Patents by Inventor Russell D. Shupe
Russell D. Shupe has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4886120Abstract: A process for removing residual oil from the near wellbore area of a subterranean formation adjacent an injection well of a waterflood operation to improve water injectivity comprising injection through said well into said area seawater containing a surfactant having the formula:RO(C.sub.3 H.sub.6 O).sub.7 (C.sub.2 H.sub.4 O).sub.2 YXwherein:R is a mixture of alkyl groups containing from 12 to 15 carbon atoms,Y is sulfate group, andX is a monovalent cation.After the treatment to improve water injectivity, the formation is waterflooded.Type: GrantFiled: February 1, 1989Date of Patent: December 12, 1989Assignee: Conoco Inc.Inventor: Russell D. Shupe
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Patent number: 4269271Abstract: Many petroleum formations contain water having high salinity and/or high concentrations of divalent ions such as calcium or magnesium dissolved therein, and are additionally at temperatures from about 70.degree. F. to about 300.degree. F. Most surfactants suitable for use in oil recovery operations are either ineffective in high salinity or high hardness waters, or cannot tolerate the higher temperatures encountered in many such formations. A water-external phase emulsion, microemulsion or micellar dispersion containing a water soluble alkylpolyalkoxyalkylene sulfonate or alkylarylpolyalkoxyalkylene sulfonate and a water-insoluble polyethoxylated aliphatic alcohol (including alkanols) or polyethoxylated alkylphenol nonionic surfactant is an effective fluid for flooding in formations containing water whose salinity is from 70,000 to 220,000 parts per million total dissolved solids and also having temperatures as high as 300.degree. F.Type: GrantFiled: May 1, 1978Date of Patent: May 26, 1981Assignee: Texaco Inc.Inventors: Russell D. Shupe, Jim Maddox, Jr.
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Patent number: 4175618Abstract: Thermal oil recovery processes employing the injection of steam and/or hot water for mobilizing viscous petroleum sweep only a small fraction of the formation between the wells because of override, underride, or channeling resulting in poor vertical conformance, as well as poor horizontal conformance of the swept portion of the formation. Both vertical and horizontal conformance are improved significantly if steam is injected into a formation until channeling has begun, after which steam injection is terminated and an aqueous fluid is injected into the formation, which has a viscosity essentially the same as water and contains an emulsifying agent capable of forming a viscous emulsion in the portions of the formation where override, underride or channeling has occurred. After a small slug of emulsifying fluid has been injected, steam injection is resumed and as a consequence of the emulsion plug, moves into portions of the formation from which oil would not be recovered if the emulsion had not been injected.Type: GrantFiled: May 10, 1978Date of Patent: November 27, 1979Assignee: Texaco Inc.Inventors: Ching H. Wu, Alfred Brown, Wilbur L. Hall, Russell D. Shupe
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Surfactant oil recovery process usable in high temperature formations containing high salinity water
Patent number: 4088189Abstract: Many petroleum-containing formations contain high salinity and/or hard water and have temperatures from 150.degree. F. to 300.degree. F. Many surfactants known for oil recovery purposes may be used in either the high salinity or hard water, or in the presence of high temperature, but few surfactants or surfactant combinations are suitable for use in formations containing both high salinity water and temperatures much in excess of about 150.degree. F. An alkylpolyalkoxyalkyl sulfonate or alkylarylpolyalkoxyalkyl sulfonate, either as the sole constituent of an aqueous surfactant fluid, or as a solubilizing co-surfactant in combination with an anionic surfactant such as a petroleum sulfonate, an alkyl sulfonate, or an alkylaryl sulfonate, is effective for use in formations containing high salinity and/or hard water which are additionally at a temperature from about 70.degree.-300.degree. F.Type: GrantFiled: December 1, 1976Date of Patent: May 9, 1978Assignee: Texaco Inc.Inventor: Russell D. Shupe -
Patent number: 4077471Abstract: Many petroleum formations contain water having high salinity and/or high concentrations of divalent ions such as calcium or magnesium dissolved therein, and are additionally at temperature from about 70.degree. F. to about 300.degree. F. Most surfactants suitable for use in oil recovery operations are either ineffective in high salinity or high hardness waters, or cannot tolerate the higher temperatures encountered in many such formations. An aqueous fluid containing a water soluble alkylpolyalkoxyalkyl sulfonate or alkylarylpolyalkoxyalkyl sulfonate and a water-insoluble polyethoxylated aliphatic alcohol or polyethoxylated alkylphenol nonionic surfactant is effective in formations containing water whose salinity is from 70,000 to 220,000 parts per million total dissolved solids and also having temperatures as high as 300.degree. F. The fluid is phase stable over a wide range of formation temperatures and water salinities and hardness values.Type: GrantFiled: December 1, 1976Date of Patent: March 7, 1978Assignee: Texaco Inc.Inventors: Russell D. Shupe, Jim Maddox, Jr.
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Patent number: 4018278Abstract: Many petroleum formations contain water having excessive quantities of salt or divalent ions such as calcium or magnesium dissolved therein, and are additionally at a temperature from about 70.degree. to about 300.degree. F. Most surfactants otherwise usable for oil recovery operations are either ineffective in high salinity or hard water, or decompose or precipitate at the higher temperature encountered in formations. A sulfonated, ethoxylated alcohol or alkylphenol surfactant, either as the sole constituent of the surfactant solution, or as a co-surfactant with a more conventional anionic surfactant such as petroleum sulfonate, alkyl sulfonate, or alkylaryl sulfonate, is effective for use in formations containing water having substantial amounts of salt and/or divalent ion salts such as calcium or magnesium dissolved therein, and which additionally may be hotter than 120.degree. F.Type: GrantFiled: November 25, 1974Date of Patent: April 19, 1977Assignee: Texaco Inc.Inventor: Russell D. Shupe
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Patent number: 3979315Abstract: Composition and method for the treatment of inorganic mineral scale, particularly calcium and/or barium sulfate scale, using a treating composition consisting of a water-soluble sulfonated ethoxylated alkylphenol of prescribed formula in an amount of from about 0.0005 to about 0.005%, on a weight basis.Type: GrantFiled: December 20, 1974Date of Patent: September 7, 1976Assignee: Texaco Inc.Inventors: Jack F. Tate, Russell D. Shupe, Jim Maddox, Jr.
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Patent number: 3975282Abstract: Composition and method for the treatment of inorganic mineral scale particularly calcium and/or barium sulfate scale, using a treating composition consisting of a water-soluble sulfonated ethoxylated alcohol of prescribed formula in an amount of from about 0.0005% to about 0.005%, on a weight basis.Type: GrantFiled: December 20, 1974Date of Patent: August 17, 1976Assignee: Texaco Inc.Inventors: Jack F. Tate, Russell D. Shupe, Jim Maddox, Jr.
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Patent number: 3946814Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation is stimulated by injecting into the formation an aqueous solution of a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to treatment by means of said compound results in a substantial improvement in hydrocarbon recovery.Type: GrantFiled: December 20, 1974Date of Patent: March 30, 1976Assignee: Texaco Inc.Inventors: Russell D. Shupe, Jim Maddox, Jr., Jack F. Tate
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Patent number: 3946813Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation containing acid-soluble components, such as one composed at least in part of dolomite or limestone, is stimulated by injecting into the formation a composition comprising an aqueous solution of a mineral acid having dissolved therein a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to acidization by means of the said compound results in a substantial improvement in hydrocarbon recovery.Type: GrantFiled: December 20, 1974Date of Patent: March 30, 1976Assignee: Texaco Inc.Inventors: Jack F. Tate, Jim Maddox, Jr., Russell D. Shupe
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Patent number: 3945438Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation containing acid-soluble components, such as one composed at least in part of dolomite or limestone, is stimulated by injecting into the formation a composition comprising an aqueous solution of a mineral acid having dissolved therein a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to acidization by means of the said compound results in a substantial improvement in hydrocarbon recovery.Type: GrantFiled: December 20, 1974Date of Patent: March 23, 1976Assignee: Texaco Inc.Inventors: Jack F. Tate, Jim Maddox, Jr., Russell D. Shupe
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Patent number: 3945439Abstract: The production of hydrocarbons from a subterranean hydrocarbon-bearing formation is stimulated by injecting into the formation an aqueous solution of a compound hereinafter described. The elimination of plugging of capillary openings within the formation and mineral scale deposition on production equipment due to post-precipitation of dissolved salts subsequent to treatment by means of the compound results in the substantial improvement in hydrocarbon recovery.Type: GrantFiled: December 20, 1974Date of Patent: March 23, 1976Assignee: Texaco Inc.Inventors: Russell D. Shupe, Jim Maddox, Jr., Jack F. Tate