Patents by Inventor Rudolf Kropp

Rudolf Kropp has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6069281
    Abstract: The invention relates to the preparation of organic nitrogen compounds, in particular of aminoalkanes, alkyloximes, alkylnitrones or mixtures thereof, which have only one nitrogen-functional group and no alcoholic hydroxyl groups in the molecule, from nitro-containing reaction products of polymers of C.sub.2 -C.sub.6 -olefins with an average degree of polymerization P=5-100 with nitrogen oxides or mixtures of nitrogen oxides and oxygen by hydrogenation of these reaction products. The invention also relates to particular mixtures of such aminoalkanes, alkyloximes and/or alkylnitrones and to individual compounds of these types themselves. The designated products are suitable as additives to fuels and lubricants.
    Type: Grant
    Filed: January 13, 1998
    Date of Patent: May 30, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Wolfgang Siegel, Boris Breitscheidel, Wolfgang Harder, Harald Schwahn, Wolfgang Reif
  • Patent number: 6005144
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: November 5, 1998
    Date of Patent: December 21, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5980594
    Abstract: Reaction products of polymers of C.sub.2 -C.sub.6 -olefins having an average degree of polymerization P of from 5 to 100 and oxides of nitrogen or mixtures of oxides of nitrogen and oxygen are used as additives for fuels, in particular for fuels for gasoline engines.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: November 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5972856
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: December 10, 1998
    Date of Patent: October 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5879420
    Abstract: Reaction products of polyisobutenes having an average degree of polymerization P of from 10 to 100 and a content E of from 60 to 90% of double bonds which can react with maleic anhydride, E=100% corresponding to the theoretical value for the case where each molecule of the polyisobutene has such a reactive double bond, with oxides of nitrogen or mixtures of oxides of nitrogen and oxygen, are suitable as additives for fuels, in particular for gasoline engines, and for lubricants.
    Type: Grant
    Filed: January 21, 1997
    Date of Patent: March 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Eckhard Hickmann, Klaus Ebel, Wolfgang Gunther, Hans Peter Rath, Harald Schwahn
  • Patent number: 5679863
    Abstract: The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides. .alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: October 21, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Fischer, Eckhard Hickmann, Rudolf Kropp, Jochen Schroeder, Beate Trentmann
  • Patent number: 5504236
    Abstract: The preparation of .alpha.-carbonylphosphine oxides by oxidizing an .alpha.-hydroxyalkyl phosphine oxide with an organic hydroperoxide or of an organic peroxy acid in the presence of a compound of a Group IV to Group VIII metal in the periodic table, and novel .alpha.-hydroxybenzyl phosphine oxides..alpha.-Carbonylphosphine oxides are used as photoinitiators for polymerizable compositions.
    Type: Grant
    Filed: September 7, 1993
    Date of Patent: April 2, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Martin Fischer, Eckhard Hickmann, Rudolf Kropp, Jochen Schroeder, Beate Trentmann
  • Patent number: 5296636
    Abstract: A process for the preparation of 2,4,6-trimethylbenzoic acid of the formula I ##STR1## in which .alpha.-chloro-2,4,6-trimethylacetophenone is reacted with an alkali hydroxide solution and chlorine in the presence of a phase-transfer catalyst at a temperature ranging from 0.degree. to 150.degree. C. and a pressure ranging from 0.01 to 50 bar, and a process for the preparation of 2,4,6-trimethylbenzoic acid I, in which .alpha.-chloro-2.4.6-trimethylacetophenone of the formula II ##STR2## is reacted with 1,3,5-trimethylbenzene and chloroacetyl chloride in the presence of a catalyst at a temperature ranging from 0.degree. to 150.degree. C. and a pressure ranging from 0.01 to 50 bar, the catalyst used being an iron oxide.
    Type: Grant
    Filed: January 28, 1993
    Date of Patent: March 22, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Siegel, Rudolf Kropp, Jochen Schroeder
  • Patent number: 5225602
    Abstract: Phenylacetaldehydes of the structure (I) ##STR1## where the substituents X are 2,4-dichloro, difluoro, trifluoro, tetrafluoro, p-trifluoromethyl, 2-methyl-4-fluoro, haloalkoxy or haloalkylthio radicals or are adjacent Cl, F, CF.sub.3, alkyl, alkoxy, haloalkoxy and/or haloalkylthio radicals.
    Type: Grant
    Filed: October 17, 1989
    Date of Patent: July 6, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Wolfgang Hoelderich, Norbert Goetz, Leopold Hupfer, Rudolf Kropp, Hans Theobald, Bernd Wolf
  • Patent number: 4909985
    Abstract: Economical, tarnish-resistant precious-metal alloys for dentistry consisting essentially of 36 to 39% silver, 28 to 32.5% gold, 17 to 19.5% palladium, 0 to 0.1% iridium, 9.5 to 10.5% copper, 0.5 to 3% indium and 0.5 to 2.5% zinc, whereby the sum of the indium and zinc contents does not exceed a maximum of 4%.
    Type: Grant
    Filed: June 2, 1989
    Date of Patent: March 20, 1990
    Assignee: Degussa Aktiengesellschaft
    Inventors: Rudolf Kropp, Wolfgang Kuerten
  • Patent number: 4870100
    Abstract: 2-benzylfuryl compounds of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are identical or different substituents and are each hydrogen, halogen, alkyl, haloalkyl, alkoxy, haloalkoxy, haloalkylthio, alkenyl or haloalkenyl, each of not more than 6 carbon atoms, n being 1, 2 or 3 where R.sup.3 is not hydrogen, and R.sup.4 and R.sup.5 are each hydrogen or alkyl of not more than 6 carbon atoms, R is --CHO or CHR.sup.6 OA, R.sup.6 is hydrogen, cyano, alkyl, alkenyl, haloalkenyl or alkynyl, each of not more than 6 carbon atoms, or carboxamide, and A is either hydrogen or a radical of an acid typical for pyrethroids, with the proviso that R.sup.2 is not hydrogen, chlorine, bromine, methyl or methoxy when R.sup.1 is hydrogen or methyl and R.sup.3 and A are each hydrogen, and furthermore with the proviso that R.sup.1 and R.sup.2 are not methyl when A is a radical of tetramethylcyclopropanecarboxylic acid, and finally with the proviso that R.sup.2 is not methyl, chlorine, bromine or methoxy and R.
    Type: Grant
    Filed: December 11, 1986
    Date of Patent: September 26, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Wolf, Hans Theobald, Rainer Becker, Norbert Goetz, Walter Himmele, Rudolf Kropp
  • Patent number: 4820821
    Abstract: Novel 1-phenyl-4(1H)-pyridazinone-imines of the formula (I) ##STR1## which are substituted at the imine nitrogen, and their addition salts with a physiologically tolerated acid, processes for their preparation, pharmaceutical formulations containing these compounds, and their use as drugs, in particular as antidepressants, antiparkinson drugs and antihypotonic agents.
    Type: Grant
    Filed: April 17, 1987
    Date of Patent: April 11, 1989
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Marco Thyes, Rainer Schlecker, Albrecht Franke, Franz Reicheneder, Dora I. Reicheneder, August Amann, Hans-Juergen Teschendorf, Rolf Kretzschmar, Martin Traut, Josef Gries
  • Patent number: 4760056
    Abstract: Oximinophosphoric acid derivatives of the formula ##STR1## where R.sup.1 is a straight-chain or branched alkyl of not more than 4 carbon atoms, R.sup.2 is a straight-chain or branched alkoxy or alkylthio group of not more than 4 carbon atoms, straight-chain or branched alkyl of not more than 3 carbon atoms, phenyl, amino or a straight-chain or branched alkylamino or dialkylamino radical, where alkyl in each case is of not more than 4 carbon atoms, and X is oxygen or sulfur, a process for the manufacture of these oximinophosphoric acid derivatives, and their use for controlling pests.
    Type: Grant
    Filed: April 23, 1986
    Date of Patent: July 26, 1988
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Buerstinghaus, Franz Merger, Rudolf Kropp, Karl Kiehs, Heinrich Adolphi
  • Patent number: 4565870
    Abstract: Salts of 1,2,3,4-tetrahydro-.beta.-carbolines of the formula I ##STR1## where R is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or trifluoromethyl, x is halogen and n is an integer from 2 to 5, and their preparation are described. The compounds are intermediates for the preparation of pharmacologically active substances.
    Type: Grant
    Filed: August 2, 1983
    Date of Patent: January 21, 1986
    Assignee: BASF Aktiengesellschaft
    Inventor: Rudolf Kropp
  • Patent number: 4324725
    Abstract: Preparation of 5-(2,2-dihalovinyl)-4,4-dialkyl-tetrahydro-furan-2-ones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl of 1 to 4 carbon atoms and X is halogen, by reacting a carboxylic acid amide of the formula II ##STR2## where R.sup.3 and R.sup.4 are each alkyl of 1 to 4 carbon atoms, aralkyl of 7 to 9 carbon atoms or aryl of 6 to 10 carbon atoms, or together with the nitrogen form a 5-membered or 6-membered saturated ring which may contain a second hetero-atom, with a carbon tetrahalide of the formula IIICX.sub.4 (III)to give an iminium salt of the formula IV ##STR3## and then hydrolyzing the iminium salt; and novel iminium salts of the formula IV.
    Type: Grant
    Filed: August 14, 1980
    Date of Patent: April 13, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Martin Fischer, Klaus Halbritter
  • Patent number: 4320062
    Abstract: Preparation of 5-(2,2,2-trihaloethyl)-4,4-dialkyl-tetrahydro-furan-2-ones of the formula I ##STR1## where R.sup.1 and R.sup.2 are each alkyl of 1 to 4 carbon atoms and X is halogen, by reacting a carboxylic acid amide of the formula II ##STR2## where R.sup.3 and R.sup.4 are each alkyl of 1 to 4 carbon atoms, aralkyl of 7 to 9 carbon atoms or aryl of 6 to 10 carbon atoms or together with the nitrogen on which they are present as substituents form a 5-membered or 6-membered saturated ring which may contain a second hetero-atom, with a carbon tetrahalide of the formula IIICX.sub.4 (III)to give an iminium salt of the formula IV ##STR3## and subsequently hydrolyzing this iminium salt; and novel iminium salts of the formula IV.
    Type: Grant
    Filed: August 14, 1980
    Date of Patent: March 16, 1982
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Martin Fischer, Klaus Halbritter
  • Patent number: 4268445
    Abstract: The preparation of bicyclic enol-ethers (I) ##STR1## (where n is from 3 to 12, and R.sup.1, R.sup.2 and R.sup.3 may be H or C.sub.1 --C.sub.4 -alkyl) by free radical adduct formation of CHR.sup.1 =CR.sup.2 --CHR.sup.3 --O--R.sup.4 (III)(where R.sup.4 is tert.-butyl, tetrahydrofuran-2-yl or tetrahydropyran-2-yl) with a cyclic ketone (IV) ##STR2## followed by acid-catalyzed cyclization, and novel compounds II ##STR3## The compounds (I) and (II) are intermediates for the synthesis of musk-like fragrances.
    Type: Grant
    Filed: January 31, 1980
    Date of Patent: May 19, 1981
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Frank Thoemel, Axel Nuerrenbach, Werner Hoffman, Franz Wenisch, Hartwig Fuchs
  • Patent number: 4255191
    Abstract: Gold-silver alloys with good tarnish resistance for the dental art are prepared which, contrary to the known tarnish resistant alloys, still contain copper and thus have a deeper gold color and a high ductility. The alloys contain 33 to 48% gold, 0-5% platinum, 1-10% palladium, 0-0.2% iridium and/or ruthenium, 3-9% copper, 1-6% zinc, 0.5-4% tin and 2.5-10% indium, balance silver, wherein the mass ratio of copper to zinc is between 1:1 and 4:1, the content of copper is not higher than the sum of zinc, tin and indium, the content of palladium is at most three times as great as that of indium and does not exceed the sum of zinc, tin and indium. Under these provisions the copper content is not perceptibly disadvantageous to the resistance to discoloration.
    Type: Grant
    Filed: February 20, 1980
    Date of Patent: March 10, 1981
    Assignee: Degussa Aktiengesellschaft
    Inventor: Rudolf Kropp
  • Patent number: 4011220
    Abstract: New pyridazinium compounds which can be used as intermediates and are of interest because of their pharmacological properties, and their production.
    Type: Grant
    Filed: March 8, 1976
    Date of Patent: March 8, 1977
    Assignee: BASF Aktiengesellschaft
    Inventors: Rudolf Kropp, Franz Reicheneder, August Amann, Hubert Giertz
  • Patent number: 4008073
    Abstract: Alloy powders suitable for the production of dental amalgams are prepared containing 75-92% silver, 8-23% copper, 1-10% tin and 0-2% zinc.
    Type: Grant
    Filed: November 18, 1975
    Date of Patent: February 15, 1977
    Assignee: Deutsche Gold- und Silber-Scheideanstalt vormals Roessler
    Inventor: Rudolf Kropp