Abstract: A method for fluid catalytic cracking (FCC) of petroleum oil feedstock includes reacting the petroleum oil feedstock with a catalyst mixture in a reaction zone of an FCC unit to obtain a product stream including desulfurized hydrocarbon product, unreacted petroleum oil feedstock, and spent catalyst. During the reacting a process control system develops a process model based on data collected during the reacting, the process model characterizing a relationship among the feed rate of the base cracking catalyst, the feed rate of the FCC additive, the operating conditions, the composition of the product stream, and emissions from the reaction; and one or more of (i) a target feed rate of the base cracking catalyst, (ii) a target feed rate of the FCC additive, and (iii) one or more target operating conditions of the reaction in the reaction zone to reduce the emissions from the FCC unit and to increase a yield of the desulfurized hydrocarbon product in the product stream are determined.

Abstract: A method for fluid catalytic cracking (FCC) of petroleum oil feedstock includes reacting the petroleum oil feedstock with a catalyst mixture in a reaction zone of an FCC unit to obtain a product stream including desulfurized hydrocarbon product, unreacted petroleum oil feedstock, and spent catalyst. During the reacting a process control system develops a process model based on data collected during the reacting, the process model characterizing a relationship among the feed rate of the base cracking catalyst, the feed rate of the FCC additive, the operating conditions, the composition of the product stream, and emissions from the reaction; and one or more of (i) a target feed rate of the base cracking catalyst, (ii) a target feed rate of the FCC additive, and (iii) one or more target operating conditions of the reaction in the reaction zone to reduce the emissions from the FCC unit and to increase a yield of the desulfurized hydrocarbon product in the product stream are determined.

Abstract: A method for fluid catalytic cracking (FCC) of petroleum oil feedstock includes reacting the petroleum oil feedstock with a catalyst mixture in a reaction zone of an FCC unit to obtain a product stream including desulfurized hydrocarbon product, unreacted petroleum oil feedstock, and spent catalyst. During the reacting a process control system develops a process model based on data collected during the reacting, the process model characterizing a relationship among the feed rate of the base cracking catalyst, the feed rate of the FCC additive, the operating conditions, the composition of the product stream, and emissions from the reaction; and one or more of (i) a target feed rate of the base cracking catalyst, (ii) a target feed rate of the FCC additive, and (iii) one or more target operating conditions of the reaction in the reaction zone to reduce the emissions from the FCC unit and to increase a yield of the desulfurized hydrocarbon product in the product stream are determined.

Abstract: A method to limit the deposition of metals from a syngas stream on a gas turbine comprising the steps of feeding the syngas stream to a pressure swing adsorption vessel of a pressure swing adsorption system, the syngas stream comprises carbonyls, the pressure swing adsorption vessel configured to perform a pressure swing adsorption cycle: adsorbing the carbonyls on a carbonyl selective adsorbent, leaving a turbine feed stream, reducing the pressure of the pressure swing adsorption vessel to a purge pressure less than the adsorbing pressure, purging the carbonyls from the carbonyl adsorbed adsorbent to create a tail gas stream, re-pressurizing the regenerated carbonyl adsorbent to the adsorbing pressure, feeding the tail gas stream to an incinerator configured to oxidize the carbonyls in the tail gas stream to metal oxides and carbon dioxide, and feeding the turbine feed stream to the gas turbine.

Abstract: A method to limit the deposition of metals from a syngas stream on a gas turbine comprising the steps of feeding the syngas stream to a pressure swing adsorption vessel of a pressure swing adsorption system, the syngas stream comprises carbonyls, the pressure swing adsorption vessel configured to perform a pressure swing adsorption cycle: adsorbing the carbonyls on a carbonyl selective adsorbent, leaving a turbine feed stream, reducing the pressure of the pressure swing adsorption vessel to a purge pressure less than the adsorbing pressure, purging the carbonyls from the carbonyl adsorbed adsorbent to create a tail gas stream, re-pressurizing the regenerated carbonyl adsorbent to the adsorbing pressure, feeding the tail gas stream to an incinerator configured to oxidize the carbonyls in the tail gas stream to metal oxides and carbon dioxide, and feeding the turbine feed stream to the gas turbine.