Abstract: Curable cyanoacrylate compositions are reported that comprise cyanoacrylate and a thermoplastic polyurethane (TPU) components. Such compositions are toughened cyanoacrylate compositions exhibiting long term viscosity stability when stored for prolonged periods at room temperature (25° C.). TPU components are reported having structural units in which at least one of the structural units has the formula —O—R1—O—Ar—O—R2—O—, wherein Ar is a C6-C20 aromatic group with at least one aromatic ring; R1 is a C2-C10 alkyl group; and R2 is a C2-C10 alkyl group. The thermoplastic polyurethane (TPU) component may be present in the curable cyanoacrylate composition from about 1 wt % to about 40 wt %, for example from about 2 wt % to about 30 wt %, such from about 3 wt % to about 20 wt %, suitably from about 5 wt % to about 10 wt %, based on the total weight of the composition.

Abstract: Curable cyanoacrylate compositions are reported that comprise cyanoacrylate and a thermoplastic polyurethane (TPU) components. Such compositions are toughened cyanoacrylate compositions exhibiting long term viscosity stability when stored for prolonged periods at room temperature (25° C.). TPU components are reported having structural units in which at least one of the structural units has the formula —O—R1—O—Ar—O—R2—O—, wherein Ar is a C6-C20 aromatic group with at least one aromatic ring; R1 is a C2-C10 alkyl group; and R2 is a C2-C10 alkyl group. The thermoplastic polyurethane (TPU) component may be present in the curable cyanoacrylate composition from about 1 wt % to about 40 wt %, for example from about 2 wt % to about 30 wt %, such from about 3 wt % to about 20 wt %, suitably from about 5 wt % to about 10 wt %, based on the total weight of the composition.