Patents by Inventor Russell D. Shupe

Russell D. Shupe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4886120
    Abstract: A process for removing residual oil from the near wellbore area of a subterranean formation adjacent an injection well of a waterflood operation to improve water injectivity comprising injection through said well into said area seawater containing a surfactant having the formula:RO(C.sub.3 H.sub.6 O).sub.7 (C.sub.2 H.sub.4 O).sub.2 YXwherein:R is a mixture of alkyl groups containing from 12 to 15 carbon atoms,Y is sulfate group, andX is a monovalent cation.After the treatment to improve water injectivity, the formation is waterflooded.
    Type: Grant
    Filed: February 1, 1989
    Date of Patent: December 12, 1989
    Assignee: Conoco Inc.
    Inventor: Russell D. Shupe
  • Patent number: 4269271
    Abstract: Many petroleum formations contain water having high salinity and/or high concentrations of divalent ions such as calcium or magnesium dissolved therein, and are additionally at temperatures from about 70.degree. F. to about 300.degree. F. Most surfactants suitable for use in oil recovery operations are either ineffective in high salinity or high hardness waters, or cannot tolerate the higher temperatures encountered in many such formations. A water-external phase emulsion, microemulsion or micellar dispersion containing a water soluble alkylpolyalkoxyalkylene sulfonate or alkylarylpolyalkoxyalkylene sulfonate and a water-insoluble polyethoxylated aliphatic alcohol (including alkanols) or polyethoxylated alkylphenol nonionic surfactant is an effective fluid for flooding in formations containing water whose salinity is from 70,000 to 220,000 parts per million total dissolved solids and also having temperatures as high as 300.degree. F.
    Type: Grant
    Filed: May 1, 1978
    Date of Patent: May 26, 1981
    Assignee: Texaco Inc.
    Inventors: Russell D. Shupe, Jim Maddox, Jr.
  • Patent number: 4175618
    Abstract: Thermal oil recovery processes employing the injection of steam and/or hot water for mobilizing viscous petroleum sweep only a small fraction of the formation between the wells because of override, underride, or channeling resulting in poor vertical conformance, as well as poor horizontal conformance of the swept portion of the formation. Both vertical and horizontal conformance are improved significantly if steam is injected into a formation until channeling has begun, after which steam injection is terminated and an aqueous fluid is injected into the formation, which has a viscosity essentially the same as water and contains an emulsifying agent capable of forming a viscous emulsion in the portions of the formation where override, underride or channeling has occurred. After a small slug of emulsifying fluid has been injected, steam injection is resumed and as a consequence of the emulsion plug, moves into portions of the formation from which oil would not be recovered if the emulsion had not been injected.
    Type: Grant
    Filed: May 10, 1978
    Date of Patent: November 27, 1979
    Assignee: Texaco Inc.
    Inventors: Ching H. Wu, Alfred Brown, Wilbur L. Hall, Russell D. Shupe
  • Patent number: 4088189
    Abstract: Many petroleum-containing formations contain high salinity and/or hard water and have temperatures from 150.degree. F. to 300.degree. F. Many surfactants known for oil recovery purposes may be used in either the high salinity or hard water, or in the presence of high temperature, but few surfactants or surfactant combinations are suitable for use in formations containing both high salinity water and temperatures much in excess of about 150.degree. F. An alkylpolyalkoxyalkyl sulfonate or alkylarylpolyalkoxyalkyl sulfonate, either as the sole constituent of an aqueous surfactant fluid, or as a solubilizing co-surfactant in combination with an anionic surfactant such as a petroleum sulfonate, an alkyl sulfonate, or an alkylaryl sulfonate, is effective for use in formations containing high salinity and/or hard water which are additionally at a temperature from about 70.degree.-300.degree. F.
    Type: Grant
    Filed: December 1, 1976
    Date of Patent: May 9, 1978
    Assignee: Texaco Inc.
    Inventor: Russell D. Shupe
  • Patent number: 4077471
    Abstract: Many petroleum formations contain water having high salinity and/or high concentrations of divalent ions such as calcium or magnesium dissolved therein, and are additionally at temperature from about 70.degree. F. to about 300.degree. F. Most surfactants suitable for use in oil recovery operations are either ineffective in high salinity or high hardness waters, or cannot tolerate the higher temperatures encountered in many such formations. An aqueous fluid containing a water soluble alkylpolyalkoxyalkyl sulfonate or alkylarylpolyalkoxyalkyl sulfonate and a water-insoluble polyethoxylated aliphatic alcohol or polyethoxylated alkylphenol nonionic surfactant is effective in formations containing water whose salinity is from 70,000 to 220,000 parts per million total dissolved solids and also having temperatures as high as 300.degree. F. The fluid is phase stable over a wide range of formation temperatures and water salinities and hardness values.
    Type: Grant
    Filed: December 1, 1976
    Date of Patent: March 7, 1978
    Assignee: Texaco Inc.
    Inventors: Russell D. Shupe, Jim Maddox, Jr.
  • Patent number: 4018278
    Abstract: Many petroleum formations contain water having excessive quantities of salt or divalent ions such as calcium or magnesium dissolved therein, and are additionally at a temperature from about 70.degree. to about 300.degree. F. Most surfactants otherwise usable for oil recovery operations are either ineffective in high salinity or hard water, or decompose or precipitate at the higher temperature encountered in formations. A sulfonated, ethoxylated alcohol or alkylphenol surfactant, either as the sole constituent of the surfactant solution, or as a co-surfactant with a more conventional anionic surfactant such as petroleum sulfonate, alkyl sulfonate, or alkylaryl sulfonate, is effective for use in formations containing water having substantial amounts of salt and/or divalent ion salts such as calcium or magnesium dissolved therein, and which additionally may be hotter than 120.degree. F.
    Type: Grant
    Filed: November 25, 1974
    Date of Patent: April 19, 1977
    Assignee: Texaco Inc.
    Inventor: Russell D. Shupe
  • Patent number: 3979315
    Abstract: Composition and method for the treatment of inorganic mineral scale, particularly calcium and/or barium sulfate scale, using a treating composition consisting of a water-soluble sulfonated ethoxylated alkylphenol of prescribed formula in an amount of from about 0.0005 to about 0.005%, on a weight basis.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: September 7, 1976
    Assignee: Texaco Inc.
    Inventors: Jack F. Tate, Russell D. Shupe, Jim Maddox, Jr.
  • Patent number: 3975282
    Abstract: Composition and method for the treatment of inorganic mineral scale particularly calcium and/or barium sulfate scale, using a treating composition consisting of a water-soluble sulfonated ethoxylated alcohol of prescribed formula in an amount of from about 0.0005% to about 0.005%, on a weight basis.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: August 17, 1976
    Assignee: Texaco Inc.
    Inventors: Jack F. Tate, Russell D. Shupe, Jim Maddox, Jr.
  • Patent number: 3946814
    Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation is stimulated by injecting into the formation an aqueous solution of a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to treatment by means of said compound results in a substantial improvement in hydrocarbon recovery.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: March 30, 1976
    Assignee: Texaco Inc.
    Inventors: Russell D. Shupe, Jim Maddox, Jr., Jack F. Tate
  • Patent number: 3946813
    Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation containing acid-soluble components, such as one composed at least in part of dolomite or limestone, is stimulated by injecting into the formation a composition comprising an aqueous solution of a mineral acid having dissolved therein a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to acidization by means of the said compound results in a substantial improvement in hydrocarbon recovery.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: March 30, 1976
    Assignee: Texaco Inc.
    Inventors: Jack F. Tate, Jim Maddox, Jr., Russell D. Shupe
  • Patent number: 3945438
    Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation containing acid-soluble components, such as one composed at least in part of dolomite or limestone, is stimulated by injecting into the formation a composition comprising an aqueous solution of a mineral acid having dissolved therein a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to acidization by means of the said compound results in a substantial improvement in hydrocarbon recovery.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: March 23, 1976
    Assignee: Texaco Inc.
    Inventors: Jack F. Tate, Jim Maddox, Jr., Russell D. Shupe
  • Patent number: 3945439
    Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation is stimulated by injecting into the formation an aqueous solution of a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to treatment by means of the compound results in the substantial improvement in hydrocarbon recovery.
    Type: Grant
    Filed: December 20, 1974
    Date of Patent: March 23, 1976
    Assignee: Texaco Inc.
    Inventors: Russell D. Shupe, Jim Maddox, Jr., Jack F. Tate