Patents by Inventor Sadahiko Matsuura
Sadahiko Matsuura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
-
Patent number: 11760819Abstract: The purpose of the present invention is to obtain an ethylene??-olefin?non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene??-olefin?non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4) 125° C. is 5-100, and (4) the B value is 1.20 or more.Type: GrantFiled: December 23, 2020Date of Patent: September 19, 2023Assignee: MITSUI CHEMICALS, INC.Inventors: Koji Endo, Mayumi Hiwara, Sadahiko Matsuura, Yusuke Mizobuchi, Yuichi Yamamura, Yuji Noguchi, Yuji Ishii, Tatsuya Sakai, Keisuke Shishido, Kotaro Ichino, Kiyohide Inomata, Fumito Takeuchi, Kenta Ide
-
Patent number: 11613595Abstract: The purpose of the present invention is to obtain an ethylene??-olefin?non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene??-olefin?non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4)125° C. is 5-100, and (4) the B value is 1.20 or more.Type: GrantFiled: December 23, 2020Date of Patent: March 28, 2023Assignee: MITSUI CHEMICALS, INC.Inventors: Koji Endo, Mayumi Hiwara, Sadahiko Matsuura, Yusuke Mizobuchi, Yuichi Yamamura, Yuji Noguchi, Yuji Ishii, Tatsuya Sakai, Keisuke Shishido, Kotaro Ichino, Kiyohide Inomata, Fumito Takeuchi, Kenta Ide
-
Patent number: 11485815Abstract: A 4-methyl-1-pentene polymer particle (X) which satisfies the following requirements (X-a), (X-b) and (X-c): (X-a) being composed of a 4-methyl-1-pentene polymer which has a content of a constitutional unit derived from 4-methyl-1-pentene being 30.0 to 99.7% by mol, and a content of a constitutional unit derived from at least one olefin selected from ethylene and an ?-olefin having 3 to 20 carbon atoms (except for 4-methyl-1-pentene) being 0.3 to 70.0% by mol; (X-b) having, when measured in a cross fractionation chromatograph apparatus (CFC) using an infrared spectrophotometer as a detector part, at least one peak A of an amount of a component eluted present in the range of 100 to 140° C., and at least one peak B of an amount of a component eluted present at lower than 100° C.; and (X-c) having a meso diad fraction (m) measured by 13C-NMR falling within the range of 95.0 to 100%.Type: GrantFiled: April 9, 2019Date of Patent: November 1, 2022Assignee: MITSUI CHEMICALS, INC.Inventors: Masakazu Tanaka, Toyoaki Sasaki, Tomoaki Matsugi, Sadahiko Matsuura, Naoto Matsukawa, Masatoshi Chinaka
-
Patent number: 11248069Abstract: A 4-methyl-1-pentene polymer having: a unit derived from 4-methyl-1-pentene of 90 to 100% by mol; a unit selected from ethylene and an ?-olefin, other than 4-methyl-1-pentene, having 3 to 20 carbon atoms of 0 to 10% by mol; and the polymer satisfying the following requirements: (a) a meso diad fraction measured by 13C-NMR within the range of 98 to 100%; (b) a ratio of Z-average molecular weight Mz to weight-average molecular weight Mw measured by GPC within the range of 2.5 to 20; (c) a ratio of weight-average molecular weight Mw to number-average molecular weight Mn measured by GPC within the range of 3.6 to 30; (d) a melt flow rate measured under conditions of 260° C. and a 5 kg load (ASTM D1238) within the range of 0.1 to 500 g/10 min; and (e) an amount of a decane-soluble portion at 23° C. is 5.0% by mass or less.Type: GrantFiled: February 21, 2017Date of Patent: February 15, 2022Assignee: MITSUI CHEMICALS, INC.Inventors: Masakazu Tanaka, Masahiko Okamoto, Makoto Nakano, Sadahiko Matsuura
-
Publication number: 20210122860Abstract: The purpose of the present invention is to obtain an ethylene??-olefin?non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene??-olefin?non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4)125° C. is 5-100, and (4) the B value is 1.20 or more.Type: ApplicationFiled: December 23, 2020Publication date: April 29, 2021Applicant: MITSUI CHEMICALS, INC.Inventors: Koji ENDO, Mayumi HIWARA, Sadahiko MATSUURA, Yusuke MIZOBUCHI, Yuichi YAMAMURA, Yuji NOGUCHI, Yuji ISHII, Tatsuya SAKAI, Keisuke SHISHIDO, Kotaro ICHINO, Kiyohide INOMATA, Fumito TAKEUCHI, Kenta IDE
-
Publication number: 20210122861Abstract: The purpose of the present invention is to obtain an ethylene??-olefin?non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene??-olefin?non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4) 125° C. is 5-100, and (4) the B value is 1.20 or more.Type: ApplicationFiled: December 23, 2020Publication date: April 29, 2021Applicant: MITSUI CHEMICALS, INC.Inventors: Koji ENDO, Mayumi HIWARA, Sadahiko MATSUURA, Yusuke MIZOBUCHI, Yuichi YAMAMURA, Yuji NOGUCHI, Yuji ISHII, Tatsuya SAKAI, Keisuke SHISHIDO, Kotaro ICHINO, Kiyohide INOMATA, Fumito TAKEUCHI, Kenta IDE
-
Patent number: 10919997Abstract: The purpose of the present invention is to obtain an ethylene.?-olefin.non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene.?-olefin.non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4)125° C. is 5-100, and (4) the B value is 1.20 or more.Type: GrantFiled: February 10, 2015Date of Patent: February 16, 2021Assignee: MITSUI CHEMICALS, INC.Inventors: Koji Endo, Mayumi Hiwara, Sadahiko Matsuura, Yusuke Mizobuchi, Yuichi Yamamura, Yuji Noguchi, Yuji Ishii, Tatsuya Sakai, Keisuke Shishido, Kotaro Ichino, Kiyohide Inomata, Fumito Takeuchi, Kenta Ide
-
Publication number: 20210032397Abstract: A 4-methyl-1-pentene polymer particle (X) which satisfies the following requirements (X-a), (X-b) and (X-c): (X-a) being composed of a 4-methyl-1-pentene polymer which has a content of a constitutional unit derived from 4-methyl-1-pentene being 30.0 to 99.7% by mol, and a content of a constitutional unit derived from at least one olefin selected from ethylene and an ?-olefin having 3 to 20 carbon atoms (except for 4-methyl-1-pentene) being 0.3 to 70.0% by mol; (X-b) having, when measured in a cross fractionation chromatograph apparatus (CFC) using an infrared spectrophotometer as a detector part, at least one peak A of an amount of a component eluted present in the range of 100 to 140° C., and at least one peak B of an amount of a component eluted present at lower than 100° C.; and (X-c) having a meso diad fraction (m) measured by 13C-NMR falling within the range of 95.0 to 100%.Type: ApplicationFiled: April 9, 2019Publication date: February 4, 2021Applicant: MITSUI CHEMICALS, INC.Inventors: Masakazu TANAKA, Toyoaki SASAKI, Tomoaki MATSUGI, Sadahiko MATSUURA, Naoto MATSUKAWA, Masatoshi CHINAKA
-
Patent number: 10329366Abstract: The invention has an object of providing ethylene/?-olefin copolymers having high randomness and a small number of double bonds in the copolymers. The ethylene/?-olefin copolymers of the invention are obtained by copolymerizing ethylene and an ?-olefin having 3 to 20 carbon atoms in the presence of an olefin polymerization catalyst which includes a bridged metallocene compound (A) represented by the formula [I], and at least one compound (B) selected from organometallic compounds (B-1), organoaluminum oxy compounds (B-2) and compounds (B-3) capable of reacting with the bridged metallocene compound (A) to form an ion pair, and have a specific weight average molecular weight, a specific molecular weight distribution, a specific glass transition point and a specific value B.Type: GrantFiled: May 31, 2018Date of Patent: June 25, 2019Assignee: MITSUI CHEMICALS, INC.Inventors: Katsuyoshi Harada, Koji Endo, Tomoaki Mizukawa, Sadahiko Matsuura
-
Publication number: 20190048109Abstract: A 4-methyl-1-pentene polymer having: a unit derived from 4-methyl-1-pentene of 90 to 100% by mol; a unit selected from ethylene and an ?-olefin, other than 4-methyl-1-pentene, having 3 to 20 carbon atoms of 0 to 10% by mol; and the polymer satisfying the following requirements: (a) a meso diad fraction measured by 13C-NMR within the range of 98 to 100%; (b) a ratio of Z-average molecular weight Mz to weight-average molecular weight Mw measured by GPC within the range of 2.5 to 20; (c) a ratio of weight-average molecular weight Mw to number-average molecular weight Mn measured by GPC within the range of 3.6 to 30; (d) a melt flow rate measured under conditions of 260° C. and a 5 kg load (ASTM D1238) within the range of 0.1 to 500 g/10 min; and (e) an amount of a decane-soluble portion at 23° C. is 5.0% by mass or less.Type: ApplicationFiled: February 21, 2017Publication date: February 14, 2019Applicant: MITSUI CHEMICALS, INC.Inventors: Masakazu TANAKA, Masahiko OKAMOTO, Makoto NAKANO, Sadahiko MATSUURA
-
Publication number: 20180273662Abstract: The invention has an object of providing ethylene/?-olefin copolymers having high randomness and a small number of double bonds in the copolymers. The ethylene/?-olefin copolymers of the invention are obtained by copolymerizing ethylene and an ?-olefin having 3 to 20 carbon atoms in the presence of an olefin polymerization catalyst which includes a bridged metallocene compound (A) represented by the formula [I], and at least one compound (B) selected from organometallic compounds (B-1), organoaluminum oxy compounds (B-2) and compounds (B-3) capable of reacting with the bridged metallocene compound (A) to form an ion pair, and have a specific weight average molecular weight, a specific molecular weight distribution, a specific glass transition point and a specific value B.Type: ApplicationFiled: May 31, 2018Publication date: September 27, 2018Applicant: MITSUI CHEMICALS, INC.Inventors: Katsuyoshi HARADA, Koji ENDO, Tomoaki MIZUKAWA, Sadahiko MATSUURA
-
Patent number: 10040884Abstract: The invention has an object of providing ethylene/?-olefin copolymers having high randomness and a small number of double bonds in the copolymers. The ethylene/?-olefin copolymers of the invention are obtained by copolymerizing ethylene and an ?-olefin having 3 to 20 carbon atoms in the presence of an olefin polymerization catalyst which includes a bridged metallocene compound (A) represented by the formula [I], and at least one compound (B) selected from organometallic compounds (B-1), organoaluminum oxy compounds (B-2) and compounds (B-3) capable of reacting with the bridged metallocene compound (A) to form an ion pair, and have a specific weight average molecular weight, a specific molecular weight distribution, a specific glass transition point and a specific value B.Type: GrantFiled: March 26, 2015Date of Patent: August 7, 2018Assignee: MITSUI CHEMICALS, INC.Inventors: Katsuyoshi Harada, Koji Endo, Tomoaki Mizukawa, Sadahiko Matsuura
-
Patent number: 9969827Abstract: A process capable of producing an ethylene/?-olefin copolymer having a high molecular weight even under the conditions of a high polymerization temperature is provided. The process for producing an ethylene/?-olefin copolymer includes copolymerizing ethylene and an ?-olefin having 3 or more carbon atoms in the presence of an olefin polymerization catalyst including a crosslinked metallocene compound (A) represented by the following general formula [I] and a cocatalyst component (B). In the general formula [I], Y is selected from a carbon atom, etc., M is a hafnium atom or the like, R1 to R12 are each selected from a hydrogen atom, a hydrocarbon group, etc., R13 and R14 are each a substituted aryl group or the like, at least one of R13 and R14 is a substituted aryl group having one or more electron-donating substituents having a Hammett substituent constant ? of not more than ?0.2, Q is selected from a halogen atom, etc., and j is an integer of 1 to 4.Type: GrantFiled: February 10, 2015Date of Patent: May 15, 2018Assignee: MITSUI CHEMICALS, INC.Inventors: Koji Endo, Mayumi Hiwara, Sadahiko Matsuura, Yoko Kosugi, Yuichi Yamamura, Yusuke Mizobuchi
-
Publication number: 20170183432Abstract: A process capable of producing an ethylene/?-olefin copolymer having a high molecular weight even under the conditions of a high polymerization temperature is provided. The process for producing an ethylene/?-olefin copolymer includes copolymerizing ethylene and an ?-olefin having 3 or more carbon atoms in the presence of an olefin polymerization catalyst including a crosslinked metallocene compound (A) represented by the following general formula [I] and a cocatalyst component (B). In the general formula [I], Y is selected from a carbon atom, etc., M is a hafnium atom or the like, R1 to R12 are each selected from a hydrogen atom, a hydrocarbon group, etc., R13 and R14 are each a substituted aryl group or the like, at least one of R13 and R14 is a substituted aryl group having one or more electron-donating substituents having a Hammett substituent constant ? of not more than ?0.2, Q is selected from a halogen atom, etc., and j is an integer of 1 to 4.Type: ApplicationFiled: February 10, 2015Publication date: June 29, 2017Applicant: MITSUI CHEMICALS, INC.Inventors: Koji ENDO, Mayumi HIWARA, Sadahiko MATSUURA, Yoko KOSUGI, Yuichi YAMAMURA, Yusuke MIZOBUCHI
-
Publication number: 20170114166Abstract: The invention has an object of providing ethylene/?-olefin copolymers having high randomness and a small number of double bonds in the copolymers. The ethylene/?-olefin copolymers of the invention are obtained by copolymerizing ethylene and an ?-olefin having 3 to 20 carbon atoms in the presence of an olefin polymerization catalyst which includes a bridged metallocene compound (A) represented by the formula [I], and at least one compound (B) selected from organometallic compounds (B-1), organoaluminum oxy compounds (B-2) and compounds (B-3) capable of reacting with the bridged metallocene compound (A) to form an ion pair, and have a specific weight average molecular weight, a specific molecular weight distribution, a specific glass transition point and a specific value B.Type: ApplicationFiled: March 26, 2015Publication date: April 27, 2017Applicant: MITSUI CHEMICALS, INC.Inventors: Katsuyoshi HARADA, Koji ENDO, Tomoaki MIZUKAWA, Sadahiko MATSUURA
-
Publication number: 20160347894Abstract: The purpose of the present invention is to obtain an ethylene•?-olefin•non-conjugated polyene copolymer that has a low permanent compression set at low temperatures, is flexible, and has an excellent balance of rubber elasticity at low temperatures and tensile strength at normal temperatures. This ethylene-based polymer is an ethylene•?-olefin•non-conjugated polyene copolymer that includes units derived from ethylene (A), units derived from an ?-olefin (B) containing 4-20 carbon atoms, and units derived from a non-conjugated polyene (C) and satisfies (1)-(4). (1) The molar ratio of (A) to (B) is 40/60-90/10, (2) the contained amount of the units derived from (C) is 0.1-6.0 mol %, (3) ML(1+4)125° C. is 5-100, and (4) the B value is 1.20 or more.Type: ApplicationFiled: February 10, 2015Publication date: December 1, 2016Applicant: MITSUI CHEMICALS, INC.Inventors: Koji ENDO, Mayumi HIWARA, Sadahiko MATSUURA, Yusuke MIZOBUCHI, Yuichi YAMAMURA, Yuji NOGUCHI, Yuji ISHII, Tatsuya SAKAI, Keisuke SHISHIDO, Kotaro ICHINO, Kiyohide INOMATA, Fumito TAKEUCHI, Kenta IDE
-
Patent number: 8236900Abstract: It is an object of the present invention to provide a modified polyolefin resin adhesive agent which is excellent in adhesiveness to a nonpolar substrate, particularly a poorly adhesive polyolefin substrate to which no surface treatment has been given and to a polar substrate, develops the excellent adhesiveness by drying or thermal compression bonding at relatively low temperature, and exhibits a low tack. That is, the present invention provides the modified polyolefin resin obtained by modifying a polyolefin resin with (A) a polarity imparting agent which is at least one selected from chlorine, unsaturated carboxylic acid, derivatives and anhydrides of unsaturated carboxylic acid and radical polymerizable monomers; and (B) an ethylene-?-olefin copolymer having an unsaturated bond at one end, and use of said modified polyolefin resin as an aqueous resin composition or an organic solvent resin composition.Type: GrantFiled: July 18, 2007Date of Patent: August 7, 2012Assignees: Nippon Paper Chemicals Co., Ltd., Mitsui Chemicals, Inc.Inventors: Yasutaka Watanabe, Kenichi Fujino, Hidetoshi Yoshioka, Naoshi Nagai, Sadahiko Matsuura
-
Publication number: 20100267908Abstract: [Task] To provide a catalyst for olefin polymerization having an excellent olefin polymerization performance and capable of producing a polyolefin with excellent properties.Type: ApplicationFiled: March 18, 2010Publication date: October 21, 2010Inventors: Kenji Michiue, Mitsuhiko Onda, Shigekazu Matsui, Sadahiko Matsuura, Koji Endo, Makoto Mitani, Terunori Fujita
-
Publication number: 20100004383Abstract: It is an object of the present invention to provide a modified polyolefin resin adhesive agent which is excellent in adhesiveness to a nonpolar substrate, particularly a poorly adhesive polyolefin substrate to which no surface treatment has been given and to a polar substrate, develops the excellent adhesiveness by drying or thermal compression bonding at relatively low temperature, and exhibits a low tack. That is, the present invention provides the modified polyolefin resin obtained by modifying a polyolefin resin with (A) a polarity imparting agent which is at least one selected from chlorine, unsaturated carboxylic acid, derivatives and anhydrides of unsaturated carboxylic acid and radical polymerizable monomers; and (B) an ethylene-?-olefin copolymer having an unsaturated bond at one end, and use of said modified polyolefin resin as an aqueous resin composition or an organic solvent resin composition.Type: ApplicationFiled: July 18, 2007Publication date: January 7, 2010Applicants: NIPPON PAPER CHEMICALS CO., LTD., MITSUI CHEMICALS, INC.Inventors: Yasutaka Watanabe, Kenichi Fujino, Hidetoshi Yoshioka, Naoshi Nagai, Sadahiko Matsuura
-
Publication number: 20090234073Abstract: An ?-olefin/non-conjugated cyclic polyene copolymer (A) includes structural units (I) derived from an ?-olefin and structural units (H) derived from a vinyl group-containing cyclic olefin. The copolymer has a molecular weight distribution (Mw/Mn) of not more than 2.7 and is amorphous or low crystalline with a crystalline heat of fusion (?H) of less than 90 kJ/kg. The copolymer is efficiently produced using a specific transition metal catalyst that has a ligand with a phenoxyimine skeleton. The copolymer of the invention has a narrower molecular weight distribution and a higher content of vinyl groups as compared with existing copolymers. The copolymer can then give crosslinked products having excellent tensile properties. The copolymer is also used as a plasticizer for polymers such as rubbers, and provides excellent processability and superior mechanical strength and rubber elasticity of crosslinked products.Type: ApplicationFiled: May 10, 2006Publication date: September 17, 2009Applicant: Mitsui Chemicals, Inc.Inventors: Shigekazu Matsui, Sadahiko Matsuura, Haruyuki Makio, Seiichi Ishii, Hiroshi Terao, Hidetatsu Murakami, Takashi Hakuta, Terunori Fujita