Patents by Inventor Rondell Paul Little, Jr.
Rondell Paul Little, Jr. has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20250011534Abstract: The present disclosure relates to crystallizable shrinkable films and thermoformable film(s) or sheet(s) comprising blends of polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NPG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties.Type: ApplicationFiled: September 13, 2024Publication date: January 9, 2025Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, Jacob Edward Napierala, Rondell Paul Little, JR., James Carl Williams, James Wesley Peer
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Patent number: 12116452Abstract: A blend composition comprising a first polyester and a second polyester. The first and second polyesters each comprises residues of terephthalic acid, neopentyl glycol (NPG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and/or diethylene glycol (DEG). The first polyester comprises NPG, CHDM, and DEG in a combined amount that is less than the second polyester. The blend composition can be useful for producing a shrink film exhibiting high ultimate shrinkage (e.g., >65% at 95° C. for 10 seconds) and a high strain induced crystalline melting point (e.g., greater than 190° C.).Type: GrantFiled: October 8, 2019Date of Patent: October 15, 2024Assignee: Eastman Chemical CompanyInventors: Mark Allen Peters, Jacob E. Napierala, Rondell Paul Little, Jr., James Carl Williams, James Wesley Peer
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Publication number: 20230128818Abstract: The present disclosure relates to crystallizable shrinkable films and thermoformable film(s) or sheet(s) comprising blends of polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), diethylene glycol (DEG) and/or 2,2,4, 4-tetramethyl-1,3-butanediol (TMCD), in certain compositional ranges having certain advantages and improved properties.Type: ApplicationFiled: April 6, 2021Publication date: April 27, 2023Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, Jacob E. Napierala, Rondell Paul Little, JR., James Carl Williams, James Wesley Peer
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Publication number: 20210395446Abstract: The present disclosure relates to crystallizable shrinkable films and thermoformable film(s) or sheet(s) comprising blends of polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties.Type: ApplicationFiled: October 8, 2019Publication date: December 23, 2021Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, Jacob E. Napierala, Rondell Paul Little, Jr., James Carl Williams, James Wesley Peer
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Publication number: 20210394468Abstract: The present disclosure relates to crystallizable shrinkable films and thermoformable sheets comprising amorphous polyester compositions which comprise residues of terephthalic acid, neopentyl glycol (NRG), 1,4-cyclohexanedimethanol (CHDM), ethylene glycol (EG), and diethylene glycol (DEG), in certain compositional ranges having certain advantages and improved properties including recyclability.Type: ApplicationFiled: October 8, 2019Publication date: December 23, 2021Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, Jacob E. Napierala, Rondell Paul Little, JR., James Carl Williams
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Publication number: 20210086468Abstract: The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 26 mole % neopentyl glycol residues; (ii) about less than 10 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.Type: ApplicationFiled: December 2, 2020Publication date: March 25, 2021Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, James Carl Williams, Rondell Paul Little, JR., James Wesley Peer, Jacob E. Napierala
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Patent number: 10882272Abstract: The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 30 mole % neopentyl glycol residues; (ii) about 0.01 to about less than 15 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.Type: GrantFiled: December 11, 2019Date of Patent: January 5, 2021Assignee: Eastman Chemical CompanyInventors: Mark Allen Peters, James Carl Williams, Rondell Paul Little, Jr., James Wesley Peer, Jacob E. Napierala
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Publication number: 20200114614Abstract: The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 30 mole % neopentyl glycol residues; (ii) about 0.01 to about less than 15 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.Type: ApplicationFiled: December 11, 2019Publication date: April 16, 2020Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, James Carl Williams, Rondell Paul Little, JR., James Wesley Peer, Jacob E. Napierala
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Patent number: 10543656Abstract: The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 30 mole % neopentyl glycol residues; (ii) about 0.01 to about less than 15 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.Type: GrantFiled: January 11, 2018Date of Patent: January 28, 2020Assignee: Eastman Chemical CompanyInventors: Mark Allen Peters, James Carl Williams, Rondell Paul Little, Jr., James Wesley Peer, Jacob E. Napierala
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Publication number: 20190211167Abstract: The present disclosure relates to a shrink film comprising a polyester composition comprising: (1) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) about 70 to about 100 mole % of terephthalic acid residues; (ii) about 0 to about 30 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and (b) a diol component comprising: (i) about 0.01 to about 30 mole % neopentyl glycol residues; (ii) about 0.01 to about less than 15 mole % 1,4-cyclohexanedimethanol residues; (iii) about 50 to 90 mole % ethylene glycol residues; and (iv) about 2 to 15 mole % total diethylene glycol residues in the final polyester composition; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the diol component is 100 mole %.Type: ApplicationFiled: January 11, 2018Publication date: July 11, 2019Applicant: Eastman Chemical CompanyInventors: Mark Allen Peters, James Carl Williams, Rondell Paul Little, JR., James Wesley Peer, Jacob E. Napierala
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Patent number: 8986591Abstract: Disclosed are void-containing polyester shrink films which show excellent density retention upon exposures to high temperatures. The films have high shrinkage and retain their low density after processing under conditions of temperature and moisture used in typical recycling processes. The films are useful for sleeve label and other shrink film applications, and their lower density allows them to be readily separated from soft drink bottles, food containers and the like during recycling operations. Also disclosed is a process for void-containing polyester shrink films having high shrinkage and low density after exposure to elevated temperatures.Type: GrantFiled: August 6, 2010Date of Patent: March 24, 2015Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Candace Michele Tanner, Mark Elliott Tincher, Rondell Paul Little, Jr.
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Publication number: 20120000833Abstract: The present invention relates to the use of ferromagnetic materials to improve the recyclability of plastic packaging.Type: ApplicationFiled: July 1, 2010Publication date: January 5, 2012Applicant: EASTMAN CHEMICAL COMPANYInventors: Marcus David Shelby, Freddie Wayne Williams, Rondell Paul Little, JR.
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Publication number: 20110081510Abstract: The invention relates to blown films and methods of making blown films using a melt-strength enhanced polyester composition. The composition has a zero-shear viscosity and a degree of shear thinning that are comparable to PVC's melt rheology. The polyester composition has a branching agent and/or a fluoropolymer processing additive and an inherent viscosity of at least 0.60 dl/g. The diacid component of the polyester composition comprises 97 to 100 mole percent of residues of terephthalic acid, naphthalenedicarboxylic acid, isophthalic acid or mixtures thereof. The glycol component of the polyester composition comprises 97 to 100 mole percent of residues of ethylene glycol, 1,4-cyclohexanedimethanol, diethylene glycol, neopentyl glycol or mixtures thereof.Type: ApplicationFiled: August 24, 2010Publication date: April 7, 2011Applicant: EASTMAN CHEMICAL COMPANYInventors: Wayne Ken Shih, Rondell Paul Little, JR., Freddie Wayne Williams
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Publication number: 20100295200Abstract: Disclosed are void-containing polyester shrink films which show excellent density retention upon exposures to high temperatures. The films have high shrinkage and retain their low density after processing under conditions of temperature and moisture used in typical recycling processes. The films are useful for sleeve label and other shrink film applications, and their lower density allows them to be readily separated from soft drink bottles, food containers and the like during recycling operations. Also disclosed is a process for void-containing polyester shrink films having high shrinkage and low density after exposure to elevated temperatures.Type: ApplicationFiled: August 6, 2010Publication date: November 25, 2010Applicant: EASTMAN CHEMICAL COMPANYInventors: Marcus David Shelby, Candace Michele Tanner, Mark Elliott Tincher, Rondell Paul Little, JR.
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Publication number: 20090227735Abstract: Disclosed are polyester blends useful for the preparation of heat-shrinkable films, and heat-shrinkable films prepared therefrom. The heat shrinkable film may be oriented in the machine direction to produce films with high machine-direction shrinkage but low transverse growth or shrinkage. The films are useful for roll-fed, shrink-on label applications. Also disclosed are heat-shrinkable roll-fed labels prepared from reactor-grade polyesters.Type: ApplicationFiled: March 4, 2009Publication date: September 10, 2009Applicant: EASTMAN CHEMICAL COMPANYInventors: Wayne Ken Shih, Rondell Paul Little, JR.
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Patent number: 7157547Abstract: An ultraviolet absorption composition has been developed for the protection of packaging or container contents in the ultraviolet range of 290 nm to 390 nm, offering effective screening from all wavelengths of solar radiation. A combination of an optical brightener with an ultraviolet absorber has been found to provide effective screening without adding significant color to the polymer composition. This extended range of ultraviolet blocking over what can be achieved with ultraviolet absorbers alone is especially valuable in food and drink packaging applications where the contents of the packages need ultraviolet protection to prevent discoloration or development of undesirable flavors.Type: GrantFiled: November 13, 2003Date of Patent: January 2, 2007Assignee: Eastman Chemical CompanyInventors: Rondell Paul Little, Jr., Gether Irick, Jr., Emerson Eston Sharpe, Jr.
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Patent number: 6362306Abstract: A reactor grade copolyester composition, as well as a heat-shrinkable film made therefrom, unexpectedly has higher ductility than a multi-component blend of copolyesters with the same monomer concentrations. The reactor grade copolyester composition is made from a diacid component of at least about 90 mole percent and a diol component of (a) about 72 to about 88 mole percent ethylene glycol, about 10 to about 15 mole percent 1,4-cyclohexanedimethanol, and about 2 to about 13 mole percent diethylene glycol, or (b) about 59 to about 77.5 mole percent ethylene glycol, about 15 to about 28 mole percent 1,4-cyclohexane-dimethanol, and about 7.5 to about 13 mole percent diethylene glycol. Further, the heat-shrinkable film may be produced to closely match the shrink characteristics of polyvinyl chloride by varying the amounts of the diol components of the reactor grade copolyester composition. Furthermore, a reactor grade copolyester composition has a b* color value of −1.0 to less than 4.Type: GrantFiled: August 11, 2000Date of Patent: March 26, 2002Assignee: Eastman Chemical CompanyInventors: Marcus David Shelby, Wayne Ken Shih, Rondell Paul Little, Jr., Candace Michele Tanner, William LeRoy Wortman