Abstract: Glass-based articles are provided that exhibit improved drop performance. The relationship between properties attributable to the glass composition and stress profile of the glass-based articles are provided that indicate improved drop performance.

Abstract: Provided are methods of forming a chemically strengthened glass-based article. Certain methods comprise: providing a glass-based substrate comprising a first surface and a second surface opposing the first surface defining a thickness (t), a length dimension, a width, and a weight; and ion exchanging a plurality of alkali ions into the glass-based substrate to form a non-zero alkali metal oxide concentration that varies along at least a substantial portion of the thickness (t). The ion exchanging comprises immersing a glass-based substrate in a molten salt bath comprising at least about 90% by weight KNO3, and less than about 10% by weight NaNO3 for a time in the range of 70% to 130% of the ion exchange time that produces a peak central tension (CT) with the same molten salt bath composition and temperature. Also provided are ion exchanged glass-based articles prepared by said methods.

Abstract: A method of reworking lithium containing ion exchanged glass articles is provided. The method includes a reverse ion exchange process that returns the glass article to approximately the composition of the glass from which the glass article was produced, before being subjected to ion exchange. The reworked glass articles exhibit a K2O concentration profile comprising a portion wherein a K2O concentration increases to a local K2O concentration maximum.

Abstract: The prism-coupling systems and methods include using a prism-coupling system to collect a 2D digital mode spectrum of an IOX article. The mode line and critical angle positions and orientations are found by performing a weighted fit to mode line and critical angle images and are used to define a compensated mode spectrum. If mode line tilt is found, it is removed from the 2D digital mode spectrum to define the compensated mode spectrum. The compensated mode spectrum is then processed using techniques known in the art to provide a more accurate estimate of stress-related characteristics of the IOX sample versus using the uncompensated mode spectrum. Derivative-based methods of accurately establishing positions of intensity transitions in a mode spectrum of an IOX sample using a derivative spectrum and curve fitting are also disclosed.

Abstract: A laminated glass article comprises a core layer comprising a core glass composition, and a cladding layer directly adjacent to the core layer and comprising a clad glass composition. A stress of the cladding layer increases with increasing distance from an outer surface of the cladding layer from a compressive stress to a tensile stress, transitions to a compressive stress as a step-change at an interface region between the core layer and the cladding layer, and increases with increasing distance from the interface region to a center of the core layer from the compressive stress to a tensile stress.

Abstract: A method of reworking lithium containing ion exchanged glass-based articles is provided. The method includes a reverse ion exchange process that returns the glass-based article to approximately the composition of the glass from which the glass-based article was produced, before being subjected to ion exchange.

Abstract: Glass-based articles comprise stress profiles providing improved fracture resistance. The glass-based articles herein provide high fracture resistance after multiple drops.

Abstract: Glass-based articles comprise: a lithium-based aluminosilicate composition; a glass-based substrate having opposing first and second surfaces defining a substrate thickness (t), wherein t is less than or equal to 0.74 mm; and a stress profile comprising: a spike region extending from the first surface and comprising a spike depth of layer (DOLsp) located at a depth of greater than or equal to 7 micrometers; and a maximum central tension (CTmax) of greater than or equal to 50 MPa.

Abstract: Glass-based articles comprise: a lithium-based aluminosilicate composition; a glass-based substrate having opposing first and second surfaces defining a substrate thickness (t), wherein t is less than or equal to 0.74 mm; and a stress profile comprising: a spike region extending from the first surface to a tail region. A stress profile comprises: a maximum compressive stress (CSmax) of greater than or equal to 450 MPa; a spike region extending from the first surface to a tail region; and the tail region extending to a center of the glass-based article; wherein the tail region comprises: a region of enhanced stress having a first average compressive stress (CSavg?1) of greater than or equal to 100 MPa; and a FSM depth of layer (DOLFSM) located at a depth of greater than or equal to 13 micrometers.

Abstract: Methods of characterizing ion-exchanged chemically strengthened Li-containing glasses include: a) measuring a mode spectrum of the glass sample; b) using the mode spectrum, estimating a first contribution to the center tension associated with a spike region and estimating a second contribution to the center tension due to a deep region only, wherein the deep region is assumed to follow a power-law stress profile; and c) determining a total center tension by adding of the first and second contributions to the center tension. The methods can be used for quality control during manufacturing of glass samples by comparing the total center tension to a center tension specification that provides optimum strength and durability.

Abstract: A non-frangible glass article strengthened by a dual or two-step ion exchange (IOX) process, where the first IOX step leads to a depth of compressive layer FSM_DOL>0.1·t or, in some embodiments, FSM_DOL>0.15·t, where t is the thickness of the glass, is provided. The glass article has a compressive stress CS1 after the first IOX step at the surface of from 100 MPa to 400 MPa or, in some embodiments, from 150 MPa to 300 MPa. The first IOX step is followed by a second IOX step, leading to a “spike” compressive stress CS2 after the second IOX step at the surface of greater than 500 MPa or, in some embodiments, 700 MPa. The width of the spike generated by the second IOX is between 1 ?m and 30 ?m, or between 8 ?m and 15 ?m, using the criteria where the magnitude (absolute value) of the slope of the spike is higher than 20 MPa/?m.

Abstract: Glasses having a thickness tin a range from about 0.1 mm to less than 0.4 mm which, when chemically strengthened, is non-frangible and has a physical center tension CT (also referred to herein as “physical CT”), wherein CT>|?1.956×10?16×t6+1.24274×10?12×t5?3.09196×10?9×t4+3.80391×10?6×t3?2.35207×10?3×t2+5.96241×10?1×t+36.5994|, where t is expressed in microns.

Abstract: A method of reworking lithium containing ion exchanged glass-based articles is provided. The method includes a reverse ion exchange process that returns the glass-based article to approximately the composition of the glass from which the glass-based article was produced, before being subjected to ion exchange.

Abstract: Glass-based articles comprise stress profiles providing improved fracture resistance. The glass-based articles herein provide high fracture resistance after multiple drops.

Abstract: Glasses having a thickness t in a range from about 0.1 mm to less than 0.4 mm which, when chemically strengthened, is non-frangible and has a physical center tension CT (also referred to herein as “physical CT”), wherein CT>|?1.956×10?16×t6+1.24274×10?12×t5?3.09196×10?9×t4+3.80391×10?6×t3?2.35207×10?3×t2+5.96241×10?1×t+36.5994|, where t is expressed in microns.

Abstract: A glass exhibiting non-frangible behavior in a region where substantially higher central tension is possible without reaching frangibility is provided. This region allows greater extension of the depth of compression in which fracture-causing flaws are arrested, without rendering the glass frangible despite the presence of high central tension region in the sample.

Abstract: Glass-based articles are provided that exhibit improved fracture resistance. The relationships between properties attributable to the glass composition and stress profile of the glass-based articles are provided that indicate improved fracture resistance.

Abstract: Glass-based articles having defined stress profiles and methods for manufacturing such glass-based articles are provided. A non-limiting glass-based article comprises an outer region extending from the surface to a depth of compression, wherein the outer region is under a neutral stress or a first compressive stress, a core region under a second compressive stress, the second compressive stress defining a compression peak having a maximum compression value and a maximum width at zero stress in a range of from about 1 micrometer to about 200 micrometers, and an intermediate region disposed between the surface and the core region, wherein the intermediate region is under a tensile stress.

Abstract: Ion-exchanged glass ceramic articles described herein have a stress that decreases with increasing distance according to a substantially linear function from a depth of about 0.07t to a depth of about 0.26t from the outer surface of the ion-exchanged glass ceramic article from a compressive stress to a tensile stress. The stress transitions from the compressive stress to the tensile stress at a depth of from about 0.18t to about 0.25t from the outer surface of the ion-exchanged glass ceramic article. An absolute value of a maximum compressive stress at the outer surface of the ion-exchanged glass article is from 1.8 to 2.2 times an absolute value of a maximum central tension (CT) of the ion-exchanged glass article, and the glass ceramic article has a fracture toughness of 1 MPa?m or more as measured according to the double cantilever beam method.

Abstract: Chemically strengthened glass articles having at least one deep compressive layer extending from a surface of the article to a depth of compression DOC of at least about 125 ?m within the glass article. The compressive stress profile includes a single linear segment or portion extending from the surface to the depth of compression DOC. Alternatively, the compressive stress profile may include an additional portion extending from the surface to a relatively shallow depth and the linear portion extending from the shallow depth to the depth of compression.