Patents by Inventor Sachio Asaoka

Sachio Asaoka has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4950824
    Abstract: A process for the production of 2,6-diisopropylnaphthalene is disclosed wherein an isopropylation reaction mixture containing isopropylated naphthalenes is subjected to transalkylation with a triisopropylnaphthalene-containing mixture to obtain a mixture containing mono-, di- and tri-isopropylnaphthalenes which is then separated into a first fraction containing monisopropylnaphthalenes, a second fraction containing diisopropylnaphthalenes and a third fraction containing triisopropylnaphthalenes. The first and third fractions are recycled to the above system, while the second fraction is subjected to separation treatments for the recovery of 2,6-diisopropylnaphthalene. The second fraction from which 2,6-diisopropylnaphthalene has been removed is subjected to transalkylation with naphthalene to obtain a monoisopropylnaphthalene-rich mixture which is to be fed to the isopropylation step.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: August 21, 1990
    Assignees: Chiyoda Corporation, NKK Corporation
    Inventors: Yoshimi Shiroto, Mitsunori Shimura, Kenji Shimokawa, Yoshio Fukui, Sachio Asaoka, Hiroto Tajima, Kazuaki Ueda, Yakudo Tachibana, Kazuhiko Tate, Hiroaki Taniguchi
  • Patent number: 4562059
    Abstract: An improved method of preparing alumina, including a first stage in which an alumina hydrogel is formed from seed aluminum hydroxide, and a second stage in which the alumina hydrogel is processed for conversion into alumina.
    Type: Grant
    Filed: June 8, 1984
    Date of Patent: December 31, 1985
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Sachio Asaoka, Takashi Sendo, Munekazu Nakamura
  • Patent number: 4555394
    Abstract: An improved process for the preparation of alumina, including forming an alumina hydrogel from aluminum hydroxide, and processing the alumina hydrogel into alumina. The improvement involves the alumina hydrogel forming step which is connected in the presence of sulfate ion and which comprises providing, in a reaction zone, an aqueous slurry containing seed aluminum hydroxide and having a pH of 6-11, and feeding to the reaction zone an aluminum compound and a pH controlling agent for mixing with the aqueous slurry while maintaining the aqueous slurry at a temperature of at least about 50.degree. C. at feed rates so that the pH of the aqueous slurry is maintained within the range of 6-11 and that 0.2-5 mols/hour of aluminum components, in terms of elemental aluminum, are fed to the reaction zone per mole of the seed aluminum hydroxide originally contained in the aqueous slurry, whereby the seed aluminum hydroxide is caused to grow to the aluminum hydrogel.
    Type: Grant
    Filed: June 1, 1984
    Date of Patent: November 26, 1985
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Sachio Asaoka, Takashi Sendo
  • Patent number: 4444655
    Abstract: A catalyst for hydrotreating a heavy hydrocarbon oil containing asphaltenes comprises a porous carrier composed of one or more inorganic oxides of at least one element selected from among those of Groups II, III and IV of the Periodic Table, and at least one catalytic metal component composited with the carrier. The metal of the catalytic metal component is selected from among those of Groups VB, VIB, VIII and IB of the Periodic Table. The catalyst contains about 1 to 30% by weight of such catalytic metal component and has the following pore characteristics with regard to its pores having a diameter of 75 .ANG. or more: an average pore diameter APD of about 180 to 500 .ANG., a total pore volume PV, expressed in cc/g, being equal to or greater than a value X ##EQU1## the volume of pores with a diameter of about 180 to 500 .ANG. being at least about 0.2 cc/g, the volume of pores with a diameter of at least 1,500 .ANG. being not greater than about 0.03 cc/g, and a total surface area being at least about 60 m.
    Type: Grant
    Filed: September 30, 1982
    Date of Patent: April 24, 1984
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Yoshimi Shiroto, Takeo Ono, Sachio Asaoka, Munekazu Nakamura
  • Patent number: 4439312
    Abstract: A catalyst for hydrotreating a heavy hydrocarbon oil comprises a carrier which is a calcined composite of a mixture of a clay mineral consisting mainly of magnesium silicate having a double-chain structure and a pseudoboehmite which shows a powder X-ray diffraction spectrum obtained by applying a CuK.sub..alpha. ray such that the half value width of the peak on the (020) plane is between about 0.8.degree. and 4.0.degree. and the intensity of said peak is between 1.2 and 8.0 times as high as that at 2.theta.=10.degree.. At least one catalytic metal component is composited with the carrier, the metal of the catalytic metal component being selected from the group consisting of metals belonging to Groups VB, VIB, VIII and IB of the Periodic Table. Disclosed also are a method of preparing such a catalyst, and a process for the hydrotreatment of heavy hydrocarbon oils containing asphaltenes and heavy metals.
    Type: Grant
    Filed: May 19, 1982
    Date of Patent: March 27, 1984
    Inventors: Sachio Asaoka, Takeo Ono, Yoshimi Shiroto
  • Patent number: 4424142
    Abstract: A catalyst for the hydrotreatment of heavy hydrocarbon oils, which is prepared by supporting more than 2% by weight of VS.sub.x, wherein x represents about 1.1-1.59 in terms of an atomic ratio of S/V, on a substrate composed of a clay mineral which consists of magnesium silicate as a major component and having a double-chain structure and a process for preparing the catalyst are provided. The catalyst is prepared by accumulating the VS.sub.x on the substrate using a heavy hydrocarbon oil which contains particularly large amounts of vanadium and sulfur.
    Type: Grant
    Filed: March 12, 1981
    Date of Patent: January 3, 1984
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Sachio Asaoka, Yoshimi Shiroto, Munekazu Nakamura, Takeo Ono
  • Patent number: 4422960
    Abstract: A catalyst for hydrotreating a heavy hydrocarbon oil containing asphaltenes comprises a porous carrier composed of one or more inorganic oxides of at least one element selected from among those of Groups II, III and IV of the Periodic Table, and at least one catalytic metal component composited with the carrier. The metal of the catalytic metal component is selected from among those of Groups VB, VIB, VIII and IB of the Periodic Table. The catalyst contains about 1 to 30% by weight of such catalytic metal component and has the following pore characteristics with regard to its pores having a diameter of 75 .ANG. or more: an average pore diameter APD of about 180 to 500 .ANG., a total pore volume PV, expressed in cc/g, being equal to or greater than a value X ##EQU1## the volume of pores with a diameter of about 180 to 500 .ANG. being at least about 0.2 cc/g, the volume of pores with a diameter of at least 1,500 .ANG. being not greater than about 0.03 cc/g, and a total surface area being at least about 60 m.
    Type: Grant
    Filed: December 14, 1980
    Date of Patent: December 27, 1983
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Yoshimi Shiroto, Takeo Ono, Sachio Asaoka, Munekazu Nakamura
  • Patent number: 4367165
    Abstract: A catalyst for hydrotreating a heavy hydrocarbon oil comprises a carrier which is a calcined composite of a mixture of a clay mineral consisting mainly of magnesium silicate having a double-chain structure and a pseudoboehmite which shows a powder X-ray diffraction spectrum obtained by applying a CuK.sub..alpha. ray such that the half value width of the peak on the (020) plane is between about 0.8.degree. and 4.0.degree. and the intensity of said peak is between 1.2 and 8.0 times as high as that at 2.theta.=10.degree.. At least one catalytic metal component is composited with the carrier, the metal of the catalytic metal component being selected from the group consisting of metals belonging to Groups VB, VIB, VIII and IB of the Periodic Table. Disclosed also are a method of preparing such a catalyst, and a process for the hydrotreatment of heavy hydrocarbon oils containing asphaltenes and heavy metals.
    Type: Grant
    Filed: November 24, 1980
    Date of Patent: January 4, 1983
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Sachio Asaoka, Takeo Ono, Yoshimi Shiroto
  • Patent number: 4326991
    Abstract: A catalyst for the hydrotreatment of heavy hydrocarbon oils, which is prepared by supporting more than 2% by weight of VS.sub.x, wherein x represents about 1.1-1.59 in terms of an atomic ratio of S/V, on a substrate composed of a clay mineral which consists of magnesium silicate as a major component and having a double-chain structure and a process for preparing the catalyst are provided. The catalyst is prepared by accumulating the VS.sub.x on the substrate using a heavy hydrocarbon oil which contains particularly large amounts of vanadium and sulfur.
    Type: Grant
    Filed: October 15, 1979
    Date of Patent: April 27, 1982
    Assignee: Chiyoda Chemical Engineering & Construction Co., Ltd.
    Inventors: Sachio Asaoka, Yoshimi Shiroto, Munekazu Nakamura