Abstract: Disclosed is an apparatus for protecting a secondary battery, in which, when the secondary battery such as a lithium-ion secondary battery is exposed to high temperature exceeding a working range due to a change in external environment, external impacts, and so on, or heated due to spontaneous generation of heat caused by internal defects, the secondary battery is discharged. The apparatus includes a thyristor or transistor having an anode and a cathode connected both terminals of the secondary battery respectively, and shorting both terminals of the secondary battery when gate current is supplied, and a temperature sensor detecting temperature of the secondary battery and supplying the gate current to the thyristor or transistor when the detected temperature is higher than predetermined temperature.

Abstract: Disclosed is a method for preparing an electrochemical device, comprising the steps of: charging an electrochemical device using an electrode active material having a gas generation plateau potential in a charging period to an extent exceeding the plateau potential; and degassing the electrochemical device. An electrochemical device, which comprises an electrode active material having a gas generation plateau potential in a charging period, and is charged to an extent exceeding the plateau potential and then degassed, is also disclosed. Some electrode active materials provide high capacity but cannot be applied to a high-capacity battery due to the gas generation. This is because a battery using such electrode active materials should be charged to an extent exceeding the gas generation plateau potential in order to realize a high capacity. To solve the problems caused by the gas generation, the battery is charged to an extent exceeding the plateau potential, and then degassed.

Abstract: Disclosed is a pretreatment method for activating an electrode active material having a certain range of potential plateau beyond a redox potential range of a transition metal forming the electrode active material, which comprises charging the electrode active material to an extent exceeding the potential plateau at least once, so as to increase capacity of the electrode active material. Also, disclosed is an electrochemical device comprising the electrode active material activated by the pretreatment method and designed to be subjected to charge/discharge cycles at a voltage lower than the potential plateau. When the electrode active material pretreated by charging it to an extent exceeding the potential plateau is subjected to charge/discharge cycles at a lower voltage, it is possible to significantly increase the capacity of the electrode active material as compared to the capacity of the non-pretreated electrode active material charged/discharged at the same voltage.

Abstract: The present invention relates to an apparatus for protecting a secondary battery by preventing overcharge of the secondary battery. The apparatus for protecting a secondary battery includes: a secondary battery; a power supply, connected with both electrode terminals of the secondary battery, for providing a charging voltage and a charging current to the secondary battery to charge the secondary battery; and a secondary battery protection unit for shorting the power supply thereby to stop charging the secondary battery if a charging voltage of the secondary battery is above a predetermined voltage.

Abstract: Disclosed is an anode active material, comprising: (a) a carbonaceous material; and (b) a carbide coating layer partially or totally formed on a surface of the carbonaceous material, the carbide coating layer comprising at least one element selected from the group consisting of metals and metalloids. An anode obtained by using the anode active material and an electrochemical device comprising the anode are also disclosed. The carbonaceous material comprises a coating layer of metal-/metalloid-carbide obtained by treating it at high temperature under inert atmosphere, wherein the coating layer has increased interfacial boding force to the carbonaceous material and thus shows minimized reactivity to lithium. The carbonaceous material as anode active material can minimize the irreversible anode capacity needed for the formation of an SEI film during the first charge/discharge cycle, thereby providing high capacity, high efficiency and significantly improved anode qualities.