Patents by Inventor Ryuichi Kuzuo

Ryuichi Kuzuo has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20180287147
    Abstract: Provided is a coated nickel hydroxide powder that is obtained by forming a coating mainly containing cobalt oxyhydroxide on the surface of particles of a nickel hydroxide powder so that the uniformity and adhesion properties of the coating are ensured, and is therefore suitable for a positive electrode active material of alkaline secondary battery. The pH of a suspension of a nickel hydroxide powder is kept at 8 to 11.5, and an aqueous cobalt salt solution and an aqueous alkali, solution are supplied to the suspension while the ratio of the supply rate ? of the aqueous cobalt salt solution to the product of the supply width d of the aqueous cobalt salt solution in a direction orthogonal to the flow direction of the suspension and the flow velocity v of the suspension in a contact portion between the suspension and the aqueous cobalt salt solution, that is, ?/(d×v) is controlled to be 3.8×10?4 mol/cm2 or less to coat the surface of nickel hydroxide particles with cobalt hydroxide.
    Type: Application
    Filed: May 31, 2018
    Publication date: October 4, 2018
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Katsuya Kase, Ryuichi Kuzuo, Minoru Shiraoka, Hideo Sasaoka
  • Patent number: 10020498
    Abstract: A method for producing coated nickel hydroxide powder for a positive electrode of an alkaline secondary battery wherein the pH of a suspension of a nickel hydroxide powder is kept at 8 to 11.5, and an aqueous cobalt salt solution and an aqueous alkali solution are supplied to the suspension to coat the surface of nickel hydroxide particles with cobalt hydroxide. Then, the pH of a slurry of the cobalt hydroxide-coated nickel hydroxide powder is adjusted to 12.5 to 13.0, and oxygen is supplied to the slurry so that the total amount of oxygen supplied per mole of cobalt in the coating is 30 l/mol or more to oxidize the cobalt hydroxide.
    Type: Grant
    Filed: October 12, 2013
    Date of Patent: July 10, 2018
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Katsuya Kase, Ryuichi Kuzuo, Minoru Shiraoka, Hideo Sasaoka
  • Patent number: 9768444
    Abstract: A coated nickel hydroxide powder that has a cobalt compound coating having improved uniformity and adhesion properties on the surface of particles thereof and is therefore suitable for a positive electrode active material of an alkaline secondary battery is obtained by coating the surface of nickel hydroxide particles with a cobalt compound, and has a transmittance ratio of 30% or higher as determined by (A?Bmax)/(B0?Bmax). The transmittance A (coated nickel hydroxide powder), the transmittance B0 (nickel hydroxide powder), or the transmittance Bmax (nickel hydroxide powder and cobalt compound containing cobalt in an amount corresponding to the amount of cobalt contained in the coating) can be determined by measuring the transmittance of a tubular transparent cell after shaking the tightly-closed transparent cell containing each powder for a certain time and then taking the contents out of the transparent cell.
    Type: Grant
    Filed: October 12, 2013
    Date of Patent: September 19, 2017
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Katsuya Kase, Ryuichi Kuzuo, Minoru Shiraoka, Hideo Sasaoka
  • Patent number: 9553311
    Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery capable of obtaining high initial discharge capacity and good output characteristics at low temperature. In order to achieve this, a cathode active material that is a lithium nickel composite oxide composed of secondary particles that are an aggregate of primary particles is expressed by the general expression: Liw(Ni1-x-yCoxAly)1-zMzO2 (where 0.98?w?1.10, 0.05?x?0.3, 0.01?y?0.1, 0?z?0.05, and M is at least one metal element selected from a group consisting of Mg, Fe, Cu, Zn and Ga), and where the crystallite diameter at (003) plane of that lithium nickel composite oxide that is found by X-ray diffraction and the Scherrer equation is within the range of 1200 ? to 1600 ? is used as the cathode material.
    Type: Grant
    Filed: December 9, 2014
    Date of Patent: January 24, 2017
    Assignees: SUMITOMO METAL MINING CO., LTD, TOYOTA JIDOSHA KABUSHIKI KAISHA
    Inventors: Katsuya Kase, Syuhei Oda, Ryuichi Kuzuo, Yutaka Oyama
  • Publication number: 20150295231
    Abstract: Provided are a coated nickel hydroxide powder that has a cobalt compound coating having improved uniformity and adhesion properties on the surface of particles thereof and is therefore suitable for use as a positive electrode active material of alkaline secondary battery, and an evaluation method for the adhesion properties of the coating. The coated nickel hydroxide powder for a positive electrode active material of alkaline secondary battery is obtained by coating the surface of nickel hydroxide particles with a cobalt compound, and has a. transmittance ratio of 30% or higher as determined by (A?Bmax)/(B0?Bmax).
    Type: Application
    Filed: October 12, 2013
    Publication date: October 15, 2015
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Katsuya Kase, Ryuichi Kuzuo, Minoru Shiraoka, Hideo Sasaoka
  • Publication number: 20150280224
    Abstract: Provided is a coated nickel hydroxide powder that is obtained by forming a coating mainly containing cobalt oxyhydroxide on the surface of particles of a nickel hydroxide powder so that the uniformity and adhesion properties of the coating are ensured, and is therefore suitable for a positive electrode active material of alkaline secondary battery. The pH of a suspension of a nickel hydroxide powder is kept at 8 to 11.5, and an aqueous cobalt salt solution and an aqueous alkali solution are supplied to the suspension while the ratio of the supply rate ? of the aqueous cobalt salt solution to the product of the supply width d of the aqueous cobalt salt solution in a direction orthogonal to the flow direction of the suspension and the flow velocity v of the suspension in a contact portion between the suspension and the aqueous cobalt salt solution, that is, ?/(d×v) is controlled to be 3.5×10?4 mol/cm2 or less to coat the surface of nickel hydroxide particles with cobalt hydroxide.
    Type: Application
    Filed: October 12, 2013
    Publication date: October 1, 2015
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Katsuya Kase, Ryuichi Kuzuo, Minoru Shiraoka, Hideo Sasaoka
  • Patent number: 9059461
    Abstract: A coated nickel hydroxide powder suitable as a cathode active material for alkaline secondary battery includes nickel hydroxide powder particles which have a coating layer thereon of preferably cobalt hydroxide or cobalt oxyhydroxide.
    Type: Grant
    Filed: October 2, 2013
    Date of Patent: June 16, 2015
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Ryuichi Kuzuo, Minoru Shiraoka
  • Patent number: 9023531
    Abstract: Disclosed is a nonaqueous secondary battery (100) comprising a positive electrode (155) having a positive current collector (151) made of a metal, and a positive electrode active material (153) composed of a lithium-metal complex oxide. The surface of the positive electrode active material (153) is coated with a lithium salt (158) having an average thickness of 20-50 nm.
    Type: Grant
    Filed: October 17, 2008
    Date of Patent: May 5, 2015
    Assignees: Toyota Jidosha Kabushiki Kaisha, Sumitomo Metal Mining Co., Ltd.
    Inventors: Tomoyoshi Ueki, Yutaka Oyama, Takuichi Arai, Kazuhiro Ohkawa, Koichi Yokoyama, Ryuichi Kuzuo, Katsuya Kase, Syuhei Oda
  • Publication number: 20150108398
    Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery capable of obtaining high initial discharge capacity and good output characteristics at low temperature. In order to achieve this, a cathode active material that is a lithium nickel composite oxide composed of secondary particles that are an aggregate of primary particles is expressed by the general expression: Liw(Ni1-x-yCoxAly)1-zMzO2 (where 0.98?w?1.10, 0.05?x?0.3, 0.01?y?0.1, 0?z?0.05, and M is at least one metal element selected from a group consisting of Mg, Fe, Cu, Zn and Ga), and where the crystallite diameter at (003) plane of that lithium nickel composite oxide that is found by X-ray diffraction and the Scherrer equation is within the range of 1200 ? to 1600 ? is used as the cathode material.
    Type: Application
    Filed: December 9, 2014
    Publication date: April 23, 2015
    Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, SUMITOMO METAL MINING CO., LTD.
    Inventors: Katsuya KASE, Syuhei ODA, Ryuichi KUZUO, Yutaka OYAMA
  • Patent number: 8999573
    Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery capable of obtaining high initial discharge capacity and good output characteristics at low temperature. In order to achieve this, a cathode active material that is a lithium nickel composite oxide composed of secondary particles that are an aggregate of primary particles is expressed by the general expression: Liw(Ni1-x-yCoxAly)1-zMzO2 (where 0.98?w?1.10, 0.05?x?0.3, 0.01?y?0.1, 0?z?0.05, and M is at least one metal element selected from a group consisting of Mg, Fe, Cu, Zn and Ga), and where the crystallite diameter at (003) plane of that lithium nickel composite oxide that is found by X-ray diffraction and the Scherrer equation is within the range of 1200 {acute over (?)} to 1600 {acute over (?)} is used as the cathode material.
    Type: Grant
    Filed: March 24, 2011
    Date of Patent: April 7, 2015
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Katsuya Kase, Syuhei Oda, Ryuichi Kuzuo, Yutaka Oyama
  • Publication number: 20140106227
    Abstract: A coated nickel hydroxide powder suitable as a cathode active material for alkaline secondary battery includes nickel hydroxide powder particles which have a coating layer thereon of preferably cobalt hydroxide or cobalt oxyhydroxide.
    Type: Application
    Filed: October 2, 2013
    Publication date: April 17, 2014
    Applicant: SUMITOMO METAL MINING CO., LTD.
    Inventors: Ryuichi KUZUO, Minoru Shiraoka
  • Patent number: 8603677
    Abstract: A method for producing a coated nickel hydroxide powder suitable as a cathode active material for alkaline secondary battery includes the steps of: dispersing a nickel hydroxide powder in water to prepare a suspension, an aqueous alkali solution to the suspension with stirring to keep a pH of the suspension at 8 or higher as measured at 25° C., and supplying an aqueous cobalt salt solution to the suspension to coat a surface of each particles of the nickel hydroxide powder with cobalt hydroxide crystallized out by neutralization.
    Type: Grant
    Filed: January 23, 2012
    Date of Patent: December 10, 2013
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Ryuichi Kuzuo, Minoru Shiraoka
  • Publication number: 20130108921
    Abstract: Provided is a cathode active material for a non-aqueous electrolyte secondary battery capable of obtaining high initial discharge capacity and good output characteristics at low temperature. In order to achieve this, a cathode active material that is a lithium nickel composite oxide composed of secondary particles that are an aggregate of primary particles is expressed by the general expression: Liw(Ni1-x-yCoxAly)1-zMzO2 (where 0.98?w?1.10, 0.05?x?0.3, 0.01?y?0.1, 0?z?0.05, and M is at least one metal element selected from a group consisting of Mg, Fe, Cu, Zn and Ga), and where the crystallite diameter at (003) plane of that lithium nickel composite oxide that is found by X-ray diffraction and the Scherrer equation is within the range of 1200 {acute over (?)} to 1600 {acute over (?)} is used as the cathode material.
    Type: Application
    Filed: March 24, 2011
    Publication date: May 2, 2013
    Inventors: Katsuya Kase, Syuhei Oda, Ryuichi Kuzuo, Yutaka Oyama
  • Publication number: 20120276453
    Abstract: A method for producing a coated nickel hydroxide powder suitable as a cathode active material for alkaline secondary battery includes the steps of: dispersing a nickel hydroxide powder in water to prepare a suspension, an aqueous alkali solution to the suspension with stirring to keep a pH of the suspension at 8 or higher as measured at 25° C., and supplying an aqueous cobalt salt solution to the suspension to coat a surface of each of particles of the nickel hydroxide powder with cobalt hydroxide crystallized out by neutralization.
    Type: Application
    Filed: January 23, 2012
    Publication date: November 1, 2012
    Inventors: Ryuichi KUZUO, Minoru Shiraoka
  • Publication number: 20100221613
    Abstract: Disclosed is a nonaqueous secondary battery (100) comprising a positive electrode (155) having a positive current collector (151) made of a metal, and a positive electrode active material (153) composed of a lithium-metal complex oxide. The surface of the positive electrode active material (153) is coated with a lithium salt (158) having an average thickness of 20-50 nm.
    Type: Application
    Filed: October 17, 2008
    Publication date: September 2, 2010
    Inventors: Tomoyoshi Ueki, Yutaka Oyama, Takuichi Arai, Kazuhiro Ohkawa, Koichi Yokoyama, Ryuichi Kuzuo, Katsuya Kase, Syuhei Oda
  • Patent number: 7604899
    Abstract: To provide a positive electrode active material for a non-aqueous electrolyte secondary battery, which if used as a positive electrode for a lithium ion secondary battery, the battery internal resistance can be reduced, giving a secondary battery superior in output characteristics and life property. After mixing raw material powders in specified quantities of each so as to become a lithium-metal complex oxide represented by LizNi1-wMwO2 (wherein M is at least one kind or more of metal elements selected from the group consisting of Co, Al, Mg, Mn, Ti, Fe, Cu, Zn, and Ga; and w and z respectively satisfy 0<w?0.25, and 1.0?z?1.1), baking is performed in two stages. At first the temperature is raised from room temperature to a first stage baking temperature (450 to 550° C.) at a temperature rise rate of 0.5 and 15° C./min, and held for 1 to 10 hours. Then the temperature is raised to a second stage baking temperature (650 to 800° C.), and held for 0.6 to 30 hours.
    Type: Grant
    Filed: March 22, 2007
    Date of Patent: October 20, 2009
    Assignees: Sumito Metal Mining Co., Ltd., Toyota Jidosha Kabushiki Kaisha, Denso Corporation
    Inventors: Syuuhei Oda, Ryuichi Kuzuo, Tomoyoshi Ueki, Satoru Suzuki, Manabu Yamada
  • Publication number: 20090081550
    Abstract: To curb a decline in the high-rate performance of non-aqueous electrolyte secondary batteries and improve safety at the time of an internal short circuit, a non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, a separator, and a non-aqueous electrolyte wherein the positive electrode includes a positive electrode active material capable of absorbing and desorbing lithium ions, the positive electrode active material includes a secondary particle, and the secondary particle is an aggregate containing primary particles and a silicon oxide. The primary particles contain a lithium nickel composite oxide. The silicon oxide is present in at least grain boundaries between the primary particles.
    Type: Application
    Filed: September 16, 2008
    Publication date: March 26, 2009
    Inventors: Toshihiro INOUE, Ryuichi Kuzuo, Hideo Sasaoka
  • Publication number: 20070248883
    Abstract: To provide a positive electrode active material for a non-aqueous electrolyte secondary battery, which if used as a positive electrode for a lithium ion secondary battery, the battery internal resistance can be reduced, giving a secondary battery superior in output characteristics and life property. After mixing raw material powders in specified quantities of each so as to become a lithium-metal complex oxide represented by LizNi1-wMwO2 (wherein M is at least one kind or more of metal elements selected from the group consisting of Co, Al, Mg, Mn, Ti, Fe, Cu, Zn, and Ga; and w and z respectively satisfy 0<w?0.25, and 1.0?z?1.1), baking is performed in two stages. At first the temperature is raised from room temperature to a first stage baking temperature (450 to 550° C.) at a temperature rise rate of 0.5 and 15° C./min, and held for 1 to 10 hours. Then the temperature is raised to a second stage baking temperature (650 to 800° C.), and held for 0.6 to 30 hours.
    Type: Application
    Filed: March 22, 2007
    Publication date: October 25, 2007
    Inventors: Syuuhei Oda, Ryuichi Kuzuo, Tomoyoshi Ueki, Satoru Suzuki, Manabu Yamada
  • Patent number: 5006388
    Abstract: Disclosed are magnetic discs having (A) a Cr-layer, as a lower layer, which has a composition comprising (1) substantially Cr or (2) 10% by weight or less of one or more selected from Cu, Nb, Ti, V, Zr, Mo, Zn, W and Ta, and a balance of being substantially Cr, and (B) a magnetic recording medium layer, as an upper layer, which has a composition comprising (1) substantially Co, (2) 30% by weight or less of Ni and a balance of being substantially Co, (3) 10% by weight or less of one or more selected from Y, La, Ce, Pr, Nd, Sm, Gd, Tb and Dy, and a balance of being substantially Co, (4) 30% by weight or less of Ni, 10% by weight or less of one or more selected from Y, La, Ce, Pr, Nd, Sm, Gd, Tb and Dy, and a balance of being substantially Co, (5) 10% by weight or less of one or more selected from Cu, Nb, Ti, V, Cr, Zr, Mo, Zn, W and Ta, and a balance of being substantially Co, (6) 30% by weight or less of Ni, 10% by weight or less of one or more selected from Cu, Nb, Ti, V, Cr, Zr, Mo, Zn, W and Ta, and a balan
    Type: Grant
    Filed: August 3, 1988
    Date of Patent: April 9, 1991
    Assignee: Sumitomo Metal Mining Company Limited
    Inventors: Ryuichi Kuzuo, Atsushi Kawamoto, Junya Tada, Kenji Ohmori, Hiroko Sekiya