Patents by Inventor Samuel A. Worcester
Samuel A. Worcester has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5242515Abstract: This is an improved method of fabricating Zircaloy-4 strip. The method is of the type wherein Zircaloy-4 material is vacuum melted, forged, hot reduced, beta-annealed, quenched, hot rolled, subjected to a post-hot-roll anneal and then reduced by at least two cold rolling steps, including a final cold rolling to final size, with intermediate annealing between the cold rolling steps and with a final anneal after the last cold rolling step. The improvement comprises: (a) utilizing a maximum processing temperature of 620.degree. C. between the quenching and the final cold rolling to final size; (b) utilizing a maximum intermediate annealing temperature of 520.degree. C.; and (c) utilizing hot rolling, post-hot-roll annealing, intermediate annealing and final annealing time-temperature combinations to give an A parameter of between 4.times.10.sup.-19 and 7.times.10.sup.Type: GrantFiled: August 21, 1992Date of Patent: September 7, 1993Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, James P. Dougherty, John P. Foster
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Patent number: 5230758Abstract: This is an alloy comprising, by weight percent, 0.5-2.0 niobium, 0.7-1.5 tin, 0.07-0.14 iron, and 0.03-0.14 of at least one of nickel and chromium, and at least 0.12 total of iron, nickel and chromium, and up to 220 ppm C, and the balance essentially zirconium. Preferably, the alloy contains 0.03-0.08 chromium, and 0.03-0.08 nickel. The alloy is also preferably subjected intermediate recrystallization anneals at a temperature of about 1200.degree.-1300.degree. F., and to a beta quench two steps prior to final size.Type: GrantFiled: March 18, 1992Date of Patent: July 27, 1993Assignee: Westinghouse Electric Corp.Inventors: John P. Foster, Robert J. Comstock, Samuel A. Worcester, George P. Sabol
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Patent number: 5194101Abstract: This is an improved method of fabricating Zircaloy-4 strip. The method is of the type wherein Zircaloy-4 material is vacuum melted, forged, hot reduced, beta-annealed, quenched, hot rolled, subjected to a post-hot-roll anneal and then reduced by at least two cold rolling steps, including a final cold rolling to final size, with intermediate annealing between the cold rolling steps and with a final anneal after the last cold rolling step. The improvement comprises: (a) utilizing a maximum processing temperature of 620.degree. C. between the quenching and the final cold rolling to final size; (b) utilizing a maximum intermediate annealing temperature of 520.degree. C.; and (c) utilizing hot rolling, post-hot-roll annealing, intermediate annealing and final annealing time-temperature combinations to give an A parameter of between 4.times.10.sup.-19 and 7.times.10.sup.Type: GrantFiled: March 16, 1990Date of Patent: March 16, 1993Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, James P. Dougherty, John P. Foster
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Patent number: 5183541Abstract: Technetium is separated from nickel by electro-refining contaminated nickel. Electrorefining controls the electrolyte solution oxidation potential to selectively reduce the technetium from the metallic feedstock solution from Tc(VII) to Tc(IV) forcing it to report to the anodic slimes and thereby preventing it from reporting to the cathodic metal product. This method eliminates the need for peripheral decontamination processes such as solvent extraction to remove the technetium prior to nickel electrorefining. These methods are particularly useful for remediating nickel contaminated by radio-contaminants such as technetium and actinides.Type: GrantFiled: October 2, 1991Date of Patent: February 2, 1993Assignee: Westinghouse Electric Corp.Inventors: Thomas S. Snyder, William R. Gass, Samuel A. Worcester, Laura J. Ayers, Gregory F. Boris
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Patent number: 5156722Abstract: Two alternate, mutually exclusive, methods of removing radio contaminants from metal are taught based respectively on electrowinning or electrorefining of the base metal. The alternative using electrorefining controls the anolyte oxidation potential to selectively reduce the technetium in the metallic feedstock solution from Tc(VII) to Tc(IV) forcing it to report to the anodic slimes preventing it from reporting to the cathodic metal product. This method eliminates the need for peripheral decontamination processes such as solvent extraction and/or ion exchange to remove the technetium prior to nickel electrorefining. The other alternative method combines solvent extraction with electrowinning. By oxidizing technetium to the heptavalent state and by using mixtures of tri-n-octyalphosphine oxide and di-2-ethyl phosphoric acid in aliphatic hydrocarbon carriers to extract the radio contaminants prior to electrowinning, the background metal may be recovered for beneficial reuse.Type: GrantFiled: July 25, 1991Date of Patent: October 20, 1992Assignee: Westinghouse Electric Corp.Inventors: Thomas S. Snyder, William R. Gass, Samuel A. Worcester, Laura J. Ayers
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Patent number: 5125985Abstract: This invention is for the processing of a somewhat broader range of compositions, including ZIRLO material. It controls creep rate in an alloy having, by weight percent, 0.5-2.0 niobium, 0.7-1.5 tin, 0.07-0.28 of at least one of iron, nickel and chromium and up to 220 ppm carbon, and the balance essentially zirconium. The method is of a type which utilizes subjecting the material to a post extrusion anneal, a series of intermediate area reductions and intermediate recrystallization anneals, with one of the intermediate recrystallization anneals possibly being a late stage beta-quench, a final pass area reduction, and a final stress relief anneal.Type: GrantFiled: May 30, 1991Date of Patent: June 30, 1992Assignee: Westinghouse Electric Corp.Inventors: John P. Foster, Samuel A. Worcester, Robert J. Comstock
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Patent number: 5112573Abstract: This is an alloy comprising, by weight percent, 0.5-2.0 niobium, 0.7-1.5 tin, 0.07-0.14 iron, and 0.03-0.14 of at least one of nickel and chromium, and at least 0.12 total of iron, nickel and chromium, and up to 220 ppm C, and the balance essentially zirconium. Preferably, the alloy contains 0.03-0.08 chromium, and 0.03-0.08 nickel. The alloy is also preferably subjected intermediate recrystallization anneals at a temperature of about 1200.degree.-1300.degree. F., and to a beta quench two steps prior to final size.Type: GrantFiled: August 28, 1989Date of Patent: May 12, 1992Assignee: Westinghouse Electric Corp.Inventors: John P. Foster, Robert J. Comstock, Samuel A. Worcester, George P. Sabol
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Patent number: 5013357Abstract: A superconductive alloy of titanium and niobium is formed during reduction of niobium pentoxide by adding an effective quantity of titanium metal and/or titanium oxide to a reduction mixture of aluminum and niobium pentoxide. The resulting mixture is reacted to form the desired niobium titanium alloy below an aluminum oxide or aluminum oxide-titanium oxide slag. The slag is easily separated from the alloy.Type: GrantFiled: October 26, 1989Date of Patent: May 7, 1991Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, Patti L. Case
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Patent number: 4849013Abstract: This is a process for making a very pure and very homogeneous material for use in lining the interior of zirconium alloy fuel element cladding. The improvement utilizes the forming of a consumable electrode from generally virgin sponge material, melting the consumable electrode in a multiple swept beam electron beam furnace with a feed rate between 1 and 20 inches per hour and then vacuum arc melting the EB melted material.Type: GrantFiled: July 30, 1987Date of Patent: July 18, 1989Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, Charles R. Woods
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Patent number: 4849016Abstract: This is a process for making a very pure and very homogeneous zirconium material for use in lining the interior of zirconium alloy fuel element cladding. The improvement utilizes the forming of consumable feed material from generally virgin sponge material, melting the consumable feed material in a multiple swept beam electron beam furnace with a feed rate generally between 0.1 and less than about 1.0 inch per hour and then vacuum arc melting the EB melted material.Type: GrantFiled: December 18, 1987Date of Patent: July 18, 1989Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, Charles R. Woods, Glenn S. Galer, Richard L. Propst
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Patent number: 4816215Abstract: This is a material for lining reactor fuel element cladding. Rather than using unalloyed zirconium, this invention utilized for a 0.1-4% tin alloy liner for the cladding. The very low metallic impurities to reduce solid solution strengthening and second phase formation and property variability from lot to lot, while using alloying to reduce the susceptibility to steam corrosion. Preferably, oxygen is controlled to a very low level as well, to provide a low, but fabricable, hardness in the alloyed liner material.Type: GrantFiled: October 22, 1987Date of Patent: March 28, 1989Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, Charles R. Woods
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Patent number: 4816214Abstract: This is a process for producing material for lining reactor fuel element claddings. Rather than using unalloyed zirconium, this invention provides for an alloy liner for the cladding. The process uses ultra-slow electron beam melting of zirconium, to give very low metallic impurities to reduce solid solution strengthening and second phase formation and property variability from lot to lot, while using alloying to reduce the susceptibility to steam corrosion. Oxygen is controlled to a very low level as well, and preferably only 0.1-0.4 tin is added to provide a low, but fabricable, hardness in the alloyed liner material.Type: GrantFiled: October 22, 1987Date of Patent: March 28, 1989Assignee: Westinghouse Electric Corp.Inventors: Samuel A. Worcester, Charles R. Woods, Glenn S. Galer, Richard L. Propst
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Patent number: 4814136Abstract: This is a process for producing material for lining reactor fuel element claddings. Rather than using unalloyed zirconium, this invention provides for an alloy liner for the cladding. The process uses electron beam melting of zirconium, to give very low metallic impurities to reduce solid solution strengthening and second phase formation and property variability from lot to lot, while using alloying to reduce the susceptibility to steam corrosion. Preferably, oxygen is controlled to a low level as well, to provide a low, but fabricable, hardness in the alloyed liner material.Type: GrantFiled: October 28, 1987Date of Patent: March 21, 1989Assignee: Westinghouse Electric Corp.Inventors: George P. Sabol, Samuel A. Worcester, John P. Foster
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Patent number: 4728507Abstract: Transition metal, notably zirconium alloy, is melted (e.g., by a plasma) to form droplets within the size range of minus 20, plus 60 mesh. The droplets are exposed to a hydrogen atmosphere for a short period while cooling through the hydriding temperature range (e.g., 600.degree. C. to 400.degree. C.). A friable particulate of uniform size and hydrogen content, suitable for sintering or forming components, is recovered.Type: GrantFiled: January 9, 1987Date of Patent: March 1, 1988Assignee: Westinghouse Electric Corp.Inventor: Samuel A. Worcester
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Patent number: 4139374Abstract: A composition of material is disclosed which comprises sintered carbide-binder metal alloys. The carbide is a solid solution of hexagonal tungsten monocarbide and molybdenum monocarbide of stoichiometric composition containing between 10 and 100 mole percent molybdenum monocarbide. The binder is selected from the metals of the iron group, and comprises between 3 and 50 weight percent of the composition. A method for making the hexagonal carbide is also disclosed.Type: GrantFiled: October 18, 1976Date of Patent: February 13, 1979Assignee: Teledyne Industries, Inc.Inventors: Stephen W. H. Yih, Samuel A. Worcester, Jr., Erwin Rudy