Abstract: The present disclosure provides an extrudable article and a composition, each including at least one polyurethane including hydroxyl groups and latent isocyanate groups in the form of uretdione groups. The hydroxyl groups are present on a first polyurethane and the latent isocyanate groups are present on either the first polyurethane or a second polyurethane and a ratio of the latent isocyanate groups to the hydroxyl groups is greater than 1.2:1. A method of making the extrudable article is provided including reacting in an extruder a polymerizable composition including a uretdione-containing material including a reaction product of a diisocyanate reacted with itself, a hydroxyl-containing compound, and an isocyanate-containing compound. A method of making a core-sheath filament is provided including forming a core composition of the at least one polyurethane and wrapping a sheath composition including an ethylene copolymer or a polyolefin around the core composition.

Abstract: An article comprising a first component having a first electrically conductive surface and a second component having a second surface. An adhesive composition comprising a zwitterionic polymer is disposed between the first electrically conductive surface and second surface and joins the first component to the second component. The effort required to separate the first component from the second component, as measured by work of adhesion per surface area, is reduced by application of a DC electric potential across the adhesive composition.

Abstract: A core-sheath filament having a non-tacky sheath and a hot-melt processable adhesive core, the sheath exhibiting a melt flow index of less than 15 grams per 10 minutes, is provided. Methods of making the core-sheath filament and methods of using the core-sheath filament to print a hot-melt processable adhesive onto a primer-treated substrate surface to provide a structural bond are described.

Abstract: An article comprising a first component having a first electrically conductive surface and a second component having a second surface. An adhesive composition comprising a cured polymerizable ionic liquid is disposed between the first electrically conductive surface and second surface and joins the first component to the second component. The polymerizable ionic liquid comprises an acid functional monomer and the conjugate acid of an imidazole compound. The effort required to separate the first component from the second component, as measured by work of adhesion per surface area, is reduced by application of a DC electric potential across the adhesive composition.

Abstract: Provided is an apparatus for dispensing a composition that includes a barrel having an inlet and outlet, an extrusion screw, and a drive mechanism operatively coupled to the extrusion screw. The extrusion screw includes a shaft having a shank end for connection to the drive mechanism and a distal end opposite the shank end. A first helical flight extends around a first section of the shaft, and a second helical flight extends around a second section of the shaft. The second section is located distal to the first section and the first helical flight has a nominal outer radius less than that of the second helical flight, and optionally the first helical flight has a pitch shorter than that of the first helical flight.

Abstract: The present invention is an assembly layer for a flexible device. The assembly layer is derived from precursors that include about 0 to about 50 wt % C1-C9 alkyl(meth)acrylate, about 40 to about 99 wt % C10-C24 (meth)acrylate, about 0 to about 30 wt % hydroxyl (meth)acrylate, about 0 to about 10 wt % of a non-hydroxy functional polar monomer, and about 0 to about 5 wt % crosslinker.

Abstract: Wet-on-wet coating processes are provided to produce multilayer articles. First and second coating materials are sequentially applied on to a structured substrate surface to form a skin layer directly over the structured substrate surface and a bulk layer over the skin layer. The conformability of the skin layer can be adjusted to provide desired surface and bulk properties.

Abstract: Methods of bonding a pressure-sensitive adhesive to a substrate are provided. The methods include heating a styrenic block copolymer composition to provide an adhesive melt composition, wherein the styrenic block copolymer composition contains a hard segment block with a glass transition temperature of from 90° C. to 220° C.; masticating the adhesive melt composition; delivering the adhesive melt composition onto the substrate at a temperature that exceeds the glass transition temperature of the hard segment block by from 20° C. to 150° C.; and cooling the adhesive melt composition to obtain a bonded pressure-sensitive adhesive. Optionally, the substrate can be a non-film substrate, or the styrenic block copolymer composition can be provided in a core-sheath filament that includes a styrenic block copolymer core and a sheath that is non-tacky at ambient temperature.

Abstract: A core-sheath filament having a non-tacky sheath and a hot-melt processable adhesive core, the sheath exhibiting a melt flow index of less than 15 grams per 10 minutes, is provided. Methods of making the core-sheath filament and methods of using the core-sheath filament to print a hot-melt processable adhesive onto a primer-treated substrate surface to provide a structural bond are described.

Abstract: A core-sheath filament including a crosslinkable adhesive core that can be cured using ultraviolet or visible light radiation. These crosslinkable adhesive core compositions can provide very high bond strength and are capable of replacing traditional mechanical fasteners in many industrial applications. Core-sheath filaments including such crosslinkable compositions, crosslinked compositions, articles containing these compositions, and methods of making the articles are provided. The crosslinkable compositions contain pendant aromatic ketone groups or pendant (meth)acryloyl groups that, upon exposure to ultraviolet radiation, result in the formation of crosslinks within the polymeric material. The crosslinked compositions can function as pressure-sensitive adhesives.

Abstract: A core-sheath filament having a non-tacky sheath and a hot-melt processable adhesive core, the sheath exhibiting a melt flow index of less than 15 grams per 10 minutes, is provided. Methods of making the core-sheath filament and methods of using the core-sheath filament to print a hot-melt processable adhesive onto a primer-treated substrate surface to provide a structural bond are described.

Abstract: Pressure-sensitive adhesive compositions are described comprising polymerized units of (meth)acrylate monomer. Also described are articles comprising such pressure-sensitive adhesive composition.

Abstract: A curable mixture, a partially cured composition, a cured composition, an article containing either the partially cured composition or the cured composition, and a method of bonding two substrates are provided. The partially cured composition functions as a pressure-sensitive adhesive while the cured composition functions as a structural or semi-structural adhesive. The curable mixture can be applied to a first substrate by printing or dispensing, if desired.

Abstract: A filament article containing a curable composition is provided. The filament article has a first part containing an epoxy resin and a second part containing a polyamine having at least two secondary or primary amino groups. The first part is surrounded by a sheath and a second part surrounded by a sheath. Either 1) the first part surrounded by the sheath and the second part surrounded by the sheath are each a separate filament or 2) the first part surrounded by the sheath and the second part surrounded by the sheath combine to form a composite filament. The curable filament article can be used to form a cured composition having structural bonding performance.

Abstract: A core-sheath filament is provided that includes a curable composition. The curable composition contains an epoxy resin and a photoacid generator. Methods of making the core-sheath filament and methods of using the core-sheath filament for printing and bonding are provided. The core-sheath filaments can be used to form a cured composition having structural bonding performance.

Abstract: Curable adhesive compositions are provided that can be cured using ultraviolet or visible light radiation. These curable adhesive compositions, which contain a curable (meth)acrylate copolymer, have a creep compliance that is less than 5(10?4) inverse Pascals at 25° C., a creep compliance that is greater than 1(10?3) inverse Pascals at 70° C., and a shear storage modulus greater than 40 kiloPascals when measured at 25° C. at a frequency of 1 radian/second.

Abstract: The present invention is an assembly layer for a flexible device. The assembly layer is derived from precursors that include about 0 to about 50 wt % C1-C9 alkyl(meth)acrylate, about 40 to about 99 wt % C10-C24 (meth)acrylate, about 0 to about 30 wt % hydroxyl (meth)acrylate, about 0 to about 10 wt % of a non-hydroxy functional polar monomer, and about 0 to about 5 wt % crosslinker.

Abstract: Wet-on-wet coating processes are provided to produce multilayer articles. First and second coating materials are sequentially applied on to a structured substrate surface to form a skin layer directly over the structured substrate surface and a bulk layer over the skin layer. The conformability of the skin layer can be adjusted to provide desired surface and bulk properties.

Abstract: Modified adhesive layers are prepared by contacting an adhesive layer to a modified microstructured release liner. The modified release liner has a release layer surface with a set of microstructured depressions and a discontinuous pattern of ink material located on the surface of the release layer. A portion of the discontinuous pattern of ink material overlaps with and is located within some of the depressions. The ink material comprises a non-adhesive but adhesively transferrable material, or an adhesive material. Upon removal of the adhesive from the release liner, the ink material transfers to the adhesive surface.

Abstract: The present disclosure relates to adhesive article that include a first, stretch releasable adhesive and patterned adhesive elements on, within, or partially embedded in a surface of the adhesive. The adhesive elements can act as spacers between the adhesive surface and the mounting surface to prevent full contact and wet out of the first adhesive, whereby the article can be removed from the wall and placed at a new location without damage to the wall surface or the article. Once the final location is selected, the separation created by the engineered elements can be overcome by applying sufficient pressure; the first adhesive can contact and adhere more permanently to the wall. Thus, a stretch releasable adhesive articles of the present disclosure can move freely relative to the desired mounting surface, while developing additional tack and holding power after sufficient pressure is applied.