Patents by Inventor Samir S. Ashrawi
Samir S. Ashrawi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7741264Abstract: Provided herein are compositions useful as detergents in cleaning a wide variety of substrates, including hard surfaces and laundry. The compositions contain a water-soluble polymer, which is a co-polymer between a polymerizable amide and a second, ethylenically-unsaturated monomer. The polymerizable amide itself is prepared from an amine-capped, alkoxylated alcohol by reaction with maleic acid anhydride. Compositions according to the invention show enhanced cleaning performance and beneficial anti-redeposition properties.Type: GrantFiled: January 25, 2005Date of Patent: June 22, 2010Assignee: Huntsman Petrochemical LLCInventors: George A. Smith, Duy T. Nguyen, Katie R. Hand, Samir S. Ashrawi
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Publication number: 20080261853Abstract: Provided herein are compositions useful as detergents in cleaning a wide variety of substrates, including hard surfaces and laundry. The compositions contain a water-soluble polymer, which is a co-polymer between a polymerizable amide and a second, ethylenically-unsaturated monomer. The polymerizable amide itself is prepared from an amine-capped, alkoxylated alcohol by reaction with maleic acid anhydride. Compositions according to the invention show enhanced cleaning performance and beneficial anti-redeposition properties.Type: ApplicationFiled: January 25, 2005Publication date: October 23, 2008Applicant: Huntsman Petrochemical CorporationInventors: George A. Smith, Duy T. Nguyen, Katie R. Hand, Samir S. Ashrawi
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Patent number: 7110051Abstract: Provided herein are consumer products contained in conventional containers. A consumer product packaged according to the present invention is one which exhibits birefringence, and the packaging used according to the present invention is arranged so that the consumer product is caused to exist between two layers of polarizing film and is thus capable of exhibiting the phenomenon of birefringence to consumers under ambient lighting conditions.Type: GrantFiled: March 3, 2004Date of Patent: September 19, 2006Assignee: Huntsman Petrochemical CorporationInventors: Raeda M. Smadi, Curtis M. Elsik, Samir S. Ashrawi, George A. Smith, Christopher J. Whewell
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Patent number: 7008914Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.Type: GrantFiled: October 3, 2002Date of Patent: March 7, 2006Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi, John F. Knifton, Melvin Stockton
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Patent number: 6995127Abstract: This invention is directed to detergent compositions which employ sulfonated alkyltoluenes as surfactants, wherein the sulfonated alkyltoluenes have a higher content of the sulfonated 2-phenyl alkyltoluenes isomers than was previously available in sulfonated alkyltoluene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated alkyltoluenes having lower contents of the 2-phenyl alkyltoluene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkyltoluenes are also provided, including dry cleaning formulations containing same.Type: GrantFiled: September 19, 2000Date of Patent: February 7, 2006Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi
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Patent number: 6887839Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.Type: GrantFiled: February 19, 2003Date of Patent: May 3, 2005Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
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Patent number: 6887830Abstract: Surfactant adjuvants that improve the bioefficacy of herbicides by combining known surfactancy, or wetting characteristics, of sulfosuccinate or sulfosuccinamate-based surfactants, with the proven bioefficiacy characteristics of alkoxylated amine-based surfactants. The surfactant adjuvants contain an amine-based surfactant, and a sulfosuccinate or sulfosuccinamate-based surfactant. The surfactant adjuvants are combined with herbicidal active ingredients, and optionally, one or more formulation aids to form herbicide compositions that have a reduced tendency to cause eye and skin irritation and can be used to control unwanted weeds or vegetation.Type: GrantFiled: June 18, 2002Date of Patent: May 3, 2005Assignee: Huntsman Petrochemical CorporationInventors: Howard Meyer Stridde, Samir S. Ashrawi, David Charles Lewis, Curtis Michael Elsik, Andrew Francis Kirby
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Patent number: 6849588Abstract: Provided herein are structured liquid surfactants produced using a linear alkylbenzene sulfonate having various levels of 2-isomer content.Type: GrantFiled: May 9, 2003Date of Patent: February 1, 2005Assignee: Huntsman Petrochemical CorporationInventors: Curtis M. Elsik, George A. Smith, Samir S. Ashrawi, Prakasa R. Anantaneni, Christopher J. Whewell
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Publication number: 20040186036Abstract: Provided herein are consumer products contained in conventional containers. A consumer product packaged according to the present invention is one which exhibits birefringence, and the packaging used according to the present invention is arranged so that the consumer product is caused to exist between two layers of polarizing film and is thus capable of exhibiting the phenomenon of birefringence to consumers under ambient lighting conditions.Type: ApplicationFiled: March 3, 2004Publication date: September 23, 2004Applicant: Huntsman Petrochemical CorporationInventors: Raeda M. Smadi, Curtis M. Elsik, Samir S. Ashrawi, George A. Smith, Christopher J. Whewell
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Publication number: 20040159415Abstract: Provided herein are amphoteric surfactants derived from ethyleneamines, which surfactants are useful in treating paper, fibers, textiles, hair, and human skin, to impart softness-to-the-touch properties thereto.Type: ApplicationFiled: February 18, 2003Publication date: August 19, 2004Applicant: Huntsman petrochemical corporationInventors: Duy T. Nguyen, Samir S. Ashrawi
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Publication number: 20040127742Abstract: Provided herein is a class of compounds with surfactant properties known as alcohol ether sulfonates. These materials are produced according to the present invention by reaction of isethionic acid or its halo-derivative with an alcohol. An alcohol ether sulfonate according to the invention is useful as a component of a finished surfactant formulation useful for cleaning hard surfaces, laundry, and dishes, among other things.Type: ApplicationFiled: October 21, 2003Publication date: July 1, 2004Applicant: Huntsman Petrochemical CorporationInventors: Prakasa R. Anantaneni, Samir S. Ashrawi, David C. Lewis, George A. Smith
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Publication number: 20040009882Abstract: Provided herein are structured liquid surfactants produced using a linear alkylbenzene sulfonate having various levels of 2-isomer content.Type: ApplicationFiled: May 9, 2003Publication date: January 15, 2004Applicant: Huntsman Petrochemical CorporationInventors: Curtis M. Elsik, George A. Smith, Samir S. Ashrawi, Prakasa R. Anantaneni, Christopher J. Whewell
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Publication number: 20030186831Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.Type: ApplicationFiled: February 19, 2003Publication date: October 2, 2003Applicant: Huntsman Petrochemical CorporationInventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
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Publication number: 20030166481Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.Type: ApplicationFiled: October 3, 2002Publication date: September 4, 2003Applicant: Huntsman Petrochemical CorporationInventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi, John F. Knifton, Melvin Stockton
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Patent number: 6562776Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.Type: GrantFiled: April 26, 2000Date of Patent: May 13, 2003Assignee: Huntsman Petrochemical CorporationInventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
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Publication number: 20030032558Abstract: Surfactant adjuvants that improve the bioefficacy of herbicides by combining known surfactancy, or wetting characteristics, of sulfosuccinate or sulfosuccinamate-based surfactants, with the proven bioefficiacy characteristics of alkoxylated amine-based surfactants. The surfactant adjuvants contain an amine-based surfactant, and a sulfosuccinate or sulfosuccinamate-based surfactant. The surfactant adjuvants are combined with herbicidal active ingredients, and optionally, one or more formulation aids to form herbicide compositions that have a reduced tendency to cause eye and skin irritation and can be used to control unwanted weeds or vegetation.Type: ApplicationFiled: June 18, 2002Publication date: February 13, 2003Inventors: Howard Meyer Stridde, Samir S. Ashrawi, David Charles Lewis, Curtis Michael Elsik, Andrew Francis Kirby
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Patent number: 6420311Abstract: Surfactants that are expected to further improve the bioefficacy of herbicides. The surfactants comprise esterified alkoxylated polyether diamines, alkoxylated polyether diamines, and mixtures thereof. The present invention also provides for herbicide compositions that contain the surfactants of the present invention. The herbicide compositions comprise a herbicidal active ingredient, a surfactant of the present invention, and optionally, one or more formulation aids. The present invention additionally provides for a method of controlling unwanted weeds or vegetation using the herbicide compositions of the present invention.Type: GrantFiled: August 17, 2000Date of Patent: July 16, 2002Assignee: Huntsman Petrochemical CorporationInventors: Howard Meyer Stridde, Samir S. Ashrawi
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Patent number: 5386968Abstract: De-icing compositions, such as used on aircraft wing surfaces, are found to not need thickeners to obtain acceptable holdover times. The compositions are based on an alkylene glycol component (such as propylene glycol, diethylene glycol and mixtures thereof), and obtain particular advantage when a nonionic alkylphenol ethoxylate surfactant is used in conjunction with an alkylaryl sulfonate hydrotrope, as additives. This latter combination of additives gives de-icing compositions with increased holdover times with no degradation of other properties. These compositions exhibit a Newtonian rheology as required for de-icing compositions.Type: GrantFiled: October 21, 1993Date of Patent: February 7, 1995Assignee: Texaco Chemical Inc.Inventors: David A. Coffey, Samir S. Ashrawi, Edward C. Nieh
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Patent number: 5282984Abstract: The invention is a method for generating bitumen-in-water dispersions and emulsions useful for recovering and transporting bitumen, which comprises mixing an aqueous surfactant solution with bitumen at an elevated temperature, said surfactant system comprising about 0.005% to about 5% by weight of a sulfonate surfactant represented by the formula ##STR1## wherein R is an alkyl chain of about 6 to about 16 carbon atoms, x has an average value of about 2 to about 10, y has an average value of about 1 to about 10, R' is ethylene, propylene or butylene, and M.sup.+ is an alkali metal or ammonium ion.Type: GrantFiled: January 30, 1992Date of Patent: February 1, 1994Assignee: Texaco Inc.Inventor: Samir S. Ashrawi
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Patent number: 5273673Abstract: Anti-icing compositions, such as used on aircraft wing surfaces, may be thickened using a blend of a polyacrylic acid and a copolymer of polyacrylic acid with a vinyl monomer, where the copolymer acts as a thickener modifier. Additional advantages are obtained when a low molecular weight nonionic alkylphenol ethoxylate surfactant is used in conjunction with an alkylaryl sulfonate hydrotrope, as additives. This latter combination of additives gives anti-icing compositions with increased holdover times with no degradation of other properties. The compositions also contain an alkylene glycol component, such as propylene glycol, diethylene glycol and mixtures thereof. These compositions retain a high viscosity, even when diluted with water, and exhibit a highly pseudoplastic rheology indicating desirable flow off characteristics.Type: GrantFiled: August 31, 1992Date of Patent: December 28, 1993Assignee: Texaco Chemical CompanyInventors: Samir S. Ashrawi, David A. Coffey