for ink-jet printing.
    Type: Grant
    Filed: November 30, 1992
    Date of Patent: December 20, 1994
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald W. Kenyon
  • Patent number: 5370730
    Abstract: Dye compositions and aqueous inks derived therefrom, especially suitable for use in ink jet printing in which the dye composition contains (a) one or more dyes which, in the free acid form, are of Formula (1): ##STR1## wherein W is H or COOH;X is H or COOH;Y is H or COOH;U & Z are each independently H, COOH or SO.sub.3 H; andV is H or SO.sub.3 H;and (b) one or both dyes which in the free acid form is of Formula (2): ##STR2## wherein A is NH.sub.2 and B is OH; orA is OH and B is NH.sub.2.
    Type: Grant
    Filed: April 12, 1993
    Date of Patent: December 6, 1994
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald W. Kenyon, John E. Presgrave
  • Patent number: 5296023
    Abstract: A colorant of Formula (1): ##STR1## wherein: L is a metal cation or hydrogen;Pc is a phthalocyanine radical having a valency from 3 to 4;R.sup.1 is H, alkyl, substituted alkyl, alkenyl, substituted alkenyl, aralkyl or substituted aralkyl;R.sup.2 is H, alkyl, alkoxy, halo or an optionally substituted amino group;M.sup.+ is NH.sub.4.sup.+ or a substituted annonium cation; and(t+q) is from 3 to 4 inclusive;with the proviso that the group CO.sub.2 -M.sup.+ is at the 2-, 3-, 5- or 6-position in Formula (1).
    Type: Grant
    Filed: January 4, 1993
    Date of Patent: March 22, 1994
    Assignee: Zeneca Limited
    Inventors: Peter Gregory, Ronald W. Kenyon
  • Patent number: 5279656
    Abstract: A compound of Formula (1): ##STR1## wherein: X.sup.1 is a sulpho or carboxy group;each X.sup.2 independently is a substituent;m has a value of from 0 to 2;Y.sup.1 and Y.sup.2 are each independently alkyl or halo; andZ is a carboxy group.The above compounds may be used as colorants for ink jet printing inks either alone or as a mixture with a second magenta compound.
    Type: Grant
    Filed: November 9, 1992
    Date of Patent: January 18, 1994
    Assignee: Imperial Chemical Industries PLC
    Inventors: Ronald W. Kenyon, Peter Gregory
  • Patent number: 5268459
    Abstract: Anionic azo compounds which, in the free acid form, have the Formula (1): ##STR1## wherein: Ar and Ar.sup.1 are each independently aryl or substituted aryl providing at least one of Ar and Ar.sup.1 has at least one substituent selected from COOH and COSH;J and J.sup.1 are each independently of formula (2), (3) or (4): ##STR2## each R.sup.5 is independently selected from H, alkyl, substituted alkyl, alkoxy, halogen, CN, ureido and NHCOR.sup.6 ;R.sup.6 is H, alkyl, substituted alkyl, aryl, substituted aryl, aralkyl or substituted aralkyl;each T is independently alkyl;each W is independently selected from H, CN, CONR.sup.10 R.sup.11, pyridinium and COOH;each m is an alkylene chain having 2 to 8 carbon atoms;B is H, alkyl or COOH;R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.10 and R.sup.11 are each independently H, alkyl or substituted alkyl;L is a divalent organic linking group;n is 0 or 1;each X is independently carbonyl or a group of the Formula (5), (6) or (7): ##STR3## Z is OR.sup.7, SR.sup.7 or NR.sup.8 R.sup.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: December 7, 1993
    Assignee: Imperial Chemical Industries plc
    Inventors: Peter Gregory, Ronald W. Kenyon
  • Patent number: 5262527
    Abstract: Anionic azo compounds which, in the free acid form, have the Formula (1): ##STR1## Ar.sup.1 and Ar.sup.2 are each independently aryl or substituted aryl providing at least one of Ar.sup.1 and Ar.sup.2 has at least one substituent selected from COOH and COSH;each R.sup.1 and R.sup.2 is independently H, alkyl, substituted alkyl, alkenyl or substituted alkenyl;L is a divalent organic linking group;n is 0 or 1;each X independently is carbonyl or a group of the formula (2), (3) or (4): ##STR2## each Z independently is NR.sup.3 R.sup.4, SR.sup.5 or OR.sup.5 ; each Y independently is H, Cl, Z, SR.sup.6 or OR.sup.6 ;each E independently is Cl or CN;R.sup.3, R.sup.4, R.sup.5 and R.sup.6 are each independently H, alkyl, substituted alkyl, alkenyl, substituted alkenyl, aryl, substituted aryl, aralkyl, substituted aralkyl or R.sup.3 and R.sup.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: November 16, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: Peter Gregory, Ronald W. Kenyon, Prahalad M. Mistry
  • Patent number: 5212313
    Abstract: Compounds of the Formula VII: ##STR1## Wherein: X.sup.1 and X.sup.2 are each independently selected from --H, cyano, alkyl, alkoxy, aryl, carbamoyl, sulphamoyl, COOH and carboxylic acid ester;Z.sup.2 and Z.sup.2 are both --O--;R.sup.1 and R.sup.2 are each independently selected from H, or an optionally substituted alkyl, alkenyl, cycloalkyl, aryl and aralkyl group;R.sup.4, R.sup.5, R.sup.7 and R.sup.8 are each independently --H, halogen or an optionally substituted alkyl, alkenyl or alkoxy group; orR.sup.1 and R.sup.4 or R.sup.2 and R.sup.5 together with N atom and Ring B from a tetrahydroquinolinyl group; and R.sup.6 is selected from H, halogen or an optionally substituted alkyl or alkoxy group and a group NR.sup.1 R.sup.2 in which each of R.sup.1 and R.sup.2 are independently as hereinbefore described and where R.sup.6 is NR.sup.1 R.sup.2, R.sup.6 is the same or different form the NR.sup.1 R.sup.2 group present in Ring B.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: May 18, 1993
    Assignee: Imperial Chemical Industries Plc
    Inventors: Ronald W. Kenyon, David F. Newton, Derek Thorp
  • Patent number: 5203912
    Abstract: A dye which, in the free acid form, has the formula ##STR1## wherein W is COOHX is selected from H, COOH, SO.sub.3 H, halo, hydroxy, nitro, cyano, C.sub.1-6 -alkyl, C.sub.1-6 -alkoxy and C.sub.1-6 -acylamino;Y is H, COOH or SO.sub.3 H;Z is H, COOH or SO.sub.3 H;R & R.sup.1 are each independently H or C.sub.1-6 -alkyl substituted by 0, 1 or 2 --COOR.sup.2 groups; andR.sup.2 is H or C.sub.1-6 -alkyl;provided that there are at least two COOH groups and that the number of COOH groups is equal to or greater than the number of SO.sub.3 H groups.The dye is adapted for the preparation of inks for use in ink jet printing in which it displays high water-fastness on paper.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: April 20, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: David Greenwood, Nigel Hughes, Ronald W. Kenyon, Suraj L. Hindagolla
  • Patent number: 5196392
    Abstract: A thermal transfer printing sheet comprising a substrate having a coating of a polycyclic dye, selected from dioxodibenzofuran, dioxofuranindole and dioxobenzodipyrrole. The polycyclic dye carries pendant phenyl groups which themselves carry a variety of open-chain, cyclic and heterocyclic substituent groups.
    Type: Grant
    Filed: July 26, 1991
    Date of Patent: March 23, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: Roy Bradbury, Ronald W. Kenyon, Derek Thorp
  • Patent number: 5189154
    Abstract: Anionic phthalocyanine compounds which, in the free acid form, have the Formula (1):Pc(SO.sub.3 H).sub.t (SO.sub.2 --NR.sup.1 --L--NR.sup.2 --X--NR.sup.3 --G).sub.q (1)The compounds are useful as the colored component of inks, particularly those used in ink jet printing.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: February 23, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: Peter Gregory, Ronald W. Kenyon, Christine Millard
  • Patent number: 5183888
    Abstract: The present invention relates to a process for the preparation of certain polycyclic dyes and in particularly the preparation of a polycyclic dye of Formula I: ##STR1## By reacting a phenyltartronic acid of Formula II: ##STR2## With either a compound of Formula III: ##STR3## or a compound of Formula IV: ##STR4##
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: February 2, 1993
    Assignee: Imperial Chemical Industries PLC
    Inventors: Ronald W. Kenyon, David F. Newton, Derek Thorp
  • Patent number: 5084580
    Abstract: Compounds of the Formula VII: ##STR1## wherein; X.sup.1 and X.sup.2 are each independently selected from H, cyano, alkyl, alkoxy, aryl, carbamoyl, sulphamoyl, COOH and carboxylic acid ester;Z.sup.1 and Z.sup.2 are both --O--;R.sup.1 and R.sup.2 are each independently selected from H, or an optionally substituted alkyl, alkenyl, cycloalkyl, aryl and aralkyl group; orR.sup.1 and R.sup.2 together with the N atom to which they are attached, form a heterocycle;R.sup.4, R.sup.5, R.sup.7 and R.sup.8 are each independently selected from E, halogen, or an optionally substituted alkyl, alkenyl and alkoxy group orR.sup.1 and R.sup.4 or R.sup.2 and R.sup.5 together with the N atom and the two carbon atoms in Ring B to which they are attached form a heterocycle fused to Ring B; orR.sup.1 and R.sup.7 or R.sup.2 and R.sup.8 together with the N atom and the two carbon atoms in Ring A to which they are attached form a heterocycle fused to Ring A; orR.sup.
    Type: Grant
    Filed: September 21, 1989
    Date of Patent: January 28, 1992
    Assignee: Imperial Chemical Industries PLC
    Inventors: Ronald W. Kenyon, David F. Newton, Derek Thorp
  • Patent number: 5055566
    Abstract: A compound of the Formula (1): ##STR1## wherein R is H, SO.sub.3 A, C.sub.1-4 -alkyl, C.sub.1-4 -alkoxy, NO.sub.2, OH or halogen;W, X, Y and Z are independently H or SO.sub.3 A; andA is NQ.sub.4 wherein at least one Q is a branched chain fatty C.sub.6-20 -aliph atic group.
    Type: Grant
    Filed: June 19, 1990
    Date of Patent: October 8, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: Peter Gregory, Ronald W. Kenyon
  • Patent number: 5053495
    Abstract: A dye which, in the free acid form, has the formula ##STR1## wherein W is COOHX is selected from H, COOH, SO.sub.3 H, halo, hydroxy, nitro, cyano, C.sub.1-6 -alkyl, C.sub.1-6 -alkoxy and C.sub.1-6 -acylamino;Y is H, COOH or SO.sub.3 H;Z is H, COOH or SO.sub.3 H;R & R.sup.1 are each independently H or C.sub.1-6 -alkyl substituted by 0, 1 or 2 --COOR.sup.2 groups; andR.sup.2 is H or C.sub.1-6 -alkyl;provided that there are at least two COOH groups and that the number of COOH groups is equal to or greater than the number of SO.sub.3 H groups.The dye is adapted for the preparation of inks for use in ink jet printing in which it displays high water-fastness on paper.
    Type: Grant
    Filed: August 24, 1989
    Date of Patent: October 1, 1991
    Assignee: Imperial Chemical Industries PLC
    Inventors: David Greenwood, Nigel Hughes, Ronald W. Kenyon, Suraj L. Hindagolla
  • Patent number: 4916240
    Abstract: Compounds of the general formula: ##STR1## wherein Z.sup.1 and Z.sup.2 are each independently --O--, --S-- or --NR.sup.5 -- in which R.sup.5 is hydrogen, an optionally substituted hydrocarbon group or an acyl group;X.sup.1 and X.sup.2 are selected from hydrogen, halogen, cyano, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, aryl, carbamoyl, sulphamoyl, carboxy or carboxylic acid ester;R.sup.1 is an optionally substituted aryl radical;A is an optionally substituted alkyl radical or a radical of the formula:R.sup.2 --(CH.dbd.CH).sub.n --in whichR.sup.2 is an optionally substituted aryl or heterocyclic radical, andn has a value of 1 or 2.The compounds are useful as dyes for synthetic textile materials.
    Type: Grant
    Filed: May 26, 1988
    Date of Patent: April 10, 1990
    Assignee: Imperial Chemical Industries PLC
    Inventor: Ronald W. Kenyon
  • Patent number: 4881943
    Abstract: A disperse monoazo dye of the formula: ##STR1## wherein each of R and R.sup.3 represents a lower alkyl radical, R.sup.1 represents a lower alkyl or C.sub.3 -C.sub.6 alkenyl radical andR.sup.2 represents a C.sub.2 -C.sub.6 alkyl radical carrying a hydroxy or acyloxy substituent.
    Type: Grant
    Filed: June 28, 1988
    Date of Patent: November 21, 1989
    Assignee: Imperial Chemical Industries PLC
    Inventors: David Brierley, Ronald W. Kenyon, Denis R. A. Ridyard