Abstract: A process for the epoxidation of propene involves reacting propene with hydrogen peroxide, in the presence of a methanol solvent and a shaped titanium zeolite epoxidation catalyst in a fixed bed reactor. The process then involves recovering methanol from the reaction mixture, treatment of the recovered methanol by passing it through a bed of an acidic ion exchange resin, and recycling the treated methanol to the epoxidation reaction; as well as regeneration of the acidic ion exchange resin. Catalyst breakage can be reduced or avoided by washing the regenerated bed of an acidic ion exchange resin with methanol until the methanol exiting the resin bed has an apparent pH higher than 1.8, before methanol treated with the acidic ion exchange resin is recycled to the epoxidation reaction.

Abstract: A process for making propene oxide involves reacting propene with hydrogen peroxide in the presence of methanol, a titanium zeolite epoxidation catalyst, and nitrogen containing compounds present in an amount of from 100 to 3000 mg/kg of hydrogen peroxide. Non-reacted propene is separated from the reaction mixture; the propene depleted reaction mixture is continuously distilled in a distillation column providing an overhead product stream containing propene oxide and methanol and a bottoms product stream; and propene oxide is separated from the overhead product stream. An acid is added to the propane depleted reaction mixture and/or to the distillation column at the same level or above the feed point for the propene depleted reaction mixture and/or contacted to the feed to the distillation column to provide an apparent pH in the bottoms product stream of from 3 to 4.5, which reduces the nitrogen content of the separated propene oxide.

Abstract: A process for making propene oxide involves reacting propene with hydrogen peroxide in the presence of methanol, a titanium zeolite epoxidation catalyst, and nitrogen containing compounds present in an amount of from 100 to 3000 mg/kg of hydrogen peroxide. Non-reacted propene is separated from the reaction mixture; the propene depleted reaction mixture Is continuously distilled in a distillation column providing an overhead product stream containing propene oxide and methanol and a bottoms product stream; and propene oxide is separated from the overhead product stream. An acid is added to the propane depleted reaction mixture and/or to the distillation column at the same level or above the feed point for the propene depleted reaction mixture and/or contacted to the feed to the distillation column to provide an apparent pH in the bottoms product stream of from 3 to 4.5, which reduces the nitrogen content of the separated propene oxide.

Abstract: An apparatus for synthesizing hydrogen chloride from chlorine and hydrogen or from chlorine and hydrocarbons with integrated heat recovery. The combustion chamber and the heat exchanger are arranged in the steam drum of a shell boiler that works according to the waste heat boiler principle.

Abstract: A device for burning a fuel/oxidant mixture in a strongly exothermic reaction, consists of a reactor with a combustion chamber containing at least one first porous material and at least one second porous material in separate zones A and C. The zones are designed in such a way that an exothermic reaction can only occur in zone B, and with one or more feed lines for the fuel and for the oxidant, whereby zone A, which consists of the first porous material, is separated by a distance of approximately 10 mm to 4000 mm, for example approximately 20 mm to 500 mm, equating to one zone B, from zone C which consists of the second porous material and is located before zone C in a flow direction of the fuel/oxidant mixture.

Abstract: An apparatus for synthesizing hydrogen chloride from chlorine and hydrogen or from chlorine and hydrocarbons with integrated heat recovery. The combustion chamber and the heat exchanger are arranged in the steam drum of a shell boiler that works according to the waste heat boiler principle.

Abstract: A device for burning a fuel/oxidant mixture in a strongly exothermic reaction, consists of a reactor with a combustion chamber containing at least one first porous material and at least one second porous material in separate zones A and C. The zones are designed in such a way that an exothermic reaction can only occur in zone B, and with one or more feed lines for the fuel and for the oxidant, whereby zone A, which consists of the first porous material, is separated by a distance of approximately 10 mm to 4000 mm, for example approximately 20 mm to 500 mm, equating to one zone B, from zone C which consists of the second porous material and is located before zone C in a flow direction of the fuel/oxidant mixture.