Abstract: An all-solid secondary battery including: a cathode layer including a cathode active material layer; an anode layer; and a solid electrolyte layer including a solid electrolyte, wherein the solid electrolyte layer is disposed between the cathode layer and the anode layer, wherein the anode layer includes an anode current collector, a first anode active material layer in contact with the solid electrolyte layer, and a second anode active material layer disposed between the anode current collector and the first anode active material layer, wherein the first anode active material layer includes a first carbonaceous anode active material, and the second anode active material layer.

Abstract: The present invention relates to a solid ion conductor compound represented by LiaMxTyPbScCldXe and having an argyrodite crystal structure, a solid electrolyte including the same, and an electrochemical cell including the same.

Abstract: Provided are a solid ion conductor represented by Formula 1 and having an argyrodite crystal structure, and a solid electrolyte and an electrochemical cell that include the solid ion conductor: Li7-2a-b-cMaPS6-a-b-cOaX1bX2c ??Formula 1 wherein, in Formula 1, M is zinc (Zn), cadmium (Cd), mercury (Hg), or a combination thereof, X1 and X2 are each independently chlorine (Cl), bromine (Br), iodine (I), a pseudohalogen, or a combination thereof, and conditions of 0<a<0.5, 0<b<2, 0<c<2, and 1<b+c<3 are satisfied.

Abstract: Disclosed are a method of preparing a sulfide solid electrolyte, a sulfide solid electrolyte prepared by the method, and an electrochemical cell comprising the sulfide solid electrolyte, the method comprising: preparing a precursor mixture by mixing raw materials with an organic compound, wherein the raw materials are for forming a sulfide solid electrolyte containing lithium, and the organic compound is non-reactive with lithium and is a non-ionic material having a hydrophobic region and a hydrophilic region; removing a solvent from the precursor mixture; and performing heat-treatment on the resultant product having the solvent removed therefrom.

Abstract: An all-solid secondary battery including: a cathode layer including a cathode active material layer; an anode layer; and a solid electrolyte layer including a solid electrolyte, wherein the solid electrolyte layer is disposed between the cathode layer and the anode layer, wherein the anode layer includes an anode current collector, a first anode active material layer in contact with the solid electrolyte layer, and a second anode active material layer disposed between the anode current collector and the first anode active material layer, wherein the first anode active material layer includes a first carbonaceous anode active material, and the second anode active material layer.

Abstract: Disclosed herein are a solid electrolyte including a compound represented by Formula 1 below and having an argyrodite crystal structure, an electrochemical battery including the solid electrolyte, and a method of preparing the solid electrolyte. (Li1?kMk)7?(a+b)PS6?(a+b+x)OxClaBrb??<Formula 1> wherein, in Formula 1, M is sodium (Na), potassium (K), calcium (Ca), iron (Fe), magnesium (Mg), silver (Ag), copper (Cu), zirconium (Zr), zinc (Zn), or a combination thereof , and 0.5?a/b?1.5, 0<a<2, 0<b<2, 0<x?1, 0?k<1, and x<3?(a+b)/2 are satisfied.

Abstract: A solid electrolyte includes a compound having an argyrodite crystal structure represented by Formula 1, LiaMxPSbBrcXd.??Formula 1 wherein Formula 1, M is Na, K, Fe, Mg, Ca, Ag, Cu, Zr, Zn, or a combination thereof; X is Cl, I, or a combination thereof; and 0?x<1, 5?(a+x)<7, 5?a?6, 4?b?6, 0<(c+d)?2, and (c/d)>4.

Abstract: A solid electrolyte includes a compound having an argyrodite crystal structure represented by Formula 1, LiaMxPSbBrcXd.??Formula 1 wherein Formula 1, M is Na, K, Fe, Mg, Ca, Ag, Cu, Zr, Zn, or a combination thereof; X is Cl, I, or a combination thereof; and 0?x<1, 5?(a+x)<7, 5?a?6, 4?b?6, 0<(c+d)?2, and (c/d)>4.

Abstract: A composite electrolyte includes: a positively charged particle, a particle that is positively charged by having a coordinate bond with a cation, or a combination thereof; and a lithium salt.

Abstract: Disclosed are a solid ion conductor compound represented by Formula 1, and having an argyrodite-type crystal structure, a solid electrolyte and an electrochemical cell each comprising the same, and a method of preparing the same: LixPyM1vSzM2wM3w???<Formula 1> where in the above formula, M1 is an element substituted at P sites and having a larger ionic radius than that of P, M2 and M3 are different elements selected from elements of Group 17 in the periodic table, and 4?x?8, 0<y<1, 0<v<1, 0<z<6, 0<w<3, 0?w?<3, and y?v.

Abstract: A composite electrolyte includes: a positively charged particle, a particle that is positively charged by having a coordinate bond with a cation, or a combination thereof; and a lithium salt.

Abstract: A composite separator includes: a porous substrate; and a composite electrolyte on a surface of the porous substrate, the composite electrolyte including block copolymer, an ionic liquid, and a particle, wherein a size of the particle is larger than a pore size of the porous substrate, the particle includes an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof, and the particle has a particle size of greater than about 1 micrometer to about 100 micrometers.

Abstract: An anodeless coating layer for an all-solid battery, the anodeless coating layer includes: an anode active material capable of forming an alloy with lithium or a compound with lithium; and a binder, wherein the binder includes a block copolymer including a conductive domain, a non-conductive domain, or a combination thereof, and wherein the conductive domain includes an ion-conductive domain, an electron-conductive domain, or a combination thereof.

Abstract: An all-solid secondary battery including: a cathode; an anode; and a solid electrolyte layer interposed between the cathode and the anode, wherein the cathode includes a cathode active material, wherein the anode includes an anode current collector and an anode active material layer on the anode current collector, wherein the anode active material layer includes a binder and an anode active material that does not include an alkali metal, wherein the binder includes a polymer main chain and a polyvinyl alcohol-containing copolymer, and wherein the polymer main chain includes polyvinyl alcohol, a polyvinyl alcohol derivative, or a combination thereof, and the polyvinyl alcohol-containing copolymer has at least one repeating unit linked to the polymer main chain.

Abstract: An all-solid-state secondary battery includes: a cathode layer including a cathode active material, an anode layer including an anode current collector and an anode active material layer disposed on the anode current collector, the anode active material layer including an anode active material and amorphous carbon, and a solid electrolyte layer disposed between the cathode active material layer and the anode active material layer, wherein a weight ratio of the anode active material to the amorphous carbon is 1:3 to 1:1, and the anode layer has sheet resistance of about 0.5 milliohms-centimeters or less.

Abstract: An all-solid secondary battery including: a cathode layer including a cathode active material layer; an anode layer; and a solid electrolyte layer including a solid electrolyte, wherein the solid electrolyte layer is disposed between the cathode layer and the anode layer, wherein the anode layer includes an anode current collector, a first anode active material layer in contact with the solid electrolyte layer, and a second anode active material layer disposed between the anode current collector and the first anode active material layer, wherein the first anode active material layer includes a first carbonaceous anode active material, and the second anode active material layer.

Abstract: A composite electrolyte structure includes: a protective layer having a Young's modulus of about 106 pascals or greater and including a first particle, the first particle including an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof, wherein the particle in the protective layer has a particle size of greater than 1 micrometer to about 100 micrometers, and a solid electrolyte layer including a second particle including an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof, wherein the second particle has a particle size of greater than 1 micrometer to about 100 micrometers, wherein the first particle and the second particle are the same or different, and wherein the protective layer is on the solid electrolyte layer.

Abstract: A solid electrolyte includes a compound having an argyrodite crystal structure represented by Formula 1, LiaMxPSbBrcXd.??Formula 1 wherein Formula 1, M is Na, K, Fe, Mg, Ca, Ag, Cu, Zr, Zn, or a combination thereof; X is Cl, I, or a combination thereof; and 0?x<1, 5?(a+x)<7, 5?a?6, 4?b?6, 0<(c+d)?2, and (c/d)>4.

Abstract: A negative electrode for a lithium metal battery, the negative electrode including: a lithium metal layer including lithium metal or a lithium metal alloy; and a protective layer on at least a portion of the lithium metal layer, wherein the protective layer includes a plurality of composite particles having a particle size of greater than about 1 micrometer to about 100 micrometers or less, wherein a composite particle of the plurality of composite particles comprises a particle comprising an organic particle, an inorganic particle, an organic-inorganic particle, or combination thereof; and a coating layer disposed on at least a portion of a surface of the particle, the coating layer including an ion conductive material including an ion conductive oligomer including an ion conductive unit, an ion conductive polymer including an ion conductive unit, or a combination thereof.

Abstract: A negative electrode for a lithium metal battery including: a lithium metal electrode including a lithium metal or a lithium metal alloy; and a protective layer on at least portion of the lithium metal electrode, wherein the protective layer has a Young's modulus of about 106 pascals or greater and includes at least one particle having a particle size of greater than 1 micrometer to about 100 micrometers, and wherein the at least one particle include an organic particle, an inorganic particle, an organic-inorganic particle, or a combination thereof.