Patents by Inventor Samir S. Ashrawi

Samir S. Ashrawi has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7741264
    Abstract: Provided herein are compositions useful as detergents in cleaning a wide variety of substrates, including hard surfaces and laundry. The compositions contain a water-soluble polymer, which is a co-polymer between a polymerizable amide and a second, ethylenically-unsaturated monomer. The polymerizable amide itself is prepared from an amine-capped, alkoxylated alcohol by reaction with maleic acid anhydride. Compositions according to the invention show enhanced cleaning performance and beneficial anti-redeposition properties.
    Type: Grant
    Filed: January 25, 2005
    Date of Patent: June 22, 2010
    Assignee: Huntsman Petrochemical LLC
    Inventors: George A. Smith, Duy T. Nguyen, Katie R. Hand, Samir S. Ashrawi
  • Publication number: 20080261853
    Abstract: Provided herein are compositions useful as detergents in cleaning a wide variety of substrates, including hard surfaces and laundry. The compositions contain a water-soluble polymer, which is a co-polymer between a polymerizable amide and a second, ethylenically-unsaturated monomer. The polymerizable amide itself is prepared from an amine-capped, alkoxylated alcohol by reaction with maleic acid anhydride. Compositions according to the invention show enhanced cleaning performance and beneficial anti-redeposition properties.
    Type: Application
    Filed: January 25, 2005
    Publication date: October 23, 2008
    Applicant: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Duy T. Nguyen, Katie R. Hand, Samir S. Ashrawi
  • Patent number: 7110051
    Abstract: Provided herein are consumer products contained in conventional containers. A consumer product packaged according to the present invention is one which exhibits birefringence, and the packaging used according to the present invention is arranged so that the consumer product is caused to exist between two layers of polarizing film and is thus capable of exhibiting the phenomenon of birefringence to consumers under ambient lighting conditions.
    Type: Grant
    Filed: March 3, 2004
    Date of Patent: September 19, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Raeda M. Smadi, Curtis M. Elsik, Samir S. Ashrawi, George A. Smith, Christopher J. Whewell
  • Patent number: 7008914
    Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.
    Type: Grant
    Filed: October 3, 2002
    Date of Patent: March 7, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi, John F. Knifton, Melvin Stockton
  • Patent number: 6995127
    Abstract: This invention is directed to detergent compositions which employ sulfonated alkyltoluenes as surfactants, wherein the sulfonated alkyltoluenes have a higher content of the sulfonated 2-phenyl alkyltoluenes isomers than was previously available in sulfonated alkyltoluene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated alkyltoluenes having lower contents of the 2-phenyl alkyltoluene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkyltoluenes are also provided, including dry cleaning formulations containing same.
    Type: Grant
    Filed: September 19, 2000
    Date of Patent: February 7, 2006
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi
  • Patent number: 6887839
    Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.
    Type: Grant
    Filed: February 19, 2003
    Date of Patent: May 3, 2005
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
  • Patent number: 6887830
    Abstract: Surfactant adjuvants that improve the bioefficacy of herbicides by combining known surfactancy, or wetting characteristics, of sulfosuccinate or sulfosuccinamate-based surfactants, with the proven bioefficiacy characteristics of alkoxylated amine-based surfactants. The surfactant adjuvants contain an amine-based surfactant, and a sulfosuccinate or sulfosuccinamate-based surfactant. The surfactant adjuvants are combined with herbicidal active ingredients, and optionally, one or more formulation aids to form herbicide compositions that have a reduced tendency to cause eye and skin irritation and can be used to control unwanted weeds or vegetation.
    Type: Grant
    Filed: June 18, 2002
    Date of Patent: May 3, 2005
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Howard Meyer Stridde, Samir S. Ashrawi, David Charles Lewis, Curtis Michael Elsik, Andrew Francis Kirby
  • Patent number: 6849588
    Abstract: Provided herein are structured liquid surfactants produced using a linear alkylbenzene sulfonate having various levels of 2-isomer content.
    Type: Grant
    Filed: May 9, 2003
    Date of Patent: February 1, 2005
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Curtis M. Elsik, George A. Smith, Samir S. Ashrawi, Prakasa R. Anantaneni, Christopher J. Whewell
  • Publication number: 20040186036
    Abstract: Provided herein are consumer products contained in conventional containers. A consumer product packaged according to the present invention is one which exhibits birefringence, and the packaging used according to the present invention is arranged so that the consumer product is caused to exist between two layers of polarizing film and is thus capable of exhibiting the phenomenon of birefringence to consumers under ambient lighting conditions.
    Type: Application
    Filed: March 3, 2004
    Publication date: September 23, 2004
    Applicant: Huntsman Petrochemical Corporation
    Inventors: Raeda M. Smadi, Curtis M. Elsik, Samir S. Ashrawi, George A. Smith, Christopher J. Whewell
  • Publication number: 20040159415
    Abstract: Provided herein are amphoteric surfactants derived from ethyleneamines, which surfactants are useful in treating paper, fibers, textiles, hair, and human skin, to impart softness-to-the-touch properties thereto.
    Type: Application
    Filed: February 18, 2003
    Publication date: August 19, 2004
    Applicant: Huntsman petrochemical corporation
    Inventors: Duy T. Nguyen, Samir S. Ashrawi
  • Publication number: 20040127742
    Abstract: Provided herein is a class of compounds with surfactant properties known as alcohol ether sulfonates. These materials are produced according to the present invention by reaction of isethionic acid or its halo-derivative with an alcohol. An alcohol ether sulfonate according to the invention is useful as a component of a finished surfactant formulation useful for cleaning hard surfaces, laundry, and dishes, among other things.
    Type: Application
    Filed: October 21, 2003
    Publication date: July 1, 2004
    Applicant: Huntsman Petrochemical Corporation
    Inventors: Prakasa R. Anantaneni, Samir S. Ashrawi, David C. Lewis, George A. Smith
  • Publication number: 20040009882
    Abstract: Provided herein are structured liquid surfactants produced using a linear alkylbenzene sulfonate having various levels of 2-isomer content.
    Type: Application
    Filed: May 9, 2003
    Publication date: January 15, 2004
    Applicant: Huntsman Petrochemical Corporation
    Inventors: Curtis M. Elsik, George A. Smith, Samir S. Ashrawi, Prakasa R. Anantaneni, Christopher J. Whewell
  • Publication number: 20030186831
    Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.
    Type: Application
    Filed: February 19, 2003
    Publication date: October 2, 2003
    Applicant: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
  • Publication number: 20030166481
    Abstract: This invention is directed to a fluorine-containing mordenite catalyst and use thereof in the manufacture of alkylbenzene (LAB) by alkylation of benzene with an olefin. The olefin may have from about 10 to 14 carbons. The fluorine-containing mordenite is prepared typically by treatment with an aqueous hydrogen fluoride solution. The benzene alkylation may be conducted using reactive distillation. This invention is also directed to a process for production of LAB having a high 2-phenyl isomer content by use of the fluorine-containing mordenite in conjunction with a conventional solid LAB alkylation catalyst. The two catalysts may be used in a mixed catalyst bed or may be packed in series, with the relative proportions being adjusted to provide a desired 2-phenyl isomer content of in the final product.
    Type: Application
    Filed: October 3, 2002
    Publication date: September 4, 2003
    Applicant: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Prakasa R. Anantaneni, Samir S. Ashrawi, Raeda M. Smadi, John F. Knifton, Melvin Stockton
  • Patent number: 6562776
    Abstract: This invention is directed to detergent compositions which employ sulfonated linear alkylbenzenes as surfactants, wherein the sulfonated linear alkylbenzenes have a higher content of the sulfonated 2-phenyl alkylbenzene isomers than was previously available in sulfonated phenyl alkylbenzene surfactants of the prior art. Cleaning compositions according to the invention are more effective as cleaning agents over their counterparts of prior art which contain sulfonated linear alkylbenzenes having lower contents of the 2-phenyl alkylbenzene isomers, owing to an unexpected increase in tolerance of water hardness minerals normally associated with precipitation of the active detergent agent. Solid sulfonate salts of alkylbenzenes are also provided, including dry formulations containing same.
    Type: Grant
    Filed: April 26, 2000
    Date of Patent: May 13, 2003
    Assignee: Huntsman Petrochemical Corporation
    Inventors: George A. Smith, Samir S. Ashrawi, Raeda M. Smadi, Prakasa R. Anantaneni
  • Publication number: 20030032558
    Abstract: Surfactant adjuvants that improve the bioefficacy of herbicides by combining known surfactancy, or wetting characteristics, of sulfosuccinate or sulfosuccinamate-based surfactants, with the proven bioefficiacy characteristics of alkoxylated amine-based surfactants. The surfactant adjuvants contain an amine-based surfactant, and a sulfosuccinate or sulfosuccinamate-based surfactant. The surfactant adjuvants are combined with herbicidal active ingredients, and optionally, one or more formulation aids to form herbicide compositions that have a reduced tendency to cause eye and skin irritation and can be used to control unwanted weeds or vegetation.
    Type: Application
    Filed: June 18, 2002
    Publication date: February 13, 2003
    Inventors: Howard Meyer Stridde, Samir S. Ashrawi, David Charles Lewis, Curtis Michael Elsik, Andrew Francis Kirby
  • Patent number: 6420311
    Abstract: Surfactants that are expected to further improve the bioefficacy of herbicides. The surfactants comprise esterified alkoxylated polyether diamines, alkoxylated polyether diamines, and mixtures thereof. The present invention also provides for herbicide compositions that contain the surfactants of the present invention. The herbicide compositions comprise a herbicidal active ingredient, a surfactant of the present invention, and optionally, one or more formulation aids. The present invention additionally provides for a method of controlling unwanted weeds or vegetation using the herbicide compositions of the present invention.
    Type: Grant
    Filed: August 17, 2000
    Date of Patent: July 16, 2002
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Howard Meyer Stridde, Samir S. Ashrawi
  • Patent number: 5386968
    Abstract: De-icing compositions, such as used on aircraft wing surfaces, are found to not need thickeners to obtain acceptable holdover times. The compositions are based on an alkylene glycol component (such as propylene glycol, diethylene glycol and mixtures thereof), and obtain particular advantage when a nonionic alkylphenol ethoxylate surfactant is used in conjunction with an alkylaryl sulfonate hydrotrope, as additives. This latter combination of additives gives de-icing compositions with increased holdover times with no degradation of other properties. These compositions exhibit a Newtonian rheology as required for de-icing compositions.
    Type: Grant
    Filed: October 21, 1993
    Date of Patent: February 7, 1995
    Assignee: Texaco Chemical Inc.
    Inventors: David A. Coffey, Samir S. Ashrawi, Edward C. Nieh
  • Patent number: 5282984
    Abstract: The invention is a method for generating bitumen-in-water dispersions and emulsions useful for recovering and transporting bitumen, which comprises mixing an aqueous surfactant solution with bitumen at an elevated temperature, said surfactant system comprising about 0.005% to about 5% by weight of a sulfonate surfactant represented by the formula ##STR1## wherein R is an alkyl chain of about 6 to about 16 carbon atoms, x has an average value of about 2 to about 10, y has an average value of about 1 to about 10, R' is ethylene, propylene or butylene, and M.sup.+ is an alkali metal or ammonium ion.
    Type: Grant
    Filed: January 30, 1992
    Date of Patent: February 1, 1994
    Assignee: Texaco Inc.
    Inventor: Samir S. Ashrawi
  • Patent number: 5273673
    Abstract: Anti-icing compositions, such as used on aircraft wing surfaces, may be thickened using a blend of a polyacrylic acid and a copolymer of polyacrylic acid with a vinyl monomer, where the copolymer acts as a thickener modifier. Additional advantages are obtained when a low molecular weight nonionic alkylphenol ethoxylate surfactant is used in conjunction with an alkylaryl sulfonate hydrotrope, as additives. This latter combination of additives gives anti-icing compositions with increased holdover times with no degradation of other properties. The compositions also contain an alkylene glycol component, such as propylene glycol, diethylene glycol and mixtures thereof. These compositions retain a high viscosity, even when diluted with water, and exhibit a highly pseudoplastic rheology indicating desirable flow off characteristics.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: December 28, 1993
    Assignee: Texaco Chemical Company
    Inventors: Samir S. Ashrawi, David A. Coffey