Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes splitting the pyrolysis gasoline into a stream comprising non-aromatic hydrocarbons and a stream comprising paraffinic hydrocarbons and aromatic hydrocarbons; aromatizing the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons, thereby converting the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX); hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX; hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and processing the second stream comprising BTX in an

Abstract: An integrated hydrotreating and hydrocracking process includes contacting a hydrocarbon oil stream with a hydrogen stream and a hydrotreating catalyst in a moving-bed hydrotreating reactor, thereby producing a hydrocarbon product stream and a spent hydrotreating catalyst; contacting the hydrocarbon product stream with a second hydrogen stream and a hydrocracking catalyst in a hydrocracking reactor, thereby producing a hydrocracked hydrocarbon product stream; processing the spent hydrotreating catalyst to produce regenerated hydrotreating catalyst; and recycling the regenerated hydrotreating catalyst to the moving-bed hydrotreating reactor.

Abstract: Processes and systems for forming olefins and aromatics from naphtha. The process includes introducing a naphtha feed stream to an adsorption unit, the adsorption unit comprising an adsorbent. N-paraffins are adsorbed from the naphtha feed stream to the adsorbent, and an iso-paraffin stream is removed from the adsorption unit. A desorbent stream is introduced into the adsorption unit, the desorbent stream comprising a desorbent, and the n-paraffins are removed from the adsorbent with the desorbent, thereby forming desorbed bottoms. The n-paraffins are collected from the desorbed bottoms, thereby forming an n-paraffin stream. The the n-paraffin stream is introduced to a steam cracking unit, and olefins and aromatics are formed from the n-paraffin stream in the steam cracking unit.

Abstract: This disclosure relates to methods of upgrading hydrocarbon feed stream, which can include separating the hydrocarbon feed stream into a heavy fraction and a light fraction, hydrotreating an aromatic feed stream with at least a first catalyst in a first reactor comprising hydrogen to produce a first product effluent, combining the heavy fraction with at least a portion of the first product effluent to form a mixed stream, and hydrotreating the mixed stream with one or more second catalysts in a second reactor comprising hydrogen to produce a second product effluent.

Abstract: A system for upgrading heavy hydrocarbon feeds, such as crude oil, include a hydrotreating unit, a hydrotreated effluent separation system, a solvent-assisted adsorption system, and a hydrocracking unit. Processes for upgrading heavy hydrocarbon feeds include hydrotreating the hydrocarbon feed to produce a hydrotreated effluent that includes asphaltenes, separating the hydrotreated effluent into a lesser boiling hydrotreated effluent and a greater boiling hydrotreated effluent comprising the asphaltenes, combining the greater boiling hydrotreated effluent with a light paraffin solvent to produce a combined stream, adsorbing the asphaltenes from the combined stream to produce an adsorption effluent, and hydrocracking the lesser boiling hydrotreated effluent and at least a portion of the adsorption effluent to produce a hydrocracked effluent with hydrocarbons boiling less than 180° C. The systems and processes increase the hydrocarbon conversion and yield of hydrocarbons boiling less than 180° C.

Abstract: An integrated hydrotreating and hydrocracking process includes contacting a hydrocarbon oil stream with a hydrogen stream and a hydrotreating catalyst in a moving-bed hydrotreating reactor, thereby producing a hydrocarbon product stream and a spent hydrotreating catalyst; contacting the hydrocarbon product stream with a second hydrogen stream and a hydrocracking catalyst in a hydrocracking reactor, thereby producing a hydrocracked hydrocarbon product stream; processing the spent hydrotreating catalyst to produce regenerated hydrotreating catalyst; and recycling the regenerated hydrotreating catalyst to the moving-bed hydrotreating reactor.

Abstract: A nano-sized mesoporous zeolite beta composition and processes for the synthesis and use of the nano-sized mesoporous zeolite beta. The nano-sized mesoporous zeolite beta is synthesized using desilication without the addition of a structure directing agent (SDA).

Abstract: In accordance with one or more embodiments of the present disclosure, a method for producing aromatic compounds from pyrolysis gasoline includes splitting the pyrolysis gasoline into a stream comprising non-aromatic hydrocarbons and a stream comprising paraffinic hydrocarbons and aromatic hydrocarbons; aromatizing the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons, thereby converting the stream comprising paraffinic hydrocarbons and aromatic hydrocarbons to a first stream comprising benzene-toluene-xylenes (BTX); hydrotreating the first stream comprising BTX in a selective hydrotreatment unit, thereby producing a de-olefinated stream comprising BTX; hydrodealkylating and transalkylating the de-olefinated stream comprising BTX in a hydrodealkylation-transalkylation unit, thereby producing a second stream comprising BTX, the second stream comprising BTX having a greater amount of benzene and xylenes than the first stream comprising BTX; and processing the second stream comprising BTX in an

Abstract: A system for upgrading heavy hydrocarbon feeds, such as crude oil, include a hydrotreating unit, a hydrotreated effluent separation system, a solvent-assisted adsorption system, and a hydrocracking unit. Processes for upgrading heavy hydrocarbon feeds include hydrotreating the hydrocarbon feed to produce a hydrotreated effluent that includes asphaltenes, separating the hydrotreated effluent into a lesser boiling hydrotreated effluent and a greater boiling hydrotreated effluent comprising the asphaltenes, combining the greater boiling hydrotreated effluent with a light paraffin solvent to produce a combined stream, adsorbing the asphaltenes from the combined stream to produce an adsorption effluent, and hydrocracking the lesser boiling hydrotreated effluent and at least a portion of the adsorption effluent to produce a hydrocracked effluent with hydrocarbons boiling less than 180° C. The systems and processes increase the hydrocarbon conversion and yield of hydrocarbons boiling less than 180° C.

Abstract: A nano-sized mesoporous zeolite beta composition and processes for the synthesis and use of the nano-sized mesoporous zeolite beta. The nano-sized mesoporous zeolite beta is synthesized using a hydrothermal treatment without drying and calcination of the zeolite prior to or after hydrothermal treatment. A process for hydrocracking a hydrocarbon feedstock using the nano-sized mesoporous zeolite beta is also provided.

Abstract: A system for upgrading heavy hydrocarbon feeds, such as crude oil, include a hydrotreating unit, a hydrotreated effluent separation system, a solvent-assisted adsorption system, and a hydrocracking unit. Processes for upgrading heavy hydrocarbon feeds include hydrotreating the hydrocarbon feed to produce a hydrotreated effluent that includes asphaltenes, separating the hydrotreated effluent into a lesser boiling hydrotreated effluent and a greater boiling hydrotreated effluent comprising the asphaltenes, combining the greater boiling hydrotreated effluent with a light paraffin solvent to produce a combined stream, adsorbing the asphaltenes from the combined stream to produce an adsorption effluent, and hydrocracking the lesser boiling hydrotreated effluent and at least a portion of the adsorption effluent to produce a hydrocracked effluent with hydrocarbons boiling less than 180° C. The systems and processes increase the hydrocarbon conversion and yield of hydrocarbons boiling less than 180° C.

Abstract: Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500° C. to 700° C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500° C. to 700° C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.

Abstract: Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500° C. to 700° C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500° C. to 700° C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.

Abstract: Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500° C. to 700° C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500° C. to 700° C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.

Abstract: According to an embodiment disclosed, a feedstock hydrocarbon may be processed by a method which may include separating the feedstock hydrocarbon into a lesser boiling point hydrocarbon fraction and a greater boiling point hydrocarbon fraction, cracking the greater boiling point hydrocarbon fraction in a high-severity fluid catalytic cracking reactor unit to form a catalytically cracked effluent, cracking the lesser boiling point hydrocarbon fraction in a steam cracker unit to form a steam cracked effluent, and separating one or both of the catalytically cracked effluent or the steam cracked effluent to form two or more petrochemical products. In one or more embodiments, the feedstock hydrocarbon may include crude oil and one of the petrochemical products may include light olefins.

Abstract: Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500° C. to 700° C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500° C. to 700° C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.

Abstract: According to an embodiment disclosed, a feedstock hydrocarbon may be processed by a method which may include separating the feedstock hydrocarbon into a lesser boiling point hydrocarbon fraction and a greater boiling point hydrocarbon fraction, cracking the greater boiling point hydrocarbon fraction in a high-severity fluid catalytic cracking reactor unit to form a catalytically cracked effluent, cracking the lesser boiling point hydrocarbon fraction in a steam cracker unit to form a steam cracked effluent, and separating one or both of the catalytically cracked effluent or the steam cracked effluent to form two or more petrochemical products. In one or more embodiments, the feedstock hydrocarbon may include crude oil and one of the petrochemical products may include light olefins.

Abstract: Methods for synthesizing acryloyl-based copolymers. The methods include providing a free radical initiator with a solution including monomeric repeating units, a chain transfer agent, and an organic solvent to form a reaction mixture, in which the monomeric repeating units include a first monomeric repeating unit having formula (1a), a second monomeric repeating unit having formula (1b) or (1d), and optionally a third monomeric repeating unit having formula (1c): in which the organic solvent is chosen from monoethylene glycol, ethanol, toluene, or combination thereof; and (B) initiating a polymerization reaction in the reaction mixture to polymerize the monomeric repeating units, thereby synthesizing the acryloyl-based copolymer. Methods for inhibiting formation of clathrate hydrates include contacting a fluid with the acryloyl-based copolymer synthesized in the reaction mixture.

Abstract: The invention relates to a process for the desulfurization of a gasoline fraction with high recovery of olefins and reduced loss of Research Octane Number (RON). A petroleum fraction is contacted with hydrogen and a commercially available hydrodesulfurization catalyst under mild conditions with to remove a first portion of the sulfur present, and is then contacted with an adsorbent for the removal of additional sulfur.

Abstract: The invention relates to a process for the desulfurization of a gasoline fraction with high recovery of olefins and reduced loss of Research Octane Number (RON). A petroleum fraction is contacted with hydrogen and a commercially available hydrodesulfurization catalyst under mild conditions with to remove a first portion of the sulfur present, and is then contacted with an adsorbent for the removal of additional sulfur.