Abstract: Methods for preparing an aluminum alloy sheet product for adhesive bonding are disclosed. A method may include preparing an aluminum alloy product for roll coating and roll coating an aqueous functionalization solution onto the prepared aluminum alloy product. For the roll coating step, the aqueous functionalization solution may include from 0.1 to 5.0 wt. % of active ingredients. The active ingredients may include a first monomer component and a second polymer component. The amount of second polymer component in the aqueous functionalization solution may be greater than an amount of the first monomer component in the aqueous functionalization solution.

Abstract: Metallic substrate treatment methods and articles comprising a phosphonate functionalized layer are provided. The method comprises contacting a metallic substrate comprising at least one of aluminum and an aluminum alloy with a fluid to form a phosphonate functionalized layer on at least a region of the metallic substrate. The fluid comprises at least one of a phosphonate containing acid and a derivative thereof. At least one of the phosphonate containing acid and the derivative thereof comprises a pKa of a first acidic proton. The fluid comprises a pH at least 0.5 pH value greater than the pKa of the first acidic proton. The article comprises a metallic substrate comprising aluminum or an aluminum alloy and a phosphonate functionalized layer on at least a region of the metallic substrate.

Abstract: Metallic substrate treatment methods and articles comprising a phosphonate functionalized layer are provided. The method comprises contacting a metallic substrate comprising at least one of aluminum and an aluminum alloy with a fluid to form a phosphonate functionalized layer on at least a region of the metallic substrate. The fluid comprises at least one of a phosphonate containing acid and a derivative thereof. At least one of the phosphonate containing acid and the derivative thereof comprises a pKa of a first acidic proton. The fluid comprises a pH at least 0.5 pH value greater than the pKa of the first acidic proton. The article comprises a metallic substrate comprising aluminum or an aluminum alloy and a phosphonate functionalized layer on at least a region of the metallic substrate.

Abstract: Metallic substrate treatment methods and articles comprising a phosphonate functionalized layer are provided. The method comprises contacting a metallic substrate comprising at least one of aluminum and an aluminum alloy with a fluid to form a phosphonate functionalized layer on at least a region of the metallic substrate. The fluid comprises at least one of a phosphonate containing acid and a derivative thereof. At least one of the phosphonate containing acid and the derivative thereof comprises a pKa of a first acidic proton. The fluid comprises a pH at least 0.5 pH value greater than the pKa of the first acidic proton. The article comprises a metallic substrate comprising aluminum or an aluminum alloy and a phosphonate functionalized layer on at least a region of the metallic substrate.

Abstract: Methods for preparing an aluminum alloy sheet product for adhesive bonding are disclosed. A method may include preparing an aluminum alloy product for roll coating and roll coating an aqueous functionalization solution onto the prepared aluminum alloy product. For the roll coating step, the aqueous functionalization solution may include from 0.1 to 5.0 wt. % of active ingredients. The active ingredients may include a first monomer component and a second polymer component. The amount of second polymer component in the aqueous functionalization solution may be greater than an amount of the first monomer component in the aqueous functionalization solution.