Abstract: A method for making a zeolite includes providing a reaction mixture containing mixed inorganic oxides and an organic templating agent, heating the reaction mixture, removing the templating agent at a temperature of no greater than 550° C. and under conditions such that the resulting zeolite is has an AAI of at least 1.2. The zeolite is preferably zeolite beta, TEA-mordenite or TEA-ZSM-12.

Abstract: An apparatus for converting at least one nitrogen oxide, such as NO, O2, or N2O converts oxide in the presence of a catalyst supported on a metal mesh-like structure. The mesh-like structure is preferably fibrous formed of metal or ceramic fibers which may include knitted wire, sintered metal fibers and so on and has a porosity greater than about 85%. The mesh is formed into channels, preferably corrugations, and includes vortex generators, which generate turbulence to create a pressure differential across the mesh, to promote flow of fluids through the mesh pores which normally do not exhibit flow therethrough in the absence of such pressure differential. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst preferably in the mesh pores and/or coated on the fibers for converting the nitrogen oxide.

Abstract: A method for making a zeolite includes providing a reaction mixture containing mixed inorganic oxides and an organic templating agent, heating the reaction mixture, removing the templating agent at a temperature of no greater than 550° C. and under conditions such that the resulting zeolite is has an AAI of at least 1.2. The zeolite is preferably zeolite beta, TEA-mordenite or TEA-ZSM-12.

Abstract: An improved zeolite having a high number of strong acid sites wherein said zeolite has an AAI of at least 1.0. In a preferred embodiment, such zeolite is produced by controlling conditions after production of the crystalline structure such that loss of tetrahedral aluminum is minimized to thereby provide a zeolite with the above defined AAI.

Abstract: A process for oxidizing environmentally harmful compounds which participate in atmospheric photochemical reactions to produce for example ozone and undesirable smog constituents from a fluid, in particular a gas, volatile organic compounds (VOC) including hydrocarbons, CO and any other constituent that participates in atmospheric photochemical reactions to produce for example ozone or smog constituents and combustible compounds to be removed from a gas stream for reasons of toxicity, photochemical reactivity or physical discomfort such as irritants, particulates, odor sources and so on, and compounds which may cause upper atmosphere ozone depletion or lower atmosphere ozone formation. The uncoated randomly oriented mesh-like structure preferably has a porosity greater than about 85%. The coated randomly oriented mesh-like structure preferably has a porosity greater than about 65%.

Abstract: An apparatus for converting at least one nitrogen oxide, such as NO1O2, or N2O converts oxide in the presence of a catalyst supported on a metal mesh-like structure. The mesh-like structure is preferably fibrous formed of metal or ceramic fibers which may include knitted wire, sintered metal fibers and so on and has a porosity greater than about 85%. The mesh is formed into channels, preferably corrugations, and includes vortex generators, which generate turbulence to create a pressure differential across the mesh, to promote flow of fluids through the mesh pores which normally do not exhibit flow therethrough in the absence of such pressure differential. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst preferably in the mesh pores and/or coated on the fibers for converting the nitrogen oxide.

Abstract: An apparatus for converting at least one nitrogen oxide, such as NO, NO2, or N2O converts oxide in the presence of a catalyst supported on a metal mesh-like structure. The mesh-like structure is preferably fibrous formed of metal or ceramic fibers which may include knitted wire, sintered metal fibers and so on and has a porosity greater than about 85%. The mesh is formed into channels, preferably corrugations, and includes vortex generators, which generate turbulence to create a pressure differential across the mesh, to promote flow of fluids through the mesh pores which normally do not exhibit flow therethrough in the absence of such pressure differential. Preferred embodiments of structured packing and monoliths are disclosed each having a catalyst preferably in the mesh pores and/or coated on the fibers for converting the nitrogen oxide.

Abstract: A process for oxidizing environmentally harmful compounds which participate in atmospheric photochemical reactions to produce for example ozone and undesirable smog constituents from a fluid, in particular a gas, volatile organic compounds (VOC) including hydrocarbons, CO and any other constituent that participates in atmospheric photochemical reactions to produce for example ozone or smog constituents and combustible compounds to be removed from a gas stream for reasons of toxicity, photochemical reactivity or physical discomfort such as irritants, particulates, odor sources and so on, and compounds which may cause upper atmosphere ozone depletion or lower atmosphere ozone formation. The uncoated randomly oriented mesh-like structure preferably has a porosity greater than about 85%. The coated randomly oriented mesh-like structure preferably has a porosity greater than about 65%.

Abstract: An improved zeolite having a high number of strong acid sites wherein said zeolite has an AAI of at least 1.0. In a preferred embodiment, such zeolite is produced by controlling conditions after production of the crystalline structure such that loss of tetrahedral aluminum is minimized to thereby provide a zeolite with the above defined AAI.

Abstract: A process for selectively oxidizing an organic molecule by reacting said organic molecule and oxygen in the presence of a selective oxidation catalyst supported on a mesh-like structure.

Abstract: A catalytic reactor and process wherein the reactor contains a fixed catalyst bed comprised of at least one layer of a mesh having catalyst particles and/or catalyst fibers retained in the interstices of the mesh, wherein the catalyst particles have an average particle size of no greater than 200 microns and the fibers have a diameter of no greater than 500 microns and wherein the wire mesh layer has a void volume of at least 45%.

Abstract: A process of selectively hydrogenating an impurity in a feed containing hydrocarbons, such as, for example, an impurity selected from the group consisting of acetylene compounds, dienes, and mixtures thereof in a feed containing at least one monoolefin and the impurity wherein the impurity is hydrogenated selectively in the presence of a selective hydrogenation catalyst supported on a particulate support. The supported catalyst is supported on a mesh-like structure.

Abstract: This invention relates to the synthesis of large pore composite molecular sieves and to the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilities of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted.

Abstract: A structured packing (which may or may not include a catalyst) formed from a mesh material having pore openings of less than 50 microns wherein the packing is provided with turbulence generators to promote flow of fluid through the pore openings and may be further provided with additional openings larger than the pores to improve bulk mixing.

Abstract: A porous composite product comprised of a network of fibers is produced by forming an unsintered preformed network of fibers and a gasifiable structure forming agent, followed by gasification of the structure forming agent prior to sintering of the fibers at appropriate junction points. The preferred structure forming agent is a cellulosic material.

Abstract: This invention relates to the synthesis of large pore composite molecular sieves and to the synthetic large pore composite molecular sieves so produced. The molecular sieves of the invention have the same general utilties of the comparable molecular sieves of the prior art but have been found to be superior catalysts and absorbents. This invention relates to a hydrothermal synthesis of large pore molecular sieves from nutrients, at least one of which contains an amorphous framework-structure, and which framework-structure is essentially retained in the synthetic molecular sieve. This invention stems from a discovery that the intrinsic porosity characteristics of a nutrient that possesses an amorphous cation oxide-framework can be substantially retained in the final molecular sieve containing product formed by a hydrothermal process by carefully controlling the conditions under which the hydrothermal process is conducted.