Patents by Inventor Sadaharu Hashimoto
Sadaharu Hashimoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11787891Abstract: The present invention provides a modified block copolymer composition comprising a modified block copolymer containing at least one aromatic vinyl polymer block and at least one conjugated diene polymer block, and having at least one modified terminal modified with a compound having a silicon atom and an acrylic group and/or a methacrylic group.Type: GrantFiled: September 27, 2018Date of Patent: October 17, 2023Assignee: ZEON CORPORATIONInventors: Atsushi Nozawa, Sadaharu Hashimoto
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Publication number: 20230212344Abstract: Provided is a thermoplastic elastomer composition for an impact-resistant material, comprising a block copolymer composition comprising a block copolymer (B) in which a functional group capable of noncovalent bonding is introduced into a block copolymer (A) including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block.Type: ApplicationFiled: February 4, 2021Publication date: July 6, 2023Applicants: ZEON CORPORATION, National University Corporation Tokai National Higher Education and Research SystemInventors: Sadaharu HASHIMOTO, Atsushi NOZAWA, Atsushi NORO, Takato KAJITA, Haruka TANAKA, Yushu MATSUSHITA
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Patent number: 11492452Abstract: A main purpose of the present invention is to provide a multi-block copolymer composition having good elasticity and excellent stress relaxation properties, as well as small tension set. The present invention achieves the purpose by providing a multi-block copolymer composition obtained by a modification treatment, the composition including a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond to a block copolymer A; wherein the block copolymer A includes a block copolymer A1 having a specific primary structure and a block copolymer A2 having a specific primary structure, and the mass ratio (A1/A2) of the block copolymer A1 and the block copolymer A2 is 100/0 to 50/50.Type: GrantFiled: August 23, 2018Date of Patent: November 8, 2022Assignees: ZEON CORPORATION, NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITYInventors: Kousuke Isobe, Sadaharu Hashimoto, Atsushi Nozawa, Atsushi Noro, Takato Kajita, Yushu Matsushita
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Patent number: 11466150Abstract: A main object of the present invention is to provide a block copolymer composition which has good elasticity, while having excellent stress relaxation properties. The object is achieved by providing a block copolymer composition obtained by a modification treatment, the block copolymer composition comprising a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond into a block copolymer A including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block.Type: GrantFiled: May 1, 2018Date of Patent: October 11, 2022Assignees: ZEON CORPORATION, NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITYInventors: Kousuke Isobe, Sadaharu Hashimoto, Atsushi Nozawa, Ryoji Kameyama, Atsushi Noro, Takato Kajita, Yushu Matsushita
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Patent number: 11459417Abstract: The present invention provides a block copolymer composition comprising a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond into a block copolymer A including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block, wherein: the block copolymer B includes an ionic group as the functional group capable of forming a non-covalent bond.Type: GrantFiled: April 25, 2019Date of Patent: October 4, 2022Assignees: ZEON CORPORATION, NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEMInventors: Kousuke Isobe, Sadaharu Hashimoto, Atsushi Noro, Takato Kajita, Haruka Tanaka, Yushu Matsushita
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Tetra-block copolymer, and polymer composition, and hot-melt sticky adhesive composition using these
Patent number: 11440987Abstract: A tetrablock copolymer having an aromatic vinyl block (A1), a conjugated diene block (B1), an aromatic vinyl block (A2), and a conjugated diene block (B2) is provided, wherein Mw(A2)/Mw(A1) is 1.2 to 5, Mw(A2) is 12,000 or more, Mw(B1)>Mw(B2), Mw(Total) is 50,000 to 400,000 where the weight average molecular weight of the aromatic vinyl block (A1) is defined as Mw(A1), the weight average molecular weight of the conjugated diene block (B1) is defined as Mw(B1), the weight average molecular weight of the aromatic vinyl block (A2) is defined as Mw(A2), the weight average molecular weight of the conjugated diene block (B2) is defined as Mw(B2), and the weight average molecular weight of the tetrablock copolymer as a whole is defined as Mw(Total), and the content of aromatic vinyl monomer units is 10 to 30% by weight.Type: GrantFiled: February 20, 2019Date of Patent: September 13, 2022Assignee: ZEON CORPORATIONInventors: Leo Tsunoi, Ryoji Oda, Sadaharu Hashimoto -
Publication number: 20210230336Abstract: The present invention provides a block copolymer composition comprising a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond into a block copolymer A including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block, wherein: the block copolymer B includes an ionic group as the functional group capable of forming a non-covalent bond.Type: ApplicationFiled: April 25, 2019Publication date: July 29, 2021Applicants: ZEON CORPORATION, NATIONAL UNIVERSITY CORPORATION TOKAI NATIONAL HIGHER EDUCATION AND RESEARCH SYSTEMInventors: Kousuke ISOBE, Sadaharu HASHIMOTO, Atsushi NORO, Takato KAJITA, Haruka TANAKA, Yushu MATSUSHITA
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TETRA-BLOCK COPOLYMER, AND POLYMER COMPOSITION, AND HOT-MELT STICKY ADHESIVE COMPOSITION USING THESE
Publication number: 20200407481Abstract: A tetrablock copolymer having an aromatic vinyl block (A1), a conjugated diene block (B1), an aromatic vinyl block (A2), and a conjugated diene block (B2) is provided, wherein Mw(A2)/Mw(A1) is 1.2 to 5, Mw(A2) is 12,000 or more, Mw(B1)>Mw(B2), Mw(Total) is 50,000 to 400,000 where the weight average molecular weight of the aromatic vinyl block (A1) is defined as Mw(A1), the weight average molecular weight of the conjugated diene block (B1) is defined as Mw(B1), the weight average molecular weight of the aromatic vinyl block (A2) is defined as Mw(A2), the weight average molecular weight of the conjugated diene block (B2) is defined as Mw(B2), and the weight average molecular weight of the tetrablock copolymer as a whole is defined as Mw(Total), and the content of aromatic vinyl monomer units is 10 to 30% by weight.Type: ApplicationFiled: February 20, 2019Publication date: December 31, 2020Applicant: ZEON CORPORATIONInventors: Leo TSUNOI, Ryoji ODA, Sadaharu HASHIMOTO -
Patent number: 10815401Abstract: A main object of the present disclosure is to provide a block copolymer composition that allows a hot melt adhesive composition having excellent hot melt properties and heat resistance stability to be obtained. The object is achieved by providing a block copolymer composition comprising a block copolymer A including an Ar1-D1 diblock as a branched chain, the block copolymer A represented by the following general formula (I), characterized in that: a molecular weight distribution (Mw/Mn) of the block copolymer A is 1.20 or less; a content of the block copolymer A in the block copolymer composition is 10% by mass or more; a content of a block copolymer B corresponding to an Ar2-D2 diblock represented by the following general formula (II), in the block copolymer composition is 60% by mass or less, and a molecular weight distribution (Mw/Mn) of the block copolymer B is 1.Type: GrantFiled: September 16, 2016Date of Patent: October 27, 2020Assignee: ZEON CORPORATIONInventors: Atsushi Nozawa, Sadaharu Hashimoto
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Publication number: 20200255650Abstract: The present invention provides a modified block copolymer composition comprising a modified block copolymer containing at least one aromatic vinyl polymer block and at least one conjugated diene polymer block, and having at least one modified terminal modified with a compound having a silicon atom and an acrylic group and/or a methacrylic group.Type: ApplicationFiled: September 27, 2018Publication date: August 13, 2020Applicant: ZEON CORPORATIONInventors: Atsushi NOZAWA, Sadaharu HASHIMOTO
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Publication number: 20200255607Abstract: A main purpose of the present invention is to provide a multi-block copolymer composition having good elasticity and excellent stress relaxation properties, as well as small tension set. The present invention achieves the purpose by providing a multi-block copolymer composition obtained by a modification treatment, the composition including a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond to a block copolymer A; wherein the block copolymer A includes a block copolymer A1 having a specific primary structure and a block copolymer A2 having a specific primary structure, and the mass ratio (A1/A2) of the block copolymer A1 and the block copolymer A2 is 100/0 to 50/50.Type: ApplicationFiled: August 23, 2018Publication date: August 13, 2020Applicants: ZEON CORPORATION, NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITYInventors: Kousuke ISOBE, Sadaharu HASHIMOTO, Atsushi NOZAWA, Atsushi NORO, Takato KAJITA, Yushu MATSUSHITA
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Patent number: 10689552Abstract: A main object of the present disclosure is to provide a block copolymer composition that allows an adhesive composition having excellent die-cutting properties, softening agent anti-migration performance, mandrel properties and transparency to be obtained.Type: GrantFiled: September 16, 2016Date of Patent: June 23, 2020Assignee: ZEON CORPORATIONInventors: Ayako Furuko, Sadaharu Hashimoto
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Publication number: 20200062948Abstract: A main object of the present invention is to provide a block copolymer composition which has good elasticity, while having excellent stress relaxation properties. The object is achieved by providing a block copolymer composition obtained by a modification treatment, the block copolymer composition comprising a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond into a block copolymer A including at least one aromatic vinyl polymer block and at least one conjugated diene polymer block.Type: ApplicationFiled: May 1, 2018Publication date: February 27, 2020Applicants: ZEON CORPORATION, NATIONAL UNIVERSITY CORPORATION NAGOYA UNIVERSITYInventors: Kousuke ISOBE, Sadaharu HASHIMOTO, Atsushi NOZAWA, Ryoji KAMEYAMA, Atsushi NORO, Takato KAJITA, Yushu MATSUSHITA
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Patent number: 10508161Abstract: Provided are a modified hydrocarbon resin that can provide a hot-melt adhesive composition with low odor, low Gardner color and high peel adhesion, a method for producing the resin, and the hot-melt adhesive composition. A modified hydrocarbon resin comprising a 1,3-pentadiene monomer unit, a C4-C6 alicyclic monoolefin monomer unit, a C4-C8 acyclic monoolefin monomer unit, an alicyclic diolefin monomer unit, and an aromatic monoolefin monomer unit, and containing a carboxyl group or acid anhydride group, wherein a weight average molecular weight (Mw), a Z average molecular weight (Mz), a ratio (Mz/Mw), a Gardner color scale of a 50 mass % toluene solution, a softening point, and an acid value are in specific ranges.Type: GrantFiled: September 28, 2016Date of Patent: December 17, 2019Assignee: ZEON CORPORATIONInventors: Sadaharu Hashimoto, Ryoji Kameyama, Yoshifumi Maruyama
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Patent number: 10457764Abstract: Provided is a modified hydrocarbon resin that provides a hot melt adhesive composition with low odor, excellent heat stability, and high adhesive properties. The modified hydrocarbon resin is obtained by hydrogenating a hydrocarbon resin comprising a plurality of specific monomeric unit in a specific range, and characterized in that: a degree of hydrogenation of the olefins, a degree of hydrogenation of the aromatic rings, a weight average molecular weight (Mw), a Z-average molecular weight (Mz), a ratio (Mz/Mw) of the Z-average molecular weight to the weight-average molecular weight, a Gardner color scale of a toluene solution of 50 mass %, and a difference between pre-hydrogenation and post-hydrogenation mixed aniline point (MMAP) are within the specific range.Type: GrantFiled: March 31, 2017Date of Patent: October 29, 2019Assignee: ZEON CORPORATIONInventors: Ryoji Kameyama, Sadaharu Hashimoto
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Publication number: 20190100612Abstract: Provided is a modified hydrocarbon resin that provides a hot melt adhesive composition with low odor, excellent heat stability, and high adhesive properties. The modified hydrocarbon resin is obtained by hydrogenating a hydrocarbon resin comprising a plurality of specific monomeric unit in a specific range, and characterized in that: a degree of hydrogenation of the olefins, a degree of hydrogenation of the aromatic rings, a weight average molecular weight (Mw), a Z-average molecular weight (Mz), a ratio (Mz/Mw) of the Z-average molecular weight to the weight-average molecular weight, a Gardner color scale of a toluene solution of 50 mass %, and a difference between pre-hydrogenation and post-hydrogenation mixed aniline point (MMAP) are within the specific range.Type: ApplicationFiled: March 31, 2017Publication date: April 4, 2019Applicant: ZEON CORPORATIONInventors: Ryoji KAMEYAMA, Sadaharu HASHIMOTO
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Patent number: 10174230Abstract: The present invention is a block copolymer composition comprising an aromatic vinyl-isoprene-aromatic vinyl triblock copolymer (A) and an aromatic vinyl-isoprene diblock copolymer (B), (i) a ratio (MwDa/MwDb) of a weight average molecular weight MwDa of a polyisoprene block in the triblock copolymer (A) to a weight average molecular weight MwDb of a polyisoprene block in the diblock copolymer (B) being 0.5 or more to less than 1, (ii) a ratio of an aromatic vinyl monomer unit in all polymer components of the block copolymer composition being 10 to 30 mass %, and (iii) the block copolymer composition having a breaking strength of less than 8 MPa and an elongation at break of less than 1,100%; a pressure-sensitive adhesive composition comprising the block copolymer composition and a tackifying resin; and a pressure-sensitive adhesive sheet comprising a pressure-sensitive adhesive layer that comprises the pressure-sensitive adhesive composition.Type: GrantFiled: September 24, 2015Date of Patent: January 8, 2019Assignee: ZEON CORPORATIONInventors: Ayako Furuko, Sadaharu Hashimoto
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Publication number: 20180265755Abstract: A main object of the present disclosure is to provide a block copolymer composition that allows an adhesive composition having excellent die-cutting properties, softening agent anti-migration performance, mandrel properties and transparency to be obtained.Type: ApplicationFiled: September 16, 2016Publication date: September 20, 2018Applicant: ZEON CORPORATIONInventors: Ayako FURUKO, Sadaharu HASHIMOTO
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Publication number: 20180258198Abstract: Provided are a modified hydrocarbon resin that can provide a hot-melt adhesive composition with low odor, low Gardner color and high peel adhesion, a method for producing the resin, and the hot-melt adhesive composition. A modified hydrocarbon resin comprising a 1,3-pentadiene monomer unit, a C4-C6 alicyclic monoolefin monomer unit, a C4-C8 acyclic monoolefin monomer unit, an alicyclic diolefin monomer unit, and an aromatic monoolefin monomer unit, and containing a carboxyl group or acid anhydride group, wherein a weight average molecular weight (Mw), a Z average molecular weight (Mz), a ratio (Mz/Mw), a Gardner color scale of a 50 mass % toluene solution, a softening point, and an acid value are in specific ranges.Type: ApplicationFiled: September 28, 2016Publication date: September 13, 2018Applicant: ZEON CORPORATIONInventors: Sadaharu HASHIMOTO, Ryoji KAMEYAMA, Yoshifumi MARUYAMA
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Publication number: 20180258328Abstract: A main object of the present disclosure is to provide a block copolymer composition that allows a hot melt adhesive composition having excellent hot melt properties and heat resistance stability to be obtained. The object is achieved by providing a block copolymer composition comprising a block copolymer A including an Ar1-D1 diblock as a branched chain, the block copolymer A represented by the following general formula (I), characterized in that: a molecular weight distribution (Mw/Mn) of the block copolymer A is 1.20 or less; a content of the block copolymer A in the block copolymer composition is 10% by mass or more; a content of a block copolymer B corresponding to an Ar2-D2 diblock represented by the following general formula (II), in the block copolymer composition is 60% by mass or less, and a molecular weight distribution (Mw/Mn) of the block copolymer B is 1.Type: ApplicationFiled: September 16, 2016Publication date: September 13, 2018Applicant: ZEON CORPORATIONInventors: Atsushi NOZAWA, Sadaharu HASHIMOTO