Patents by Inventor Samuel Neto
Samuel Neto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9688606Abstract: Process for scrubbing a crude mixture which is obtained in the nitration of toluene after separating off the nitrating acid and comprises dinitrotoluene, nitric acid, nitrogen oxides and sulfuric acid, which comprises two scrubbing steps (WS-I) and (WS-II), wherein i) in a first scrubbing step (WS-I), the crude mixture is extracted with a scrubbing acid I comprising nitric acid, nitrogen oxides and sulfuric acid in a scrub comprising at least one extraction stage, where the scrubbing acid discharged from the first extraction stage (WS-I-1) of the first scrubbing step (WS-I) has a total acid content of from 10 to 40% by weight and a content of from 80 to 350 ppm of hydrocyanic acid, giving a prescrubbed crude mixture, ii) in a second scrubbing step (WS-II), the prescrubbed crude mixture comprising dinitrotoluene is extracted with a scrubbing acid II in a scrub comprising at least one, preferably at least 2, extraction stage(s), where the scrubbing acid discharged from the first extraction stage (WS-II-1) of thType: GrantFiled: October 22, 2014Date of Patent: June 27, 2017Assignees: BASF SE, Josef Meissner GmbH & Co. KGInventors: Samuel Neto, Rüdiger Fritz, Renate Hempel, Holger Allardt, Yuan Shen Dai, Barbara Becker, Sebastian Ahrens, Julia Leschinski, Henrich Hermann, Mirko Haendel, Jürgen Pöhlmann
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Publication number: 20160251302Abstract: Process for scrubbing a crude mixture which is obtained in the nitration of toluene after separating off the nitrating acid and comprises dinitrotoluene, nitric acid, nitrogen oxides and sulfuric acid, which comprises two scrubbing steps (WS-I) and (WS-II), wherein i) in a first scrubbing step (WS-I), the crude mixture is extracted with a scrubbing acid I comprising nitric acid, nitrogen oxides and sulfuric acid in a scrub comprising at least one extraction stage, where the scrubbing acid discharged from the first extraction stage (WS-I-1) of the first scrubbing step (WS-I) has a total acid content of from 10 to 40% by weight and a content of from 80 to 350 ppm of hydrocyanic acid, giving a prescrubbed crude mixture, ii) in a second scrubbing step (WS-II), the prescrubbed crude mixture comprising dinitrotoluene is extracted with a scrubbing acid II in a scrub comprising at least one, preferably at least 2, extraction stage(s), where the scrubbing acid discharged from the first extraction stage (WS-II-1) of tType: ApplicationFiled: October 22, 2014Publication date: September 1, 2016Inventors: SAMUEL NETO, Rüdiger FRITZ, Renate HEMPEL, Holger ALLARDT, Yuan Shen DAI, Barbara BECKER, Sebastian AHRENS, Julia LESCHINSKI, Henrich HERMANN, Mirko HAENDEL, Jürgen PÖHLMANN
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Patent number: 9284257Abstract: Proposed is a separation method in a toluene to dinitrotoluene process, wherein said method with a first process step comprising feeding a toluene comprising first stream (1) and a nitric acid comprising second stream (2) into a first reactor (R1), reacting of the toluene comprising first stream (1) and the nitric acid comprising second stream (2) within the first reactor (R1) to a first reaction mixture (3), said first reaction mixture (3) comprising a first liquid/liquid mixed phase of an acid phase and an organic phase comprising mononitrotoluene, feeding the first reaction mixture (3) into a first separation device (S1), separating the first reaction mixture (3) within the first separation device (S1) into a first forward stream (4) having a flow direction to a second process step and a first backward stream (5) having a flow direction back to the first reactor (R1), said method having a second process step comprising feeding the first forward stream (4) into a second reactor (R2), feeding a nitric acid cType: GrantFiled: December 10, 2013Date of Patent: March 15, 2016Assignees: BASF SE, Shanghai BASF Polyurethane Company LimitedInventors: Yuanshen Dai, Da Peng Li, Pei Shi Jia, Zhan Cai, Samuel Neto
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Patent number: 9249083Abstract: The invention relates to a process for scrubbing a crude mixture comprising dinitrotoluene, nitric acid, nitrogen oxides and sulfuric acid obtained in the nitration of toluene after the nitrating acid has been separated off, which comprises two scrubbing steps (SS-I) and (SS-II), wherein i) in a first scrubbing step (SS-I), the crude mixture is extracted with a scrubbing acid I comprising nitric acid, nitrogen oxides and sulfuric acid in a scrub comprising at least one extraction stage, where the scrubbing acid discharged from the first extraction stage (SS-I-1) of the first scrubbing step (SS-I) has a total acid content of from 20 to 40% by weight and a prescrubbed crude mixture is obtained, ii) in a second scrubbing step (SS-II), the prescrubbed crude mixture comprising dinitrotoluene is extracted with a scrubbing acid II in a scrub comprising at least one extraction stage, where the scrubbing acid discharged from the first extraction stage (SS-II-1) of the second scrubbing step (SS-II) has a pH of lessType: GrantFiled: April 25, 2013Date of Patent: February 2, 2016Assignees: BASF SE, Josef Meissner GmbH & Co. KGInventors: Samuel Neto, Ruediger Fritz, Renate Hempel, Holger Allardt, Barbara Becker, Julia Leschinski, Sebastian Ahrens, Heinrich Hermann, Mirko Haendel, Juergen Poehlmann
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Publication number: 20150329469Abstract: Proposed is a separation method in a toluene to dinitrotoluene process, wherein said method with a first process step comprising feeding a toluene comprising first stream (1) and a nitric acid comprising second stream (2) into a first reactor (R1), re acting of the toluene comprising first stream (1) and the nitric acid comprising second stream (2) within the first reactor (R1) to a first reaction mixture (3), said first reaction mixture (3) comprising a first liquid/liquid mixed phase of an acid phase and an organic in phase comprising mononitrotoluene, feeding the first reaction mixture (3) into a first separation device (S1), separating the first reaction mixture (3) within the first separation device (S1) into a first forward stream (4) having a flow direction to a second process step and a first backward stream (5) having a flow direction back to the first reactor (R1), said method having a second process step comprising feeding the first forward stream (4) into a second reactor (R2), feeding a nitric acType: ApplicationFiled: December 10, 2013Publication date: November 19, 2015Applicants: BASF SE, SHANGHAI BASF POLYURETHANE COMPANY LIMITEDInventors: Yuanshen DAI, Da Peng LI, Pei Shi JIA, Zhan CAI, Samuel NETO
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Patent number: 9115049Abstract: A process for obtaining pure aniline contains catalytically hydrogenating nitrobenzene, to obtain a reaction mixture, separating the reaction mixture into a gas phase containing hydrogen and a liquid phase, liquid/liquid phase separating the liquid phase to obtain an aqueous phase and also crude aniline containing water as an organic phase, distillatively pre-purifying the crude aniline by removing the water via an overhead stream of a first distillation column to obtain a first bottom stream, feeding the first bottom stream as a feed stream to a pure column from which a pure aniline stream is taken off at the top and a second bottom stream containing high boilers is taken off, and passing the second bottom stream to incineration, by pumping the second bottom stream through heated pipelines and by adding methanol, ethanol, propanol, and/or acetone to the second bottom stream.Type: GrantFiled: October 4, 2013Date of Patent: August 25, 2015Assignee: BASF SEInventors: Koenraad Vandewalle, Karen Vercruysse, Leo Denissen, Filip Deberdt, Hendrik De Winne, Bart Van De Voorde, Michael Reiser, Samuel Neto
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Patent number: 8895783Abstract: The present invention relates to a continuous process for preparing at least one aromatic amine by hydrogenation of at least one nitroaromatic by means of hydrogen, where a liquid phase comprising at least the aromatic amine and a gas phase comprising at least hydrogen are present, in the presence of a catalyst suspended in the liquid phase at a temperature of from 50 to 250° C. and a pressure of from 5 to 50 bar, wherein the pressure in the reactor is kept essentially constant by continuous adaptation of the amount of hydrogen fed to the reactor, the total amount of hydrogen fed to the reactor is monitored and the introduction of the at least one nitroaromatic is interrupted if the hydrogen uptake in the reactor is not at least 50 mol % of the amount of hydrogen required for stoichiometric reaction of the at least one nitroaromatic to form the at least one aromatic amine.Type: GrantFiled: February 5, 2013Date of Patent: November 25, 2014Assignee: BASF SEInventors: Andreas Raichle, Stefanie Haase, Holgar Braunsberg, Johannes Buettner, Ulrich Penzel, Samuel Neto
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Publication number: 20140107378Abstract: A process for obtaining pure aniline contains catalytically hydrogenating nitrobenzene, to obtain a reaction mixture, separating the reaction mixture into a gas phase containing hydrogen and a liquid phase, liquid/liquid phase separating the liquid phase to obtain an aqueous phase and also crude aniline containing water as an organic phase, distillatively pre-purifying the crude aniline by removing the water via an overhead stream of a first distillation column to obtain a first bottom stream, feeding the first bottom stream as a feed stream to a pure column from which a pure aniline stream is taken off at the top and a second bottom stream containing high boilers is taken off, and passing the second bottom stream to incineration, by pumping the second bottom stream through heated pipelines and by adding methanol, ethanol, propanol, and/or acetone to the second bottom stream.Type: ApplicationFiled: October 4, 2013Publication date: April 17, 2014Applicant: BASF SEInventors: Koenraad VANDEWALLE, Karen VERCRUYSSE, Leo DENISSEN, Filip DEBERDT, Hendrik DE WINNE, Bart VAN DE VOORDE, Michael REISER, Samuel NETO
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Patent number: 8697921Abstract: The invention relates to a process for purifying crude aromatic nitro compounds which originate from the nitration of aromatic compounds, comprising the single or multiple performance of the following wash stage (a): (a) contacting the crude aromatic nitro compound (N-in) with an aqueous phase (W-res) and then separating the phases to obtain an organic phase (N-res) and an aqueous phase (W-res), wherein at least one demulsifier (D) is present in one or more of the wash stages (a).Type: GrantFiled: August 8, 2012Date of Patent: April 15, 2014Assignee: BASF SEInventors: Petra Deckert, Leo Denissen, Bart Van De Voorde, Julia Leschinski, Stefan Robert Deibel, Matthias Fankhaenel, Samuel Neto
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Patent number: 8614356Abstract: A process for preparing tolylenediamine by hydrogenating dinitrotoluene with hydrogen in the presence of a suspended catalyst in a vertically upright reactor (1), at the upper end of which is arranged a motive jet nozzle (2) through which the reaction mixture drawn off from the reactor bottom, via an external loop, is sprayed into the upper region of the reactor (1) and then flows into a central inserted tube (4) which is arranged in the longitudinal direction of the reactor, flows through the latter from the top downward and flows upward again outside the inserted tube (4) in an internal loop motion, with a heat exchanger (6) in the interior of the reactor (1), through which cooling water flows, and absorbs some of the heat of reaction as it does so, with a feed for the dinitrotoluene at the upper end of the reactor (1) and a feed for the hydrogen at the lower end of the reactor (1), and wherein, in addition to the heat exchanger (6) arranged in the interior of the reactor (1), a further heat exchanger (WType: GrantFiled: December 21, 2009Date of Patent: December 24, 2013Assignee: BASF SEInventors: Joana Coelho Tsou, Steffen Oehlenschlaeger, Ekkehard Schwab, Wolfgang Mackenroth, Hartwig Voss, Stefan Maixner, Samuel Neto, Sven Boehmeke, Frederik Van Laar
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Patent number: 8609899Abstract: The invention relates to a process for the continuous preparation of toluenediamine by liquid-phase hydrogenation of dinitrotoluene by means of hydrogen in the presence of a suspended, nickel-comprising catalyst in a reactor with a product isolation unit downstream of the reactor to give a product output from the reactor comprising a liquid phase comprising toluenediamine and dinitrotoluene, in which the nickel-comprising catalyst is suspended, wherein the concentration of dinitrotoluene in the liquid phase of the product output from the reactor in the region between the reactor and the downstream product isolation unit is set to a value in the range from 1 to 200 ppm by weight, based on the total weight of the liquid phase of the product output from the reactor.Type: GrantFiled: May 17, 2011Date of Patent: December 17, 2013Assignee: BASF SEInventors: Andreas Raichle, Joana Coelho Tsou, Samuel Neto, Ulrich Penzel, Steffen Oehlenschlaeger, Michael Zoellinger, Holgar Braunsberg, Stefanie Haase, Johannes Buettner
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Publication number: 20130211141Abstract: The present invention relates to a continuous process for preparing at least one aromatic amine by hydrogenation of at least one nitroaromatic by means of hydrogen, where a liquid phase comprising at least the aromatic amine and a gas phase comprising at least hydrogen are present, in the presence of a catalyst suspended in the liquid phase at a temperature of from 50 to 250° C. and a pressure of from 5 to 50 bar, wherein the pressure in the reactor is kept essentially constant by continuous adaptation of the amount of hydrogen fed to the reactor, the total amount of hydrogen fed to the reactor is monitored and the introduction of the at least one nitroaromatic is interrupted if the hydrogen uptake in the reactor is not at least 50 mol % of the amount of hydrogen required for stoichiometric reaction of the at least one nitroaromatic to form the at least one aromatic amine.Type: ApplicationFiled: February 5, 2013Publication date: August 15, 2013Inventors: Andreas RAICHLE, Stefanie Haase, Holgar Braunsberg, Johannes Buettner, Ulrich Penzel, Samuel Neto
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Publication number: 20130041188Abstract: The invention relates to a process for purifying crude aromatic nitro compounds which originate from the nitration of aromatic compounds, comprising the following wash stages (a1) and (a2), where each of stages (a1) and (a2) may be performed once or more than once in succession: (a1) contacting the crude aromatic nitro compound (N1-in) with a first aqueous phase (W1-in) comprising at least one base (B) and then separating the phases to obtain an organic phase (N1-res)and an aqueous phase (W1-res); and then (a2) contacting the organic phase (N1-res) obtained in stage (a1) with a second aqueous phase (W2-in) and then separating the phases to obtain a purified organic phase (N2-res) and at least one aqueous phase (W2-res), the aqueous phase used (W2-in) having a pH of 6 to 9.Type: ApplicationFiled: August 6, 2012Publication date: February 14, 2013Applicant: BASF SEInventors: Julia Leschinski, Petra Deckert, Leo Denissen, Bart Van De Voorde, Stefan Robert Deibel, Matthias Fankhänel, Samuel Neto
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Publication number: 20130041189Abstract: The invention relates to a process for purifying crude aromatic nitro compounds which originate from the nitration of aromatic compounds, comprising the single or multiple performance of the following wash stage (a): (a) contacting the crude aromatic nitro compound (N-in) with an aqueous phase (W-res) and then separating the phases to obtain an organic phase (N-res) and an aqueous phase (W-res), wherein at least one demulsifier (D) is present in one or more of the wash stages (a).Type: ApplicationFiled: August 8, 2012Publication date: February 14, 2013Applicant: BASF SEInventors: Petra DECKERT, Leo Denissen, Bart Van De Voorde, Julia Leschinski, Stefan Robert Deibel, Matthias Fankhänel, Samuel Neto
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Publication number: 20120205308Abstract: The invention relates to a process for working up wastewaters which are obtained in the purification of crude aromatic nitro compounds after the nitration of aromatic compounds, comprising the following steps: (a) single-stage or multistage washing of the crude aromatic nitro compound to obtain at least one organic phase and at least one aqueous phase, and removal of the aqueous phase or of the aqueous phases, step (a) comprising the addition of a base other than ammonia, and then (b) optional removal of organic constituents from at least a portion of the aqueous phase or aqueous phases obtained in step (a) by stripping, preferably with steam, then (c) removal of organic compounds from at least a portion of the aqueous phase or aqueous phases resulting from step (a) or step (b) by thermal and/or oxidative degradation, then (d) distillative depletion of ammonia from at least a portion of the aqueous phase or aqueous phases resulting from step (c), and then (e) optional supply of at least a portion of the aqType: ApplicationFiled: August 10, 2011Publication date: August 16, 2012Applicant: BASF SEInventors: Julia Leschinski, Leo Denissen, Ludwig E. Heck, Peter Gammer, Bart Van De Voorde, Andreas Heußler, Samuel Neto
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Publication number: 20110295039Abstract: The invention relates to a process for the continuous preparation of toluenediamine by liquid-phase hydrogenation of dinitrotoluene by means of hydrogen in the presence of a suspended, nickel-comprising catalyst in a reactor with a product isolation unit downstream of the reactor to give a product output from the reactor comprising a liquid phase comprising toluenediamine and dinitrotoluene, in which the nickel-comprising catalyst is suspended, wherein the concentration of dinitrotoluene in the liquid phase of the product output from the reactor in the region between the reactor and the downstream product isolation unit is set to a value in the range from 1 to 200 ppm by weight, based on the total weight of the liquid phase of the product output from the reactor.Type: ApplicationFiled: May 17, 2011Publication date: December 1, 2011Applicant: BASF SEInventors: Andreas Raichle, Joana Coelho Tsou, Samuel Neto, Ulrich Penzel, Steffen Oehlenschläger, Michael Zöllinger, Holgar Braunsberg, Stefanie Haase, Johannes Büttner
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Publication number: 20110275858Abstract: A process for preparing tolylenediamine by hydrogenating dinitrotoluene with hydrogen in the presence of a suspended catalyst in a vertically upright reactor (1), at the upper end of which is arranged a motive jet nozzle (2) through which the reaction mixture drawn off from the reactor bottom, via an external loop, is sprayed into the upper region of the reactor (1) and then flows into a central inserted tube (4) which is arranged in the longitudinal direction of the reactor, flows through the latter from the top downward and flows upward again outside the inserted tube (4) in an internal loop motion, with a heat exchanger (6) in the interior of the reactor (1), through which cooling water flows, and absorbs some of the heat of reaction as it does so, with a feed for the dinitrotoluene at the upper end of the reactor (1) and a feed for the hydrogen at the lower end of the reactor (1), and wherein, in addition to the heat exchanger (6) arranged in the interior of the reactor (1), a further heat exchanger (WType: ApplicationFiled: December 21, 2009Publication date: November 10, 2011Applicant: BASF SEInventors: Joana Coelho Tsou, Steffen Oehlenschlaeger, Ekkehard Schwab, Wolfgang Mackenroth, Hartwig Voss, Stefan Maixner, Samuel Neto, Sven Boehmeke, Frederik van Laar
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Patent number: 7985705Abstract: Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systems.Type: GrantFiled: February 18, 2010Date of Patent: July 26, 2011Assignee: BASF AktiengesellschaftInventors: Sebastian Storck, Jürgen Zühlke, Samuel Neto, Frank Rosowski
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Patent number: 7851398Abstract: Catalytic titanium dioxide mixtures comprising: a first anatase titanium dioxide having a BET surface area greater than 15 m2/g and a hydrogen uptake for the reduction of Ti4+ to Ti3+ of from 5 to 20 ?mol/m2; and a second anatase titanium dioxide having a BET surface area less than or equal to 15 m2/g and a hydrogen uptake for the reduction of Ti4+ to Ti3+ of from 0.6 to 7 ?mol/m2, processes for preparing catalysts containing the same, catalysts containing active compositions including such titanium dioxide mixtures on support materials, and catalyst systems using the same.Type: GrantFiled: November 16, 2005Date of Patent: December 14, 2010Assignee: BASF SEInventors: Samuel Neto, Sebastian Storck, Jürgen Zühlke, Frank Rosowski
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Publication number: 20100210857Abstract: Catalyst systems for preparing phthalic anhydride by means of gas-phase oxidation of o-xylene and/or naphthalene, and a process for preparing phthalic anhydride using the catalyst systemsType: ApplicationFiled: February 18, 2010Publication date: August 19, 2010Applicant: BASF SEInventors: Sebastian Storck, Jürgen Zühlke, Samuel Neto, Frank Rosowski