Patents by Inventor Rui Imoto
Rui Imoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 12087952Abstract: Mesoporous carbon has a connecting structure in which primary particles made of carbon particles having primary pores with a primary pore diameter of less than 20 nm are connected. In the mesoporous carbon, the pore capacity of secondary pores with secondary pore diameters within a range of 20 nm to 100 nm, which is measured by a mercury intrusion method, is 0.42 cm3/g or more and 1.34 cm3/g or less. In addition, the mesoporous carbon has a linearity of 2.2 or more and 2.6 or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores in the mesoporous carbon. Furthermore, a catalyst layer includes the electrode catalyst for the fuel cell and a catalyst layer ionomer.Type: GrantFiled: March 28, 2022Date of Patent: September 10, 2024Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Naoki Hasegawa, Kazuhisa Yano, Tomohiro Takeshita, Rui Imoto, Kumiko Nomura, Noriyuki Kitao, Yunan Wang, Yuuki Kasama
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Publication number: 20240286902Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.Type: ApplicationFiled: May 8, 2024Publication date: August 29, 2024Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Naoki HASEGAWA, Kazuhisa YANO, Tomohiro TAKESHITA, Rui IMOTO, Kumiko NOMURA
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Publication number: 20240246826Abstract: [Problem] To provide a practical solid polymer fuel cell having high cell performance and excellent durability. [Means for solving] The polymer electrolyte fuel cell according to the present invention includes: a membrane electrode assembly in which electrodes each including a catalyst layer are joined to both surfaces of an electrolyte membrane; and a peroxide decomposition catalyst which is fixed to the electrolyte membrane and/or the electrodes and includes a hardly soluble carbide, a boride, and/or a silicide. The peroxide decomposition catalyst preferably contains a carbide, a boride and/or a silicide of a rare earth element, a transition metal element or a typical metal element.Type: ApplicationFiled: June 20, 2022Publication date: July 25, 2024Applicants: KABUSHIKI KAISHA TOYOTA CHUO KENKYUSHO, TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATIONInventors: Tomohiro TAKESHITA, Kazuhisa YANO, Rui IMOTO, Noriyuki KITAO, Kenji YAMAMOTO, Godai KITAYAMA
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Patent number: 12006216Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.Type: GrantFiled: November 25, 2020Date of Patent: June 11, 2024Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Naoki Hasegawa, Kazuhisa Yano, Tomohiro Takeshita, Rui Imoto, Kumiko Nomura
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Publication number: 20240006619Abstract: The present embodiment is a catalyst for a fuel cell including: a catalyst metal; and a carrier that supports the catalyst metal, in which an outer surface area of the carrier to an inner surface area of the carrier, which is a ratio between the inner and outer surface areas of the carrier, is 0.56 to 0.69, and a proportion of the catalyst metal supported on an outer surface of the carrier is 23% to 35%.Type: ApplicationFiled: June 14, 2023Publication date: January 4, 2024Inventors: Kumiko NOMURA, Rui IMOTO, Hidetoshi OKADA, Naoki HASEGAWA, Tomohiro TAKESHITA, Kazuhisa YANO, Kenji YAMAMOTO, Yuko MATSUMURA, Yuuki KASAMA
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Publication number: 20230343971Abstract: To provide a carbon support for catalysts for fuel cells, which increases the power generation performance of fuel cells, a catalyst for fuel cells, a catalyst layer for fuel cells, and a method for producing the carbon support. A carbon support for catalysts for fuel cells, wherein the carbon support includes at least one pore; wherein a thickness of a carbon wall of the carbon support, which is derived from a three-dimensional pore structure of a silica mold obtained by pore volume measurement of the silica mold by nitrogen adsorption analysis, is 3.3 nm or more and 11.2 nm or less; and wherein a carbon wall content is more than 60.3 ml/g and less than 190.8 ml/g.Type: ApplicationFiled: April 20, 2023Publication date: October 26, 2023Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, CATALER CORPORATIONInventors: Yunan WANG, Rui IMOTO, Kumiko NOMURA, Naoki HASEGAWA, Tomohiro TAKESHITA, Kazuhisa YANO, Hironobu NANBU, Yuuki KASAMA, Keisuke ASAKURA, Takanobu KUROKI, Hitohiko SATO, Tsubasa YONEUCHI, Akihiro HORI
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Publication number: 20230299308Abstract: Mesoporous carbon includes a linked structure in which carbon particles are linked. The carbon particles have primary pores and are primary particles. An average entrance diameter of the primary pores is 2.0 nm or more and 3.0 nm or less. An average constriction diameter of the primary pores is 1.6 nm or more and 2.4 nm or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores of the mesoporous carbon. A catalyst layer includes the electrode catalyst for a fuel cell and a catalyst layer ionomer.Type: ApplicationFiled: March 13, 2023Publication date: September 21, 2023Inventors: Naoki HASEGAWA, Kazuhisa YANO, Tomohiro TAKESHITA, Rui IMOTO, Kumiko NOMURA, Yunan WANG, Yuko MATSUMURA, Yuuki KASAMA
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Publication number: 20220320528Abstract: Mesoporous carbon has a connecting structure in which primary particles made of carbon particles having primary pores with a primary pore diameter of less than 20 nm are connected. In the mesoporous carbon, the pore capacity of secondary pores with secondary pore diameters within a range of 20 nm to 100 nm, which is measured by a mercury intrusion method, is 0.42 cm3/g or more and 1.34 cm3/g or less. In addition, the mesoporous carbon has a linearity of 2.2 or more and 2.6 or less. An electrode catalyst for a fuel cell includes the mesoporous carbon and catalyst particles supported in the primary pores in the mesoporous carbon. Furthermore, a catalyst layer includes the electrode catalyst for the fuel cell and a catalyst layer ionomer.Type: ApplicationFiled: March 28, 2022Publication date: October 6, 2022Inventors: Naoki HASEGAWA, Kazuhisa YANO, Tomohiro TAKESHITA, Rui IMOTO, Kumiko NOMURA, Noriyuki KITAO, Yunan WANG, Yuuki KASAMA
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Publication number: 20220119260Abstract: Porous carbon is produced by a method in which a carbon source and a pore-forming agent are added to spherical silica serving as a template, the carbon source is then polymerized and carbonized, and finally the spherical silica serving as a template is removed.Type: ApplicationFiled: September 13, 2021Publication date: April 21, 2022Inventors: Yunan WANG, Rui IMOTO, Tomohiro OHNISHI, Toshiyuki YOKOI
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Publication number: 20210163292Abstract: Mesoporous carbon has a beaded structure in which primary particles with mesopores are linked. In the mesoporous carbon, an average primary particle size is 7 nm or more and 300 nm or less, a pore diameter is 2 nm or more and 10 nm or less, an average thickness of pore walls is 3 nm or more and 15 nm or less, a pore volume is 0.2 mL/g or more and 3.0 mL/g or less, and a tap density is 0.03 g/cm3 or more and 0.3 g/cm3 or less. In a polymer electrolyte fuel cell, the mesoporous carbon is used as a catalyst carrier for at least an air electrode catalyst layer. The mesoporous carbon can be obtained by impregnating mesoporous silica satisfying a predetermined condition with a carbon source, performing polymerization and carbonization, and removing a template.Type: ApplicationFiled: November 25, 2020Publication date: June 3, 2021Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Naoki HASEGAWA, Kazuhisa YANO, Tomohiro TAKESHITA, Rui IMOTO, Kumiko NOMURA
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Publication number: 20200251748Abstract: The present invention provides a fuel cell catalyst that can demonstrate high activity during low loads and high loads. A fuel cell catalyst comprising a carbon support having fine pores, and a catalyst metal supported by the carbon support, wherein the carbon support has a mode diameter of mesopores in the range of 2.5 nm to 5.0 nm, a BET specific surface area in the range of 700 m2/g to 1300 m2/g, a median diameter of particle diameter in the range of 0.10 ?m to 0.50 ?m, and a crystallite size of (002) plane of carbon in the range of 5.0 nm to 12.0 nm.Type: ApplicationFiled: January 22, 2020Publication date: August 6, 2020Inventor: Rui IMOTO
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Patent number: 9498771Abstract: To provide an exhaust gas catalyst using a fired aluminum phosphate body with more excellent performance, and a method for producing it. (1) An exhaust gas purification catalyst including at least one platinum-group metal selected from the group consisting of Pt, Rh and Pd having a mean particle diameter of between 0.50 nm and 2.0 nm, supported on a tridymite-type fired aluminum phosphate body. (2) A method for producing an exhaust gas purification catalyst, including the steps of: firing aluminum phosphate obtained from an aqueous solution prepared to a pH of 3.5 to 4.5, at a temperature of between 1000° C. and 1200° C. for 2 hours or longer, to obtain a fired aluminum phosphate body, and supporting at least one type of platinum-group metal selected from the group consisting of Pt, Rh and Pd on the fired aluminum phosphate body.Type: GrantFiled: September 6, 2013Date of Patent: November 22, 2016Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Rui Imoto, Daichi Sato, Satoshi Nagao, Masaya Ibe
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Patent number: 9156027Abstract: An exhaust-gas catalyst carrier made of a composite of ?-alumina and a zirconia-titania solid solution, an exhaust-gas catalyst employing the exhaust-gas catalyst carrier, and a method of manufacturing the exhaust-gas catalyst carrier are provided.Type: GrantFiled: December 21, 2010Date of Patent: October 13, 2015Assignee: Toyota Jidosha Kabushiki KaishaInventor: Rui Imoto
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Publication number: 20150217280Abstract: To provide an exhaust gas catalyst using a fired aluminum phosphate body with more excellent performance, and a method for producing it. (1) An exhaust gas purification catalyst including at least one platinum-group metal selected from the group consisting of Pt, Rh and Pd having a mean particle diameter of between 0.50 nm and 2.0 nm, supported on a tridymite-type fired aluminum phosphate body. (2) A method for producing an exhaust gas purification catalyst, including the steps of: firing aluminum phosphate obtained from an aqueous solution prepared to a pH of 3.5 to 4.5, at a temperature of between 1000° C. and 1200° C. for 2 hours or longer, to obtain a fired aluminum phosphate body, and supporting at least one type of platinum-group metal selected from the group consisting of Pt, Rh and Pd on the fired aluminum phosphate body.Type: ApplicationFiled: September 6, 2013Publication date: August 6, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Rui Imoto, Daichi Sato, Satoshi Nagao, Masaya Ibe
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Publication number: 20150196899Abstract: An exhaust gas purification catalyst includes: a substrate; a first catalyst layer that is arranged on an upper surface of the substrate and contains a first support and platinum supported on the first support, in which the first support contains a composite oxide which is formed of oxygen and at least one element selected from the group consisting of aluminum, phosphorus and boron and has an oxygen 1s binding energy in a range of 530 eV to 535 eV; and a second catalyst layer that is arranged on an upper surface of the first catalyst layer and contains a second support and rhodium supported on the second support, in which the second support contains a less-thermally-deteriorative ceria-zirconia composite oxide or a porous alumina.Type: ApplicationFiled: January 2, 2015Publication date: July 16, 2015Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventor: Rui IMOTO
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Patent number: 9067193Abstract: An exhaust gas purifying catalyst, which is obtained by having at least one platinum group metal selected from the group consisting of Pt, Rh, and Pd supported on a calcined aluminum phosphate body. The calcined aluminum phosphate body has a tridymite crystal structure and the ratio of the cumulative pore distribution of pores having a size of 10 nm or less to the cumulative pore distribution of pores having a size of 300 nm or less is 20% or more in the calcined aluminum phosphate body. A method for producing an exhaust gas purifying catalyst including calcining aluminum phosphate, which has been obtained from an aqueous solution that is controlled to have a pH within a predetermined range, at a predetermined temperature for a predetermined period of time, thereby obtaining a calcined aluminum phosphate body; and having at least one platinum group metal selected from the group consisting of Pt, Rh, and Pd supported on the calcined aluminum phosphate body.Type: GrantFiled: December 18, 2012Date of Patent: June 30, 2015Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Satoshi Nagao, Rui Imoto, Daichi Sato, Yusaku Inatomi
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Publication number: 20140336042Abstract: An exhaust gas purifying catalyst, which is obtained by having at least one platinum group metal selected from the group consisting of Pt, Rh, and Pd supported on a calcined aluminum phosphate body. The calcined aluminum phosphate body has a tridymite crystal structure and the ratio of the cumulative pore distribution of pores having a size of 10 nm or less to the cumulative pore distribution of pores having a size of 300 nm or less is 20% or more in the calcined aluminum phosphate body. A method for producing an exhaust gas purifying catalyst including calcining aluminum phosphate, which has been obtained from an aqueous solution that is controlled to have a pH within a predetermined range, at a predetermined temperature for a predetermined period of time, thereby obtaining a calcined aluminum phosphate body; and having at least one platinum group metal selected from the group consisting of Pt, Rh, and Pd supported on the calcined aluminum phosphate body.Type: ApplicationFiled: December 18, 2012Publication date: November 13, 2014Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Satoshi Nagao, Rui Imoto, Daichi Sato, Yusaku Inatomi
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Publication number: 20120270730Abstract: An exhaust-gas catalyst carrier made of a composite of ?-alumina and a zirconia-titania solid solution, an exhaust-gas catalyst employing the exhaust-gas catalyst carrier, and a method of manufacturing the exhaust-gas catalyst carrier are provided.Type: ApplicationFiled: December 21, 2010Publication date: October 25, 2012Inventor: Rui Imoto
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Publication number: 20100307133Abstract: An exhaust gas control apparatus for an internal combustion engine includes a NOx adsorbent that is provided in an exhaust passage of an internal combustion engine, and that adsorbs nitrogen monoxide; an active oxygen supply device that supplies active oxygen to an area upstream of the NOx adsorbent; and a control portion that performs a first control that does not cause the active oxygen supply device to supply the active oxygen while exhaust gas flows to the NOx adsorbent at a time of cold start of the internal combustion engine, whereby the nitrogen monoxide is adsorbed by the NOx adsorbent, wherein the control portion performs a second control that causes the active oxygen supply device to supply the active oxygen after the first control is finished, whereby the nitrogen monoxide adsorbed by the NOx adsorbent is converted to a nitrate or a nitrate ion on the NOx adsorbent.Type: ApplicationFiled: June 3, 2010Publication date: December 9, 2010Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Masao Watanabe, Koutarou Hayashi, Youhei Kinoshita, Rui Imoto