Patents by Inventor Sachio Yoshikawa

Sachio Yoshikawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20240132738
    Abstract: The present invention provides a polymeric dispersant that is to be blended in an aqueous pigment dispersion in which a pigment is finely dispersed in a stable manner and at a high level, the aqueous pigment dispersion enabling preparation of an aqueous inkjet ink capable of recording an image excellent in adhesiveness and durability on plastic media and textiles. The polymeric dispersant is a polymer that includes a constituent unit (i) derived from styrene, a constituent unit (ii) derived from methyl methacrylate and/or the like, a constituent unit (iii) derived from 2-ethylhexyl methacrylate and/or the like, a constituent unit (iv) derived from 2-hydroxyethyl methacrylate and/or the like, and a constituent unit (v) derived from methacrylic acid, and at least part of carboxy groups is neutralized with an alkali.
    Type: Application
    Filed: November 26, 2021
    Publication date: April 25, 2024
    Inventors: Hiroyuki SHIMANAKA, Katsuhiko KANO, Kosuke KUME, Chikako MIYAZAKI, Yoshikazu MURAKAMI, Sachio YOSHIKAWA
  • Publication number: 20240101844
    Abstract: There is provided an aqueous pigment dispersion that makes it possible to prepare an environmentally conscious aqueous inkjet ink in which a pigment is finely dispersed in a stable manner and at a high level and which is capable of recording an image having excellent durability, glossiness, color developability, and adhesiveness to various printing substrates. The aqueous pigment dispersion is an aqueous pigment dispersion containing a pigment, water, a water-soluble organic solvent, and a polymeric dispersant that disperses the pigment, wherein the polymeric dispersant is a polymer including a constitutional unit (i) derived from at least one of (meth)acrylic acid and itaconic acid, and a constituent unit (ii) derived from a (meth)acrylate derived from biological material, such as ethyl (meth)acrylate, having an acid value of 30 to 250 mgKOH/g, having a number average molecular weight of 1,000 to 30,000, and having a polydispersity index (weight average molecular weight/number average molecular weight) of 2.
    Type: Application
    Filed: September 16, 2021
    Publication date: March 28, 2024
    Inventors: Hiroyuki SHIMANAKA, Jun KAMABAYASHI, Sachio YOSHIKAWA, Toshie OKUBO, Lu TIAN, Akifumi TANAKA
  • Patent number: 11926741
    Abstract: A quinacridone solid solution pigment that allows a colored product to have high chroma and a properly yellowish hue and has a controlled particle diameter, and a method for producing the quinacridone solid solution pigment. In the method, a water-containing crude quinacridone solid solution is produced by a co-cyclization reaction of a diarylaminoterepththalic acid and a dialkylarylaminoterephthalic acid in polyphosphoric acid, then the resulting water-containing crude quinacridone solid solution having a mass ratio of unsubstituted quinacridone to a 2,9-dialkylquinacridone of 85:15 to 60:40 is dried, thereby obtaining a powdery, crude quinacridone solid solution having a water content of less than 1%. Then, the resulting powdery, crude quinacridone solid solution is heated in a liquid medium that does not dissolve the crude quinacridone solid solution. Also, a pigment dispersion liquid and an inkjet ink each containing the obtained quinacridone solid solution pigment are provided.
    Type: Grant
    Filed: March 30, 2018
    Date of Patent: March 12, 2024
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Naoto Kamata, Sachio Yoshikawa
  • Publication number: 20230357479
    Abstract: The present invention provides an environmentally friendly pigment dispersant composition that can be produced relatively easily. In this pigment dispersant composition, the content of a volatile component is significantly reduced even though the pigment dispersant composition contains a pigment dispersant mainly containing a constituent unit derived from a vinyl-based monomer, and a pigment dispersion and an ink which are excellent in pigment dispersability can be prepared using this pigment dispersant composition.
    Type: Application
    Filed: August 12, 2021
    Publication date: November 9, 2023
    Inventors: Hiroyuki SHIMANAKA, Yoshikazu MURAKAMI, Jun KAMABAYASHI, Toshiyasu FUJITA, Kazutaka ARAI, Sachio YOSHIKAWA
  • Publication number: 20230348651
    Abstract: The present invention provides an A-B block copolymer that enables preparation of a polymer emulsion useful as a binder component for an aqueous inkjet ink that is excellent in inkjet printability and is capable of forming a printed film excellent in durability, such as adhesiveness and rub resistance, on a substrate to be printed, such as a polyolefin-based plastic film. The block copolymer is an A-B block copolymer satisfying the following requirements (1-1) to (1-3). (1-1) Containing 90% by mass or more of a constituent unit derived from a methacrylate-based monomer or the like. (1-2) The chain A has a constituent unit (A-i) derived from methyl methacrylate or the like and a constituent unit (A-ii) derived from 2-ethylhexyl methacrylate or the like. (1-3) The chain B has a constituent unit (B) derived from methacrylic acid, a constituent unit (B-i) derived from methyl methacrylate or the like, and a constituent unit (B-ii) derived from 2-ethylhexyl methacrylate or the like.
    Type: Application
    Filed: August 12, 2021
    Publication date: November 2, 2023
    Inventors: Hiroyuki SHIMANAKA, Jun KAMABAYASHI, Akifumi TANAKA, Toshie OKUBO, Lu TIAN, Yoshikazu MURAKAMI, Sachio YOSHIKAWA
  • Patent number: 11773267
    Abstract: There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters.
    Type: Grant
    Filed: May 16, 2022
    Date of Patent: October 3, 2023
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Naoto Kamata, Toshiyuki Hitotsuyanagi, Sachio Yoshikawa, Satoshi Minami
  • Patent number: 11535755
    Abstract: There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters.
    Type: Grant
    Filed: October 10, 2017
    Date of Patent: December 27, 2022
    Assignee: Dainichiseika Color & Chemicals Mfg. Co.. Ltd.
    Inventors: Naoto Kamata, Toshiyuki Hitotsuyanagi, Sachio Yoshikawa, Satoshi Minami
  • Publication number: 20220275214
    Abstract: There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters.
    Type: Application
    Filed: May 16, 2022
    Publication date: September 1, 2022
    Inventors: Naoto KAMATA, Toshiyuki HITOTSUYANAGI, Sachio YOSHIKAWA, Satoshi MINAMI
  • Patent number: 10982020
    Abstract: There is provided a resin-treated pigment that is useful as a coloring agent for color filters or inkjet inks, that can expand a hue range and improve performances such as color density, color developability, and transparency, and that is excellent in properties such as dispersibility and dispersion stability of pigments, re-dissolvability, and alkali-solubility. An A-B block copolymer 90% by mass or more of which is constituted by a methacrylate-based monomer or methacrylate-based monomers, in which the block A has a carboxy group-containing methacrylate as a constituent, and the block B has an ionic bond moiety represented by formula (1) as a constitutional unit, the ionic bond moiety containing a methacrylate, and an organic coloring matter having one or more sulfonate ions each being bonded thereto and each being a counter ion of a nitrogen cation of a quaternary ammonium salt.
    Type: Grant
    Filed: June 25, 2014
    Date of Patent: April 20, 2021
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Hiroyuki Shimanaka, Yoichi Tagi, Yoshikazu Murakami, Shinichiro Aoyagi, Kazutaka Arai, Sachio Yoshikawa
  • Publication number: 20200407563
    Abstract: The present invention relates to a technique for providing a quinacridone solid solution pigment, by which a quinacridone solid solution pigment that allows a colored product to have high chroma and a properly yellowish hue, and suitably, that has a controlled particle diameter and has the above-described, desired hue can be obtained.
    Type: Application
    Filed: March 30, 2018
    Publication date: December 31, 2020
    Inventors: Naoto KAMATA, Sachio YOSHIKAWA
  • Publication number: 20200062965
    Abstract: There is provided a technique for producing a quinacridone solid solution pigment, the technique making it possible to obtain a quinacridone solid solution pigment which produces a colored product having high chroma and a bluish hue, more preferably which has controlled particle diameters.
    Type: Application
    Filed: October 10, 2017
    Publication date: February 27, 2020
    Applicant: Dainichiseika Color & Chemicals MFG. Co., Ltd.
    Inventors: Naoto KAMATA, Toshiyuki HITOTSUYANAGI, Sachio YOSHIKAWA, Satoshi MINAMI
  • Publication number: 20170166665
    Abstract: There is provided a resin-treated pigment that is useful as a coloring agent for color filters or inkjet inks, that can expand a hue range and improve performances such as color density, color developability, and transparency, and that is excellent in properties such as dispersibility and dispersion stability of pigments, re-dissolvability, and alkali-solubility. An A-B block copolymer 90% by mass or more of which is constituted by a methacrylate-based monomer or methacrylate-based monomers, in which the block A has a carboxy group-containing methacrylate as a constituent, and the block B has an ionic bond moiety represented by formula (1) as a constitutional unit, the ionic bond moiety containing a methacrylate, and an organic coloring matter having one or more sulfonate ions each being bonded thereto and each being a counter ion of a nitrogen cation of a quaternary ammonium salt.
    Type: Application
    Filed: June 25, 2014
    Publication date: June 15, 2017
    Inventors: Hiroyuki SHIMANAKA, Yoichi TAGI, Yoshikazu MURAKAMI, Shinichiro AOYAGI, Kazutaka ARAI, Sachio YOSHIKAWA
  • Patent number: 9644106
    Abstract: A novel aqueous emulsion solution is provided that can be used as a binder for forming a coating film suitable for an inkjet printing system. The present invention is an aqueous emulsion solution containing a polymer I and a polymer II mixed together therein, wherein the polymer I is an A-B block copolymer formed from 90 mass % or more of a methacrylate-based monomer, the A-B block copolymer neutralized with an alkali, a polymer block A is substantially water-insoluble and has a number average molecular weight of 1000 to 10000 and a polydispersity index of 1.5 or less, a polymer block B is synthesized using a monomer containing at least a methacrylic acid and has an acid value of 30 to 250 mgKOH/g, the A-B block copolymer has a number average molecular weight of 5000 to 20000, a content of the polymer block A of 5 to 60% in the A-B block copolymer, and a polydispersity index as a whole of 1.
    Type: Grant
    Filed: April 17, 2014
    Date of Patent: May 9, 2017
    Assignee: DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
    Inventors: Hiroyuki Shimanaka, Yoshikazu Murakami, Shinichiro Aoyagi, Sachio Yoshikawa, Mitsuo Yamazaki
  • Patent number: 9512321
    Abstract: Disclosed are an alkoxysilyl-containing A-B block copolymer formed from (meth)acrylate monomers as constituent monomers, characterized in that a polymer block of A chain has a number average molecular weight (Mn) of from 1,000 to 50,000 and a molecular weight distribution (Mw/Mn) of not greater than 1.6, a polymer block of B chain comprises alkoxysilyl-containing (meth)acrylate units as constituent monomer units, and the A-B block copolymer as a whole has a molecular weight distribution of not greater than 1.6, a process for the production of the block copolymer, a resin-treated pigment, and a pigment dispersion.
    Type: Grant
    Filed: February 24, 2011
    Date of Patent: December 6, 2016
    Assignees: DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD., KYOTO UNIVERSITY
    Inventors: Hiroyuki Shimanaka, Yoshikazu Murakami, Sachio Yoshikawa, Shinya Tsuchida, Atsushi Goto, Yoshinobu Tsujii
  • Publication number: 20160053125
    Abstract: A novel aqueous emulsion solution is provided that can be used as a binder for forming a coating film suitable for an inkjet printing system. The present invention is an aqueous emulsion solution containing a polymer I and a polymer II mixed together therein, wherein the polymer I is an A-B block copolymer formed from 90 mass % or more of a methacrylate-based monomer, the A-B block copolymer neutralized with an alkali, a polymer block A is substantially water-insoluble and has a number average molecular weight of 1000 to 10000 and a polydispersity index of 1.5 or less, a polymer block B is synthesized using a monomer containing at least a methacrylic acid and has an acid value of 30 to 250 mgKOH/g, the A-B block copolymer has a number average molecular weight of 5000 to 20000, a content of the polymer block A of 5 to 60% in the A-B block copolymer, and a polydispersity index as a whole of 1.
    Type: Application
    Filed: April 17, 2014
    Publication date: February 25, 2016
    Inventors: Hiroyuki SHIMANAKA, Yoshikazu MURAKAMI, Shinichiro AOYAGI, Sachio YOSHIKAWA, Mitsuo YAMAZAKI
  • Patent number: 9120948
    Abstract: Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it.
    Type: Grant
    Filed: March 13, 2013
    Date of Patent: September 1, 2015
    Assignees: DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD., KYOTO UNIVERSITY
    Inventors: Hiroyuki Shimanaka, Taiyo Aoyagi, Yoshikazu Murakami, Sachio Yoshikawa, Naoyuki Sakai, Atsushi Goto, Yoshinobu Tsujii, Takeshi Fukuda
  • Publication number: 20120329940
    Abstract: Disclosed are an alkoxysilyl-containing A-B block copolymer formed from (meth)acrylate monomers as constituent monomers, characterized in that a polymer block of A chain has a number average molecular weight (Mn) of from 1,000 to 50,000 and a molecular weight distribution (Mw/Mn) of not greater than 1.6, a polymer block of B chain comprises alkoxysilyl-containing (meth)acrylate units as constituent monomer units, and the A-B block copolymer as a whole has a molecular weight distribution of not greater than 1.6, a process for the production of the block copolymer, a resin-treated pigment, and a pigment dispersion.
    Type: Application
    Filed: February 24, 2011
    Publication date: December 27, 2012
    Applicants: KYOTO UNIVERSITY, DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
    Inventors: Hiroyuki Shimanaka, Yoshikazu Murakami, Sachio Yoshikawa, Shinya Tsuchida, Atsushi Goto, Yoshinobu Tsujii
  • Publication number: 20110223529
    Abstract: Disclosed are an aqueous pigment dispersion containing at least a pigment, water, a high-molecular dispersant, and an alkali. The high-molecular dispersant is a diblock polymer having a formula (1) of A-B or a triblock polymer having a formula (2) of A-B-C. The diblock or triblock polymer is a diblock or triblock polymer obtained by polymerizing addition-polymerizable monomers with a radical generator while using an organic iodide as a polymerization initiating compound and an organic phosphorus compound, organic nitrogen compound or organic oxygen compound as a catalyst. Also disclosed are a production method and use of the aqueous pigment dispersion. With the high-molecular dispersant obtained by a simple living radical polymerization process free of the problems of conventional living radical polymerization and having a precisely-controlled molecular structure, the aqueous pigment dispersion can be obtained with the pigment dispersed in it.
    Type: Application
    Filed: July 24, 2009
    Publication date: September 15, 2011
    Applicants: Dainichiseika Color & Chemicals Mfg. Co., Ltd., Kyoto University
    Inventors: Hiroyuki Shimanaka, Taiyo Aoyagi, Yoshikazu Murakami, Sachio Yoshikawa, Naoyuki Sakai, Atsushi Goto, Yoshinobu Tsujii, Takeshi Fukuda
  • Publication number: 20100036060
    Abstract: Ion-conducting (co)polymer media and ion-conducting oligomer media close in ion conductivity to organic-solvent-based electrolytes can be produced easily and safely on industrial scale. These ion-conducting (co)polymer media use (co)polymers containing at least one cyclocarbonato group, and these ion-conducting oligomer media employ oligomers containing at least two cyclocarbonato groups.
    Type: Application
    Filed: October 14, 2009
    Publication date: February 11, 2010
    Applicant: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Michiei Nakamura, Sachio Yoshikawa, Minoru Takizawa, Toshiyasu Fujita, Seiji Doi, Nobuhiro Kihara
  • Patent number: 7138211
    Abstract: A solidifying material for a cell electrolyte solution is a block copolymer, which comprises, as segments A, a polymer non-compatible with the cell electrolyte solution and, as segments B, a polymer compatible with the cell electrolyte solution. The solidifying material absorbs and solidifies the cell electrolyte solution. A smallest unit of the block copolymer is A-B-A. To each of the segments B, at least one group selected from the group consisting of a carboxyl group, an ester group, a hydroxyl group, a sulfonic group, an amino group, a cyclic carbonate group and a polyoxyalkylene group is bonded via a ā€”Sā€” bond or a ā€”Cā€” bond.
    Type: Grant
    Filed: April 22, 2004
    Date of Patent: November 21, 2006
    Assignee: Dainichiseika Color & Chemicals Mfg. Co., Ltd.
    Inventors: Minoru Takizawa, Yoshifumi Sugito, Naomi Oguma, Seiji Doi, Sachio Yoshikawa, Michiei Nakamura