Abstract: A bipolar plate, a fuel cell stack with the bipolar plate and a power generation system with the bipolar plate are provided. The bipolar plate includes a first polar plate and a second polar plate. The first polar plate includes a first side and a second side, and the second polar plate includes a third side and a fourth side. The first side of the first polar plate and the third side of the second polar plate have different flow fields. The bipolar plate further includes at least one synchronous undulation areas, which are the channels for the coolant to be introduced into and discharged out of the interlayer of the bipolar plate. The second polar plate is provided with a coolant diversion dike, which can guide the coolant to flow according to the preset route.