Abstract: A process for simultaneous removal of hydrogen sulfide (H2S ) and heavy metals from mixture includes charging a contaminated aqueous composition containing heavy metal ions to a reactor. The process also includes passing a H2S -containing gas composition via a plurality of gas spargers through the contaminated aqueous composition present in the reactor to form a H2S-containing contaminated aqueous composition and a purified gas composition. The process further includes reacting the H2S from the H2S -containing contaminated aqueous composition with the heavy metal ions in the H2S -containing contaminated aqueous composition to form a metal sulfide precipitate in a metal-sulfide-containing contaminated aqueous composition.

Abstract: A process for removing hydrogen sulfide (H2S) from a H2S-containing gas composition includes charging a liquid to a reactor under continuous agitation and dispersing particles of a graphene supported mixed-metal hydroxide composite in the liquid to form a graphene supported mixed-metal hydroxide composite mixture. The method further includes introducing the H2S-containing gas composition to the reactor containing the graphene supported mixed-metal hydroxide composite mixture under continuous agitation and passing the H2S-containing gas composition through the graphene supported mixed-metal hydroxide composite mixture. In addition, the method includes adsorbing the H2S from the H2S-containing gas composition onto the graphene supported mixed-metal hydroxide composite to remove the H2S from the H2S-containing gas composition and form a purified gas composition.

Abstract: A process for removing hydrogen sulfide (H2S) from a H2S-containing gas composition includes charging a liquid to a reactor under continuous agitation and dispersing particles of a CuMgAl compound in the liquid to form a CuMgAl complex mixture. The CuMgAl compound includes CuMgAl layered triple hydroxides and CuMgAl layered triple oxides. The method further includes introducing the H2S-containing gas composition to the reactor containing the CuMgAl complex mixture under continuous agitation and passing the H2S-containing gas composition through the CuMgAl complex mixture. In addition, the method includes adsorbing and removing H2S from the gas composition by the CuMgAl complex mixture to form a purified gas composition.

Abstract: A two or particularly three-phase process, and corresponding apparatus, desulfurizes sour hydrocarbon gas, e.g., natural gas, generally better than known, using a fixed-bed, two-phase processes in terms of the amount of H2S scavenged and the breakthrough time of H2S. The three-phase process is effective in scavenging H2S at ambient temperature and pressure, using a copper salt catalyst impregnated on alumina or other generally inert support, which is regenerable.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore in the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide. The method further includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid includes an aqueous solvent, a hydrogen sulfide scavenger including particles of a manganese oxide supported on a porous support. The particles are suspended in the aqueous solvent. The method further includes reacting the hydrogen sulfide scavenger with the hydrogen sulfide present in the formation fluid to form a manganese sulfide.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H2S scavenger which is potassium permanganate. The drilling fluid composition includes an invert emulsion includes a continuous phase including palm oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H2S scavenger which is potassium permanganate. The drilling fluid composition includes an invert emulsion which includes a continuous phase including mineral oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H2S scavenger which is potassium permanganate. The drilling fluid composition includes an invert emulsion includes a continuous phase including palm oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.

Abstract: A method of removing a sulfide-containing scale from a wellbore, pipe, or other metal-containing surface associated with an oil or gas well is provided. The method includes contacting the sulfide-containing scale with a de-scaler solution including an aqueous solvent, an acid and a hydrogen sulfide scavenger. The hydrogen sulfide scavenger includes particles of a manganese oxide supported on a porous support. The particles are suspended in the aqueous solvent. The method includes reacting the acid with the sulfide-containing scale to produce hydrogen sulfide. The method further includes reacting the hydrogen sulfide in the wellbore with the manganese oxide to form a manganese sulfide.

Abstract: A two or particularly three-phase process, and corresponding apparatus, desulfurizes sour hydrocarbon gas, e.g., natural gas, generally better than known, using a fixed-bed, two-phase processes in terms of the amount of H2S scavenged and the breakthrough time of H2S. The three-phase process is effective in scavenging H2S at ambient temperature and pressure, using a copper salt catalyst impregnated on alumina or other generally inert support, which is regenerable.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore in the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide. The method further includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid includes an aqueous solvent, a hydrogen sulfide scavenger including particles of a manganese oxide supported on a porous support. The particles are suspended in the aqueous solvent. The method further includes reacting the hydrogen sulfide scavenger with the hydrogen sulfide present in the formation fluid to form a manganese sulfide.

Abstract: A method and an electrocatalytic electrode for electrochemically reducing carbon dioxide to methanol are provided. An exemplary electrocatalytic electrode includes copper (I) oxide crystals electrodeposited over an atomically smooth copper electrode.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H2S scavenger, which is potassium permanganate, and an invert emulsion, which includes a continuous phase including a vegetable oil which is at least one selected from the group consisting of corn oil, soybean oil, rapeseed oil, canola oil, sunflower oil, safflower oil, peanut oil, and cottonseed oil and a dispersive phase including water.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore in the subterranean geological formation thereby producing a formation fluid. The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid includes 0.05 to 1 wt. % of a rhamnolipid surfactant based on a total weight of the drilling fluid. The drilling fluid includes an invert emulsion including a continuous phase and a dispersive phase including water.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H2S scavenger which is potassium permanganate. The drilling fluid composition includes an invert emulsion which includes a continuous phase including mineral oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore in the subterranean geological formation thereby producing a formation fluid. The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid includes 1 to 3 wt. % of a weighting agent which includes hydrophobic metallic zinc nanoparticles including a metallic core and organic ligands present on a surface of the metallic core, based on a total weight of the drilling fluid. The drilling fluid includes an invert emulsion including a continuous phase and a dispersive phase including water.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt.% of a primary H2S scavenger which is potassium permanganate. The drilling fluid composition includes an invert emulsion includes a continuous phase including palm oil and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.

Abstract: A method of drilling a subterranean geological formation is described. The method includes driving a drill bit to form a wellbore into the subterranean geological formation thereby producing a formation fluid including hydrogen sulfide (H2S). The method includes injecting a drilling fluid into the subterranean geological formation through the wellbore. The drilling fluid composition includes 0.25 to 2 wt. % of a primary H2S scavenger which is potassium permanganate. The drilling fluid composition includes an invert emulsion includes a continuous phase including diesel and a dispersive phase including water. The potassium permanganate present in the drilling fluid composition reacts with the H2S present in the formation fluid to produce a dispersion of manganese-containing particles which are at least one selected from the group consisting of manganese sulfide and manganese sulfate.

Abstract: A method for forming an atomically smooth surface on a copper electrode through electropolishing and the atomically smooth surface are provided. An exemplary method for forming an atomically smooth surface by electropolishing includes placing a copper foil in an electrolyte solution including ethylene glycol and phosphoric acid. The copper foil is coupled to a current source. Current is applied to the copper foil to electropolish the copper foil. The electropolishing is stopped when the electropolishing is completed.

Abstract: An aminated magnesium oxide adsorbent, which is the reaction product of a magnesium oxide matrix having disordered mesopores and an amino silane, wherein amine functional groups are present on an external surface and within the disordered mesopores of the magnesium oxide matrix, and wherein the aminated magnesium oxide adsorbent has an average pore volume of 0.2 to 0.4 cm3/g. A method of making the aminated magnesium oxide adsorbent and a method of capturing CO2 from a gas mixture with the aminated magnesium oxide adsorbent are also described.