Patents by Inventor Sadanobu Shuto

Sadanobu Shuto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20090246815
    Abstract: The present invention provides a protease detection material having, on a support, at least a layer containing a dye precursor and a layer which contains a protease substrate and is disposed on the same side of the support as the layer containing the dye precursor and farther from the support than the layer containing the dye precursor, wherein the layer containing the protease substrate further contains a development center-forming substance. Further, a set of protease detection materials and a method for measuring protease using the above-described protease detection material are provided. A protease detection material, a set of protease detection materials, and a method of measuring protease which allow protease activity to be measured promptly with high sensitivity, and that allow, at the same time, morphological observation of tissues and cells on a thin film to be performed easily.
    Type: Application
    Filed: March 30, 2009
    Publication date: October 1, 2009
    Inventors: Sadanobu SHUTO, Katsuhisa OHZEKI, Mikinaga MORI
  • Patent number: 6824968
    Abstract: A silver halide color reversal photographic light-sensitive material comprising at least one interimage effect imparting layer (a) defined below and at least one interimage effect imparting layer (b) defined below, wherein, when the photographic light-sensitive material is exposed to light of a “skin color” having the spectral distribution of Table 1 described in the specification and is then subjected to development, a ratio of the chroma C*70 at a brightness L*=70 represented by CIE Lab color system to the chroma C*50 at a brightness L*=50, C*70/C*50, is 0.7 or more. (a) an interimage effect imparting layer containing a short-wavelength green-sensitive silver halide emulsion having a weight-averaged wavelength of a spectral sensitivity distribution of 500 to 560 nm; (b) an interimage effect imparting layer containing a red-sensitive silver halide emulsion having a weight-averaged wavelength of a spectral sensitivity distribution of 580 to 700 nm.
    Type: Grant
    Filed: October 10, 2003
    Date of Patent: November 30, 2004
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yutaka Maeno, Sadanobu Shuto, Akihiro Kakinuma
  • Publication number: 20040081927
    Abstract: A silver halide color reversal photographic light-sensitive material comprising at least one interimage effect imparting layer (a) defined below and at least one interimage effect imparting layer (b) defined below, wherein, when the photographic light-sensitive material is exposed to light of a “skin color” having the spectral distribution of Table 1 described in the specification and is then subjected to development, a ratio of the chroma C*70 at a brightness L*=70 represented by CIE Lab color system to the chroma C*50 at a brightness L*=50, C*70/C*50, is 0.7 or more.
    Type: Application
    Filed: October 10, 2003
    Publication date: April 29, 2004
    Applicant: FUJI PHOTO FILM CO., LTD
    Inventors: Yutaka Maeno, Sadanobu Shuto, Akihiro Kakinuma
  • Patent number: 6048673
    Abstract: The present invention relates to a color reversal photographic light-sensitive material, and particularly to a color reversal photographic light-sensitive material improved in skin color (flesh color) reproduction. More specifically, it relates to a color reversal photographic light-sensitive material that is excellent in tone reproduction of gray and skin colors, and that also exhibits a preferable chroma (colorfulness or saturation) with respect to skin colors of different tints.
    Type: Grant
    Filed: February 19, 1998
    Date of Patent: April 11, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masayuki Kuramitsu, Sadanobu Shuto, Shigeru Kuwashima, Makoto Yamada
  • Patent number: 5691125
    Abstract: There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (I) and (a) a monodisperse silver halide emulsion, (b) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (c) a colloidal silver, (d) negative-type interval latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (e) a sensitizing dye containing a sulfonamide group, (f) three separated layers of high, medium, and low sensitivities, (g) two separated layers each having different content of iodine, (h) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, or (i) a DIR-hydroquinone: formula (I) ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituent, R.sup.
    Type: Grant
    Filed: June 19, 1996
    Date of Patent: November 25, 1997
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takefumi Hara, Kazuyoshi Yamakawa, Sadanobu Shuto, Mitsuru Yamamoto, Makoto Suzuki, Yasuhiro Shimada, Katsuro Nagaoka, Satoshi Nagaoka, Yoshihiko Shibahara, Hideo Ikeda
  • Patent number: 5587280
    Abstract: A light-sensitive silver halide emulsion contains tabular silver halide grains with an equivalent-circle diameter/thickness ratio of 8 to 100. In this light-sensitive silver halide emulsion, a variation coefficient of a grain size distribution of the tabular silver halide grains is 1% to 20%, and 50% or more (number) of all of the tabular silver halide grains are grains whose ratio, b/a, of a longest distance, a, between two or more twin planes of the tabular silver halide grain to a grain thickness, b, is 1.5.ltoreq.b/a<5.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: December 24, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hideo Ikeda, Sadanobu Shuto, Takefumi Hara
  • Patent number: 5578441
    Abstract: There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (Ia) and (a) a sensitizing dye containing a sulfonamide group, (b) negative-type internal latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (c) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, (d) a monodisperse silver halide emulsion, (e) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (f) a colloidal silver, or (g) a DIR-hydroquinone: formula (Ia) ##STR1## wherein the substituents are as defined herein the specification.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: November 26, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoshi Nagaoka, Kazuyoshi Yamakawa, Mitsuru Yamamoto, Makoto Suzuki, Yasuhiro Shimada, Katsuro Nagaoka, Hideo Ikeda, Takefumi Hara, Sadanobu Shuto
  • Patent number: 5578436
    Abstract: There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (I) and (a) a monodisperse silver halide emulsion, (b) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (c) a colloidal silver, (d) negative-type interval latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (e) a sensitizing dye containing a sulfonamide group, (f) three separated layers of high, medium, and low sensitivities, (g) two separated layers each having different content of iodine, (h) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, or (i) a DIR-hydroquinone: formula (I) ##STR1## wherein R.sup.1 represents a hydrogen atom or a substituent, R.sup.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: November 26, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takefumi Hara, Kazuyoshi Yamakawa, Sadanobu Shuto, Mitsuru Yamamoto, Makoto Suzuki, Yasuhiro Shimada, Katsuro Nagaoka, Satoshi Nagaoka, Yoshihiko Shibahara, Hideo Ikeda
  • Patent number: 5478714
    Abstract: A silver halide photographic emulsion contains tabular silver halide grains having an aspect ratio of 2 or more in an amount of 70% or more of a total projected area of all grains. A variation coefficient of the grain size distribution of all silver halide grains is 20% or less, a signal having at least two peaks is present in a diffraction angle range of less than 1.5 degree at a maximum peak height.times.0.13 of a (420) X-ray diffraction signal obtained using the K.sub..alpha. line of Cu, and a peak interval thereof is 0.1 degree or more in terms of the diffraction angle.
    Type: Grant
    Filed: March 2, 1994
    Date of Patent: December 26, 1995
    Assignee: Fuji Photo Film, Co., Ltd.
    Inventors: Sadanobu Shuto, Hideo Ikeda, Takefumi Hara
  • Patent number: 5460929
    Abstract: There is disclosed a silver halide color photographic material having a red-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer, a blue-sensitive silver halide emulsion layer, which comprises a cyan dye-forming coupler represented by formula (Ia) and (a) a sensitizing dye containing a sulfonamide group, (b) negative-type internal latent image-type silver halide grains chemically sensitized to a defined depth from the surface, (c) grains each having a defined spectral sensitivity distribution and a DIR-hydroquinone, (d) a monodisperse silver halide emulsion, (e) non-photosensitive silver halide emulsion wherein the inside or the surface of grains is fogged, (f) a colloidal silver, or (g) a DIR-hydroquinone: ##STR1## wherein Za represents --NH-- or --CH(R.sub.3)--, Zb and Zc each represent --C(R.sub.4).dbd. or --N.dbd., R.sub.1, R.sub.2, and R.sub.3 each represent an electron-attracting group wherein the Hammett substituent constant .sigma..sub.p value is 0.
    Type: Grant
    Filed: April 14, 1993
    Date of Patent: October 24, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Satoshi Nagaoka, Kazuyoshi Yamakawa, Mitsuru Yamamoto, Makoto Suzuki, Yasuhiro Shimada, Katsuro Nagaoka, Hideo Ikeda, Takefumi Hara, Sadanobu Shuto
  • Patent number: 5310638
    Abstract: A silver halide color photographic material comprises a support, a blue sensitive layer, a green sensitive layer and a red sensitive layer. The total silver content of the photographic material is not more than 1.0 g/m.sup.2. The photographic material further contains a compound represented by the formula (1a) or (1b): ##STR1## in which R.sup.12 is an aliphatic group, an aromatic group or a heterocyclic group; M is --CO--, --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.15)SO.sub.2 --; each of R.sup.14, R.sup.15 and R.sup.24 independently is hydrogen, an alkyl group or an aryl group; L is a divalent linking group necessary for forming a 5, 6 or 7-membered ring; each of R.sup.11, R.sup.13 and R.sup.21 independently is hydrogen or a substituent group of the hydroquinone nucleus; Time is a group which is released from the oxidation product of the hydroquinone nucleus to further release X; X is a development inhibitor; and t is 0 or 1. M preferably is --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: May 10, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Takashi Ozawa
  • Patent number: 5286615
    Abstract: A silver halide color photographic material comprises a support, a blue sensitive layer, a green sensitive layer and a red sensitive layer and at least one non-light-sensitive layer. The non-light-sensitive layer is an intermediate layer arranged between the silver halide emulsion layers. According to the present invention, the non-light-sensitive intermediate layer contains a compound represented by the formula (1a) or (1b): ##STR1## in which R.sup.12 is an aliphatic group, an aromatic group or a heterocyclic group; M is --CO--, --SO.sub.2 --, --N(R.sup.15)CO--, --OCO-- or --N(R.sup.15)SO.sub.2 --; each of R.sup.14, R.sup.15 and R.sup.24 independently is hydrogen, an alkyl group or an aryl group; L is a divalent linking group necessary for forming a 5, 6 or 7-membered ring; each of R.sup.11, R.sup.13 and R.sup.
    Type: Grant
    Filed: October 15, 1991
    Date of Patent: February 15, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Akio Mitsui
  • Patent number: 5266448
    Abstract: A method for color reversal processing of an imagewise exposed silver halide color photographic material comprising first developing in a black-and-white developing bath, next color developing in a color developing bath, and then desilvering in a bath having a bleaching ability. The black-and-white developing bath has a bromide concentration in the range of 0.025 to 0.1 mol/l and is used for the black-and-white development. Furthermore, in a preferred embodiment, the photographic material comprises at least one silver halide emulsion layer containing a silver halide emulsion comprising silver halide grains having an average grain size of 0.3 .mu.m or less. In accordance with the invention, the maximum densities of the developed color images are increased without lowering of the sensitivity and contrast.
    Type: Grant
    Filed: March 27, 1992
    Date of Patent: November 30, 1993
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Takatoshi Ishikawa
  • Patent number: 5110719
    Abstract: A process for preparing a direct positive photosensitive material comprising providing on a support at least one silver halide light-sensitive emulsion layer containing the combination of (a) non-prefogged internal latent image silver halide grains; (b) a binder; (c) at least one compound represented by formulae (I), (II), or (III); and at least one compound represented by formula (IV):R--SO.sub.2 S--M (I)R--SO.sub.2 S--R.sup.1 (II)R--SO.sub.2 S--L.sub.m --S.O.sub.2 S--R.sup.2 (III)wherein R, R.sup.1 and R.sup.2 each represents a substituted or unsubstituted aliphatic group, a substituted or unsubstituted aromatic group or a substituted or unsubstituted heterocyclic group; M represents a cation; L represents a divalent linking group; and m is 0 or 1; andR.sup.3 --SO.sub.2 --M.sup.1 (IV)wherein R.sup.3 represents an aliphatic group, an aromatic group or a heterocyclic group; and M.sup.1 represents a cation. The material provides a direct positive image with high Dmax, low Dmin and high contrast.
    Type: Grant
    Filed: November 13, 1990
    Date of Patent: May 5, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Hatsumi Tanemura, Shigeo Hirano
  • Patent number: 5104784
    Abstract: A novel direct positive photosensitive material is provided comprising a support having therein at least one photographic emulsion layer containing internal latent image type silver halide grains not having been previously fogged, wherein the photographic emulsion layer comprises:(1) at least one of compounds represented by the general formulae [I], [II] and [III]; and(2) at least one of compounds represented by the general formulae [IV], [V] and [VI]:R--SO.sub.2 S--M [I]R--SO.sub.2 S--R.sup.1 [II]R--SO.sub.2 S--Lm--S.O.sub.2 S--R.sup.2 [III]wherein R, R.sup.1 and R.sup.2 may be the same or different and each represents an aliphatic group, aromatic group or heterocyclic group; M represents a cation; L represents a divalent connecting group; and m represents an integer 0 or 1;M'.sub.2 SO.sub.3 [IV]M'HSO.sub.3 [V]M'.sub.2 S.sub.2 O.sub.5 [VI]wherein M' represents a hydrogen atom or cation.
    Type: Grant
    Filed: April 17, 1990
    Date of Patent: April 14, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Naoyasu Deguchi
  • Patent number: 5081009
    Abstract: A direct positive photosensitive material composed of a support having thereon at least one photosensitive emulsion layer comprising non-prefogged internal latent image silver halide grains and at least one compound represented by formulae (I), (II), (III) or (IV): ##STR1## wherein M.sub.1 represents hydrogen, a cation or a protective group capable of being cleaved by an alkali; and Z represents an atomic group necessary for forming a 5-membered or 6-membered substituted or unsubstituted ring selected from a heterocyclic ring and a condensed heterocyclic ring; ##STR2## wherein Z.sub.1 represents an alkyl group containing from 1 to 18 carbon atoms, an aryl group containing from 6 to 18 carbon atoms or a heterocyclic group; Y.sub.1 and Y.sub.2, which may be the same or different, each represents an atomic group necessary for forming an aromatic ring containing from 6 to 18 carbon atoms or a heterocyclic ring; M represents a metal atom or an organic cation; and n is an integer of 2 to 10.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: January 14, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hatsumi Tanemura, Sadanobu Shuto, Noriyuki Inoue, Naoyasu Deguchi
  • Patent number: 4886738
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide photographic emulsion layer and at least one layer containing colloidal silver, wherein said colloidal silver-containing layer comprises at least one compound selected from compounds of general formula (I) and (II) below, and at least one photosensitive or non-photosensitive layer selected from a silver halide photosensitive layer positioned farthest from said support and any layers positioned between said farthest photosensitive layer and said support comprises a silver halide emulsion containing internally-fogged or surface-fogged silver halide grains: ##STR1## wherein the substituent groups on general formula (I) and (II) are as defined in the specification.
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: December 12, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Naoyasu Deguchi, Sadao Kamei, Kensuke Goda, Sadanobu Shuto, Yasuhiro Hayashi
  • Patent number: 4828972
    Abstract: A method for manufacturing a silver halide emulsion comprising the steps of forming silver halide grains in the presence of a hydrophilic colloid, physical ripening, desalting, and chemical ripening, wherein a photographic spectral sensitizing dye is added to the emulsion after adding at least 85% by weight of a soluble silver salt solution but before the desalting step is described.
    Type: Grant
    Filed: October 26, 1987
    Date of Patent: May 9, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Mikio Ihama, Sadanobu Shuto, Tadaaki Tani, Naoyasu Deguchi
  • Patent number: 4720451
    Abstract: A silver halide color reversal light-sensitive material comprising a support having thereon at least one red-sensitive emulsion layer, at least one green-sensitive emulsion layer and at least one blue-sensitive emulsion layer, at least one layer of said light-sensitive material comprising (1) an emulsion containing tabular silver halide grains having a diameter/thickness ratio of at least of about 4 and (2) at least one compound represented by the following general formulae (I) to (IV), said tabular silver halide grains being present in amount of at least about 50% of the total projected area of silver halide grains present in the same layer: ##STR1## wherein M.sub.1 represents a hydrogen atom, a cation or a group cleavable in alkaline conditions, and Z represents an atomic group as defined in the specification; ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents an alkyl group, an aryl group or an aralkyl group as defined in the specification, X.sup..
    Type: Grant
    Filed: September 18, 1985
    Date of Patent: January 19, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sadanobu Shuto, Naoyasu Deguchi
  • Patent number: 4717648
    Abstract: A process for processing a silver halide color reversal photographic light-sensitive material is disclosed, which comprises developing an imagewise exposed silver halide color reversal photographic light-sensitive material with a black-and-white developer containing at least one compound selected from the compounds of Group A, at least one compound selected from the compounds of Group B, and preferably further at least one compound selected from the compounds of Group C, whereinGroup A consists of organic heterocyclic compounds represented by formulae (A-I), (A-II), (A-III), and (A-IV) ##STR1## Group B consists of benzoimidazole, indazole, benzotriazole, benzooxazole and benzothiazole compounds, not containing a thiol group, a thioether bond, a thioketone group, or a disulfide bond.Group C consists of compounds represented by formulae (C-I) and (C-II). ##STR2## wherein the symbols are as defined in the appended claims.
    Type: Grant
    Filed: February 7, 1986
    Date of Patent: January 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shinji Ueda, Junya Nakajima, Tadao Shishido, Sadanobu Shuto