Patents by Inventor Sam Louis Samuels

Sam Louis Samuels has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20150274951
    Abstract: A nanofilled ionomer composition comprises a nanofiller in a blend of a first ionomer and a second ionomer that is different from the first ionomer. The second ionomer is a water dispersable ionomer that allows for excellent dispersion of the nanofiller in the ionomer matrix. A variety of articles may comprise or be produced from the nanofilled ionomer composition, for example by injection molding.
    Type: Application
    Filed: October 11, 2013
    Publication date: October 1, 2015
    Inventors: Karlheinz Hausmann, Sam Louis Samuels, Gordon Mark Cohen, Mark David Wetzel
  • Publication number: 20150251384
    Abstract: Provided herein are glass laminates having at least one glass layer and a nanofilled ionomeric interlayers comprising a nanofiller in a blend of a first ionomer and a second ionomer that is different from the first ionomer. The second ionomer is a water dispersable ionomer that allows for excellent dispersion of the nanofiller in the ionomer matrix. The laminates retain favorable performance properties such as high transparency while exhibiting lower creep or heat deflection.
    Type: Application
    Filed: October 11, 2013
    Publication date: September 10, 2015
    Inventors: Stephen J. Bennison, Sam Louis Samuels, Gordon Mark Cohen, Mark David Wetzel
  • Publication number: 20150255653
    Abstract: A solar cell module comprising a solar cell layer and a sheet comprising at least one layer of a nanofilled ionomer composition, wherein the nanofilled ionomer composition comprises (1) an ionomer that is derived from a precursor ?-olefin carboxylic acid copolymer wherein (a) the precursor ?-olefin carboxylic acid copolymer comprises (i) copolymerized units of an ?-olefin and (ii) about 20 to about 25 weight % of copolymerized units of an ?,?-ethylenically unsaturated carboxylic acid; and (b) at least a portion of the total content of the carboxylic acid groups present in the precursor ?-olefin carboxylic acid copolymer have been neutralized to form metal salts of the carboxylic acid groups; and (2) one or more nanofillers.
    Type: Application
    Filed: October 11, 2013
    Publication date: September 10, 2015
    Inventors: Sam Louis Samuels, Gordon Mark Cohen, Mark David Wetzel
  • Publication number: 20150225525
    Abstract: Disclosed are fabrics and shaped articles, such as molded articles including containers and closures, tubing, films and sheets comprising ionomers that have been impregnated with antimicrobial ions such as silver or copper ions by ion exchange. The articles and fabrics have effective antimicrobial properties. Packaging materials comprising the shaped articles and other uses for the antimicrobial shaped articles and/or fabrics are also disclosed.
    Type: Application
    Filed: April 17, 2015
    Publication date: August 13, 2015
    Inventor: SAM LOUIS SAMUELS
  • Publication number: 20150158986
    Abstract: Provided herein are interlayer sheets formed of an acid copolymer composition, which comprises an acid copolymer resin or an ionomer that is the neutralized product of the acid copolymer resin. The acid copolymer resin comprises copolymerized units of an ?-olefin having 2 to 10 carbon atoms; about 10 to about 25 wt % of copolymerized units of a first ?,?-ethylenically unsaturated carboxylic acid having 3 to 10 carbon atoms; and about 15 to about 30 wt % of copolymerized units of a derivative of a second ?,?-ethylenically unsaturated carboxylic acid having 3 to 10 carbon atoms. In addition, the acid copolymer resin has a melt flow rate of about 1 to about 400 g/10 min. Light weight safety laminates comprising these interlayer sheets are characterized by good strength and superior acoustic damping, due to the properties of the acid copolymer composition.
    Type: Application
    Filed: December 4, 2014
    Publication date: June 11, 2015
    Inventors: Jingjing XU, Stephen J. BENNISON, Steven C. PESEK, Toshikazu KOBAYASHI, W. Alexander SHAFFER, Shannon D. MEERSCHEIDT, Charles Anthony SMITH, Sam Louis SAMUELS, Steven M. HANSEN, Yuki SHITANOKI, Kazuyuki NAKATA
  • Patent number: 8772624
    Abstract: The present invention provides a solar cell module comprising at least one encapsulant layer which has 1) a total thickness of from about 0.1 to about 20 mils and 2) at least one surface layer made of ionomers containing a finite amount of polymerized residues of ?-olefins and from about 18 to about 25 wt % of polymerized residues of ?,?-ethylenically unsaturated carboxylic acids. The present invention also provides a process of manufacturing the solar cell module.
    Type: Grant
    Filed: July 28, 2006
    Date of Patent: July 8, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Geraldine M. Lenges, Steven C. Pesek, Sam Louis Samuels, Charles Anthony Smith
  • Publication number: 20140182664
    Abstract: A polymeric film or sheet comprising an ionomeric composition comprising ionomeric copolymer of an alpha olefin and about 1 to about 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the ionomeric copolymer, wherein the carboxylic acid is neutralized to a level of 1 to 100 mol %, with one or more metal ions, based on the total number of moles of carboxylate groups in the ionomeric copolymer, and wherein the ionomeric copolymer has a Melt Index of about 20 to about 300 g/10 min. The ionomeric composition preferably comprises an additive selected from the group consisting of silane coupling agent, organic peroxide, and combinations thereof. In addition, an article comprising an interlayer formed of the polymeric film or sheet and an additional layer selected from the group consisting of glass, other polymeric interlayer sheets, polymeric film layers, and metal films or sheets. Examples of articles include safety windows and solar cells.
    Type: Application
    Filed: March 5, 2014
    Publication date: July 3, 2014
    Applicant: E. I. DU Pont DE Nemours And Company
    Inventors: RICHARD ALLEN HAYES, SAM LOUIS SAMUELS, MATTHEW SCOTT HALL
  • Publication number: 20140134442
    Abstract: A polymeric film or sheet comprising an acid copolymer composition comprising acid copolymer of an alpha olefin and about 1 to about 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the acid copolymer composition, wherein the acid copolymer has a Melt Index of about 75 to about 600 g/10 min. The acid copolymer composition preferably comprises an additive selected from the group consisting of silane coupling agent, organic peroxide, and combinations thereof. In addition, an article comprising an interlayer formed of the polymeric film or sheet and an additional layer selected from the group consisting of glass, other polymeric interlayer sheets, polymeric film layers, and metal films or sheets. Examples of articles include safety windows and solar cells.
    Type: Application
    Filed: January 21, 2014
    Publication date: May 15, 2014
    Applicant: E I DU PONT DE NEMOURS AND COMPANY
    Inventors: RICHARD ALLEN HAYES, SAM LOUIS SAMUELS, MATTHEW SCOTT HALL
  • Patent number: 8691372
    Abstract: A polymeric film or sheet comprising an ionomeric composition comprising ionomeric copolymer of an alpha olefin and about 1 to about 30 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the ionomeric copolymer, wherein the carboxylic acid is neutralized to a level of 1 to 100 mol %, with one or more metal ions, based on the total number of moles of carboxylate groups in the ionomeric copolymer, and wherein the ionomeric copolymer has a Melt Index of about 20 to about 300 g/10 min. The ionomeric composition preferably comprises an additive selected from the group consisting of silane coupling agent, organic peroxide, and combinations thereof. In addition, an article comprising an interlayer formed of the polymeric film or sheet and an additional layer selected from the group consisting of glass, other polymeric interlayer sheets, polymeric film layers, and metal films or sheets. Examples of articles include safety windows and solar cells.
    Type: Grant
    Filed: February 6, 2008
    Date of Patent: April 8, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Sam Louis Samuels, Matthew Scott Hall
  • Patent number: 8657993
    Abstract: A process of manufacturing a solar cell module, the process comprising: (i) providing a solar cell pre-laminate assembly comprising a solar cell component comprising one or a plurality of solar cells and an encapsulant film or sheet consisting essentially of a non-neutralized acid copolymer composition prepared from (a) non-neutralized acid copolymer of an alpha olefin and about 15 to about 23 wt % of alpha,beta-ethylenically unsaturated carboxylic acid having 3 to 8 carbons, based on the total weight of the acid copolymer, wherein the acid copolymer has a Melt Index of greater than 100 to about 600 g/10 min, and (b) about 0.01 to about 10 wt %, based upon the total weight of the acid copolymer composition, of organic peroxide; and (ii) laminating the pre-laminate assembly to form the solar cell module by subjecting the assembly to heat and, optionally, vacuum.
    Type: Grant
    Filed: December 13, 2011
    Date of Patent: February 25, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Sam Louis Samuels, Matthew Scott Hall
  • Patent number: 8637150
    Abstract: The present invention provides an acid terpolymer comprising multilayer film or sheet and safety laminates and solar cell pre-lamination assemblies comprising the same.
    Type: Grant
    Filed: October 1, 2007
    Date of Patent: January 28, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Jane Kapur, Sam Louis Samuels
  • Patent number: 8603272
    Abstract: A multilayer film comprises a layer consisting essentially of a fluorinated copolymer resin film and a layer consisting essentially of a blend of two ethylene copolymers. The first ethylene copolymer comprises copolymerized units of ethylene, optionally a first olefin having the formula CH2?C(R1)CO2R2, and a second olefin having the formula CH2?C(R3)COOH. The second ethylene copolymer consists essentially of copolymerized units of ethylene, optionally a first olefin having the formula CH2?C(R1)CO2R2, and a third olefin having the formula CH2?C(R4)D. R1, R3 and R4 represent hydrogen or an alkyl group; R2 represents an alkyl group; and D represents a moiety containing an epoxy group. The multilayer film is useful as an integrated frontsheet or backsheet for photovoltaic modules. Methods for preparing the multilayer film and the photovoltaic modules are also included.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: December 10, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: George Wyatt Prejean, Sam Louis Samuels
  • Patent number: 8598446
    Abstract: A safety laminate comprises an interlayer that comprises a crosslinkable blend of ethylene copolymers. The first ethylene copolymer comprises copolymerized units of ethylene, optionally a first olefin having the formula CH2?C(R1)CO2R2, and a second olefin having the formula CH2?C(R3)COOH. The first ethylene copolymer is optionally at least partially neutralized. The second ethylene copolymer consists essentially of copolymerized units of ethylene, optionally a first olefin having the formula CH2?C(R1)CO2R2, and a third olefin having the formula CH2?C(R4)D. R1, R3 and R4 represent hydrogen or an alkyl group; R2 represents an alkyl group; and D represents a moiety containing an epoxy group. The crosslinkable blend is useful as an interlayer in safety laminates. Methods for preparing the safety laminates are also provided.
    Type: Grant
    Filed: July 29, 2011
    Date of Patent: December 3, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: George Wyatt Prejean, Sam Louis Samuels, Alison Margaret Anne Bennett
  • Patent number: 8507097
    Abstract: A multilayer film comprises a layer consisting essentially of a fluorinated copolymer resin and a layer consisting essentially of an ethylene copolymer ionomer blend. The ethylene copolymer ionomer blend, or the product of crosslinking the blend, can be used as an encapsulant layer for solar cells, and the multilayer film is useful as a component of photovoltaic modules. Methods for preparing the multilayer films and the photovoltaic modules are also described.
    Type: Grant
    Filed: December 21, 2010
    Date of Patent: August 13, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Penny L. Perry, George Wyatt Prejean, Sam Louis Samuels
  • Patent number: 8409379
    Abstract: Disclosed is a multilayer film laminate comprising a layer consisting essentially of a fluorinated copolymer resin and a layer consisting essentially of an ethylene terpolymer. The ethylene terpolymer layer can be used as an encapsulant layer for solar cells and the multilayer laminate is useful as a component of photovoltaic modules. Methods for preparing photovoltaic modules are also included.
    Type: Grant
    Filed: July 30, 2010
    Date of Patent: April 2, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventors: Sam Louis Samuels, George Wyatt Prejean
  • Patent number: 8319094
    Abstract: The present invention provides a solar cell pre-lamination assembly comprising a terionomer multilayer film or sheet and solar cell modules prepared therefrom.
    Type: Grant
    Filed: November 16, 2007
    Date of Patent: November 27, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Jane Kapur, Sam Louis Samuels
  • Patent number: 8211264
    Abstract: Disclosed is a method for preparing a multilayer film laminate having a first film layer comprising a perfluorinated copolymer resin layer adhered to a polymeric second film layer that has been surface treated with an aminosilane. The multilayer laminate is useful as a photovoltaic module component. Methods for preparing photovoltaic modules that include the multilayer laminate are also disclosed.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: July 3, 2012
    Assignee: E I du Pont de Nemours and Company
    Inventor: Sam Louis Samuels
  • Patent number: 8211265
    Abstract: Disclosed is a method for preparing a multilayer film laminate having a first layer comprising a perfluorinated copolymer resin layer adhered to a second layer comprising an olefin ester copolymer that has been blended with an organosilane. The multilayer laminate is useful in photovoltaic modules. Methods for preparing photovoltaic modules are also included.
    Type: Grant
    Filed: June 7, 2010
    Date of Patent: July 3, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Sam Louis Samuels
  • Publication number: 20120152323
    Abstract: A multilayer film comprises a layer consisting essentially of a fluorinated copolymer resin and a layer consisting essentially of an ethylene copolymer ionomer blend. The ethylene copolymer ionomer blend, or the product of crosslinking the blend, can be used as an encapsulant layer for solar cells, and the multilayer film is useful as a component of photovoltaic modules. Methods for preparing the multilayer films and the photovoltaic modules are also described.
    Type: Application
    Filed: December 21, 2010
    Publication date: June 21, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: PENNY L. PERRY, GEORGE WYATT PREJEAN, SAM LOUIS SAMUELS
  • Publication number: 20120085482
    Abstract: A non-autoclave process of manufacturing a glass laminate comprising: (a) providing an assembly comprising (i) a first rigid sheet layer, and (ii) an interlayer sheet comprising a copolymer comprising units from an alpha olefin and about 17 weight to about 25 weight % of units from an alpha, beta-ethylenically unsaturated carboxylic acid, groups wherein about 1 to about 100 mole % of the carboxylic acid groups are neutralized with metal ions; and (b) forming the glass laminate from the assembly without use of an autoclave comprising in sequence (i) applying vacuum to the assembly; and (ii) applying heat to the assembly while still under vacuum.
    Type: Application
    Filed: December 16, 2011
    Publication date: April 12, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: Robert J. Cadwallander, Richard Allen Hayes, Steven C. Pesek, Sam Louis Samuels, Charles Anthony Smith