Abstract: A light-emitting polymer comprising a light-emitting repeat unit in a backbone of the polymer, wherein the polymer has an anisotropy of no more than 0.8 and wherein a transition dipole moment of the light-emitting repeat unit is aligned with the polymer backbone.

Abstract: A polymer comprising one or more optionally substituted repeat units of formula (I): (I) wherein each Ar1 independently represents a substituted or unsubstituted aromatic or heteroaromatic group; each Ar2 independently represents a substituted or unsubstituted aromatic or heteroaromatic group; n and m in each occurrence is at least 1; and R1 and R2 are substituents wherein R1 and R2 are different.

Abstract: An OLED comprising a hole-transporting layer and light-emitting layer wherein the hole-transporting layer comprises a hole-transporting polymer wherein no more than 5% of the polystyrene equivalent polymer weight measured by gel permeation chromatography consists of chains with weight of less than 50,000.

Abstract: A composition suitable for use in an organic light-emitting layer (103) of an organic light-emitting device having an anode (101) and a cathode (105), the composition comprising a fluorescent light-emitting material, a first triplet-accepting material and a second triplet-accepting material that is different from the first triplet-accepting material. The fluorescent light-emitting material may be a repeat unit of a light-emitting polymer, and the first and second triplet-accepting materials may independently be repeat units of the light-emitting polymer or may be mixed with the fluorescent light-emitting material.

Abstract: A composition comprising a first material substituted with at least one group of formula (I) and a second material substituted with at least one group selected from groups of formulae (IIa) and (IIb): wherein: Sp1 and Sp2 are spacer groups; NB independently in each occurrence is a norbornene group that may be unsubstituted or substituted with one or more substituents; n1 and n2 are 0 or 1; m1 is 1 if n1 is 0 and m1 is at least 1 if n1 is 1; m2 is 1 if n2 is 0 and m2 is at least 1 if n2 is 1; Ar1 represents an aryl or heteroaryl group; R1 independently in each occurrence is H or a substituent; and * represents a point of attachment to the first or second material. The composition may be used to form a layer of an organic electronic device, for example the hole-transporting layer of an organic light-emitting device.

Abstract: Methods of metal-catalysed polymerisation are described using a metal catalyst of formula (III): wherein R3 in each occurrence is independently selected from C1-10 alkyl and aryl that may be unsubstituted or substituted with one or more substituents; y is 0 or 2; and Z?is an anion. Methods described include Buchwald-type and Suzuki-type polymerisation.

Abstract: Methods of metal-catalyzed polymerization are described using a metal catalyst of formula (III): wherein R3 in each occurrence is independently selected from C1-10alkyl and aryl that may be unsubstituted or substituted with one or more substituents; y is 0 or 2; and Z? is an anion. Methods described include Buchwald-type and Suzuki-type polymerization.

Abstract: A block copolymer comprising a first block and a second block wherein the first block comprises a repeat unit of formula (I) and the second block comprises a repeat unit of formula (II): wherein R1 and R2 are independently H or a substituent; R3 independently in each occurrence is a substituent; each n is independently 0, 1, 2 or 3; Ar8, Ar9 and Ar10 independently in each occurrence is an aryl or heteroaryl group that may be unsubstituted or substituted with one or more substituents; R13 independently in each occurrence is a substituent; c, d and e are each independently at least 1; and g is 0 or a positive integer. The block copolymer may be used as a light-emitting material in an organic light-emitting device.

Abstract: An OLED comprising a hole-transporting layer and light-emitting layer wherein the hole-transporting layer comprises a hole-transporting polymer wherein no more than 5% of the polystyrene equivalent polymer weight measured by gel permeation chromatography consists of chains with weight of less than 50,000.

Abstract: A copolymer comprising a repeat unit of Formula (I) and at least one further repeat unit: Formula (I) wherein: wherein: Ar1 and Ar2 are each independently selected from aryl and heteroaryl, each of which is independently unsubstituted or substituted with one or more substituents; each R is independently a substituent; each n is independently 0, 1 or 2; each m is independently 0, 1, 2 or 3, and at least one of the repeat units of the polymer is a partially conjugating repeat unit.

Abstract: Methods of metal-catalysed polymerisation are described using a metal catalyst of formula (III): wherein R3 in each occurrence is independently selected from C1-10alkyl and aryl that may be unsubstituted or substituted with one or more substituents; y is 0 or 2; and Z? is an anion. Methods described include Buchwald-type and Suzuki-type polymerisation.

Abstract: A polymer compound is provided having constitutional units of formula (1) and formula (2), and a constitutional unit of formula (3) and/or (4?): wherein Ar1 to Ar4, Ar20, Ar30? and Ar40 represent arylene groups or the like; Ar5 to Ar7 represent aryl groups or the like; Ar8 represents (2+p)-valent aromatic hydrocarbon group or the like; Ar10 represents (2+n)-valent aromatic hydrocarbon group or the like; R1 represents alkyl group or the like; La, Lb, Lg and Lh represent alkylene groups or the like; LA and LD represent oxygen atoms or the like; Q1 represents monovalent crosslinkable group; Q2? to Q4? represent monovalent crosslinkable groups or the like; x, y, c, nA and nD represent 0 or 1; p represents integer of 1 or greater.; na and ng represent integer of 0 to 3; nb and nh represent integer of 0 to 12; and n represents integer of 1 to 4.

Abstract: An organic electronic device comprising an anode, a cathode, a semiconducting layer between the anode and the cathode and a hole transporting layer between the anode and the semiconducting layer, the hole-transporting layer comprising a co-polymer comprising repeat units of formula (I) and one or more co-repeat units: (I) wherein: Ar1 independently in each occurrence represents a fused aryl or fused heteroaryl group that may be unsubstituted or substituted with one or more substituents; Ar2 represents an aryl or heteroaryl group that may be unsubstituted or substituted with one or more substituents; R independently in each occurrence represents a substituent; and m is 1 or 2, preferably 1; and each Ar1 is directly bound to an aromatic or heteroaromatic group of a co-repeat unit.

Abstract: A polymer comprising one or more optionally substituted repeat units of formula (I): (I) wherein each Ar1 independently represents a substituted or unsubstituted aromatic or heteroaromatic group; each Ar2 independently represents a substituted or unsubstituted aromatic or heteroaromatic group; n and m in each occurrence is at least 1; and R1 and R2 are substituents wherein R1 and R2 are different.

Abstract: Composition comprising a fluorescent light-emitting material and a triplet-accepting unit comprising an optionally substituted compound of formula (I): The composition may be used in an organic light-emitting device; the optionally substituted compound of formula (I) may be blended with or attached to the fluorescent light emitting material; and the composition may be deposited by solution deposition.