Abstract: Embodiments of present invention provide a method of forming a semiconductor structure. The method includes forming a semiconductor structure having a first metal layer and a plurality of dielectric layers on top of the first metal layer; creating one or more openings through the plurality of dielectric layers to expose the first metal layer underneath the plurality of dielectric layers; causing the one or more openings to expand downward into the first metal layer and expand horizontally into areas underneath the plurality of dielectric layers; applying a layer of lining material in lining sidewalls of the one or more openings inside the plurality of dielectric layers; and filling the expanded one or more openings with a conductive material.

Abstract: Methods for multiple patterning a substrate may include: forming a hard mask including a carbonaceous layer and an oxynitride layer over the carbonaceous layer on a substrate; and forming a first pattern into the oxynitride layer and partially into the carbonaceous layer using a first soft mask positioned over the hard mask. A wet etching removes a portion of the first soft mask from the first pattern in the oxynitride layer without damaging the carbonaceous layer. Subsequently, a second pattern and a third pattern are formed into the hard mask, creating a multiple pattern in the hard mask. The multiple pattern may be etched into the substrate, followed by removing any remaining portion of the hard mask.

Abstract: Embodiments of present invention provide a method of forming a semiconductor structure. The method includes forming a semiconductor structure having a first metal layer and a plurality of dielectric layers on top of the first metal layer; creating one or more openings through the plurality of dielectric layers to expose the first metal layer underneath the plurality of dielectric layers; causing the one or more openings to expand downward into the first metal layer and expand horizontally into areas underneath the plurality of dielectric layers; applying a layer of lining material in lining sidewalls of the one or more openings inside the plurality of dielectric layers; and filling the expanded one or more openings with a conductive material.

Abstract: Embodiments of present invention provide a method of forming a semiconductor structure. The method includes forming a semiconductor structure having a first metal layer and a plurality of dielectric layers on top of the first metal layer; creating one or more openings through the plurality of dielectric layers to expose the first metal layer underneath the plurality of dielectric layers; causing the one or more openings to expand downward into the first metal layer and expand horizontally into areas underneath the plurality of dielectric layers; applying a layer of lining material in lining sidewalls of the one or more openings inside the plurality of dielectric layers; and filling the expanded one or more openings with a conductive material.

Abstract: The present invention relates to a method of selectively removing metal oxide, particularly tungsten oxide without etching the un-oxidized metal. The method removes metal oxide with little or no loss of the clean metal to improve the contact resistance for contact metal in semiconductor device fabrication. The method includes a step of exposing a substrate containing a tungsten oxide layer over a tungsten layer to a low oxygen aqueous ammonia solution to selectively remove the tungsten oxide layer. The low oxygen aqueous ammonia solution has an ammonia concentration in a range of about 0.01 M to about 2.0 M. The oxygen level in the solution is no more than 50 ppb. The solution may further contain a corrosion inhibitor and/or a compound having two or more carboxyl groups separated by at least one carbon atom.

Abstract: Embodiments of present invention provide a method of forming a semiconductor structure. The method includes forming a semiconductor structure having a first metal layer and a plurality of dielectric layers on top of the first metal layer; creating one or more openings through the plurality of dielectric layers to expose the first metal layer underneath the plurality of dielectric layers; causing the one or more openings to expand downward into the first metal layer and expand horizontally into areas underneath the plurality of dielectric layers; applying a layer of lining material in lining sidewalls of the one or more openings inside the plurality of dielectric layers; and filling the expanded one or more openings with a conductive material.

Abstract: Embodiments of present invention provide a method of forming a semiconductor structure. The method includes forming a semiconductor structure having a first metal layer and a plurality of dielectric layers on top of the first metal layer; creating one or more openings through the plurality of dielectric layers to expose the first metal layer underneath the plurality of dielectric layers; causing the one or more openings to expand downward into the first metal layer and expand horizontally into areas underneath the plurality of dielectric layers; applying a layer of lining material in lining sidewalls of the one or more openings inside the plurality of dielectric layers; and filling the expanded one or more openings with a conductive material.

Abstract: Embodiments of present invention provide a method of forming a semiconductor structure. The method includes forming a semiconductor structure having a first metal layer and a plurality of dielectric layers on top of the first metal layer; creating one or more openings through the plurality of dielectric layers to expose the first metal layer underneath the plurality of dielectric layers; causing the one or more openings to expand downward into the first metal layer and expand horizontally into areas underneath the plurality of dielectric layers; applying a layer of lining material in lining sidewalls of the one or more openings inside the plurality of dielectric layers; and filling the expanded one or more openings with a conductive material.

Abstract: A method of measuring temperature across wafers during semiconductor processing includes the step of providing a correlation between a peak wafer temperature during a processing step and a change in wafer surface charge or surface potential following the processing step. A first wafer to be characterized for its peak temperature spatial distribution during the processing step is processed through the processing step. The wafer surface charge or surface potential at a plurality of locations on the first wafer are measured following the processing step. A peak temperature spatial distribution for the first wafer is then determined based on the correlation and the wafer surface charge or surface potential measured in the measuring step.

Abstract: A method of forming an interconnect structure for an integrated circuit, including the steps of providing a substrate and forming a dielectric stack on the substrate including an etch-stop layer, a low-k dielectric layer, and a hardmask layer. The method further includes the steps of patterning a photoresist masking layer on the dielectric stack to define a plurality of feature defining regions and plasma processing the substrate in a plasma-based reactor, The processing step includes etching a plurality of features into the hardmask layer and at least a portion of the low-k dielectric layer and performing a plasma treatment process in situ in the plasma-based reactor, where the plasma treatment process includes flowing at least one hydrocarbon into the reactor and generating a plasma, where a mass flow rate of the hydrocarbon is at least 0.1 sccm. The method also includes forming a metal conductor in the plurality of features.

Abstract: A method of measuring temperature across wafers during semiconductor processing includes the step of providing a correlation between a peak wafer temperature during a processing step and a change in wafer surface charge or surface potential following the processing step. A first wafer to be characterized for its peak temperature spatial distribution during the processing step is processed through the processing step. The wafer surface charge or surface potential at a plurality of locations on the first wafer are measured following the processing step. A peak temperature spatial distribution for the first wafer is then determined based on the correlation and the wafer surface charge or surface potential measured in the measuring step.

Abstract: A method of forming an interconnect structure for an integrated circuit, including the steps of providing a substrate and forming a dielectric stack on the substrate including an etch-stop layer, a low-k dielectric layer, and a hardmask layer. The method further includes the steps of patterning a photoresist masking layer on the dielectric stack to define a plurality of feature defining regions and plasma processing the substrate in a plasma-based reactor, The processing step includes etching a plurality of features into the hardmask layer and at least a portion of the low-k dielectric layer and performing a plasma treatment process in situ in the plasma-based reactor, where the plasma treatment process includes flowing at least one hydrocarbon into the reactor and generating a plasma, where a mass flow rate of the hydrocarbon is at least 0.1 sccm. The method also includes forming a metal conductor in the plurality of features.