Abstract: Provided is a carbon dioxide reduction composite catalyst, comprising an organic-inorganic porous body, and a molecular reduction catalyst combined with the organic-inorganic porous body, wherein the organic-inorganic porous body includes metal oxide clusters, and a light-condensing organic material as linkers between the metal oxide clusters, and the linkers absorb visible light to form excitons, and move the excitons through energy transfer between the linkers to transfer the electrons of the excitons to the molecular reduction catalyst.

Abstract: A method of fabricating the organic-inorganic hybrid coating layer includes: preparing a gel mixture including an organic precursor and colloidal silica particles; preparing a first mixed solution by heating the gel mixture; preparing a second mixed solution by adding quantum dots to the first mixed solution; and coating the second mixed solution on a substrate and irradiating light thereon to form a polymer matrix in which the organic precursor and the colloidal silica particles are crosslinked, and preparing a coating layer in which the quantum dots are dispersed in the polymer matrix, wherein the organic precursor may include at least one of dipentaerythritol pentaacrylate (DPPA) or dipentaerythritol hexaacrylate (DPHA).

Abstract: An iridium phosphorescent material comprises an iridium-containing core metal and a phenyl-pyridine ligand which is a bidentate ligand of the central metal and in which a steric hindrance phenyl group is introduced, wherein the steric hindrance phenyl is introduced at the ortho position of the phenyl group of the ligand. The present application relates to an iridium phosphorescent material comprising a phenylpyridine ligand in which a steric hindrance functional group is introduced, a method for preparing the same, and the photophysical properties of the material.

Abstract: This blue phosphorescent material includes: a central metal containing iridium; and a phenyl-imidazopyridine ligand which is a bidentate ligand of the central metal and has an iridium-carbon bond with the central metal, wherein the ligand may include a ligand in which a 2,6-dimethylphenyl functional group has been introduced to a phenyl group of the ligand. The present application relates to a blue phosphorescent material, a production method thereof, and photophysical properties thereof, the blue phosphorescent material having an iridium-carbon bond and including a phenyl-imidazopyridine ligand to which a sterically hindered functional group has been introduced.

Abstract: The present invention relates to a method for producing a core-shell structure including a CdSe core based on a glyme solvent. The method of the present invention enables the production of a core-shell structure including a CdSe core in a simple and economical manner. The present invention also relates to a core-shell structure including a CdSe core produced by the method. The core-shell structure of the present invention includes a large amount of CdSe and is uniform in size. Particularly, the core-shell structure of the present invention can be coated on a flexible plastic substrate of an optical device or semiconductor device due to its high stability.

Abstract: A carbon dioxide reducing photocatalyst is provided. The carbon dioxide reducing photocatalyst comprises: an electron receptor comprising a metal oxide; a polymer concentrator deposited on the electron receptor; and a metal catalyst deposited on the electron receptor, wherein electrons move from the polymer concentrator to the metal catalyst through the conduction band of the electron receptor if the polymer concentrator absorbs light.

Abstract: A method of fabricating the organic-inorganic hybrid coating layer includes: preparing a gel mixture including an organic precursor and colloidal silica particles; preparing a first mixed solution by heating the gel mixture; preparing a second mixed solution by adding quantum dots to the first mixed solution; and coating the second mixed solution on a substrate and irradiating light thereon to form a polymer matrix in which the organic precursor and the colloidal silica particles are crosslinked, and preparing a coating layer in which the quantum dots are dispersed in the polymer matrix, wherein the organic precursor may include at least one of dipentaerythritol pentaacrylate (DPPA) or dipentaerythritol hexaacrylate (DPHA).

Abstract: Provided is a carbon dioxide reduction composite catalyst, comprising an organic-inorganic porous body, and a molecular reduction catalyst combined with the organic-inorganic porous body, wherein the organic-inorganic porous body includes metal oxide clusters, and a light-condensing organic material as linkers between the metal oxide clusters, and the linkers absorb visible light to form excitons, and move the excitons through energy transfer between the linkers to transfer the electrons of the excitons to the molecular reduction catalyst.

Abstract: The present invention relates to a method for producing a core-shell structure including a CdSe core based on a glyme solvent. The method of the present invention enables the production of a core-shell structure including a CdSe core in a simple and economical manner. The present invention also relates to a core-shell structure including a CdSe core produced by the method. The core-shell structure of the present invention includes a large amount of CdSe and is uniform in size. Particularly, the core-shell structure of the present invention can be coated on a flexible plastic substrate of an optical device or semiconductor device due to its high stability.

Abstract: Disclosed herein is a method of preparing 1-octene at high activity and high selectivity while stably maintaining reaction activity by tetramerizing ethylene using a chromium-based catalyst system comprising a transition metal or a transition metal precursor, a cocatalyst, and a P—C—C—P backbone structure ligand represented by (R1)(R2)P—(R5)CHCH(R6)—P(R3)(R4).

Abstract: Disclosed is a hybrid catalyst system for the production of hydrogen/carbon monoxide syngas. The hybrid catalyst system includes a dye, a rhenium (Re) catalyst, and a cobalt (Co) catalyst grafted on a semiconductor metal oxide. The hybrid catalyst system can produce syngas without the aid of external energy and enables control over the ratio of hydrogen/carbon monoxide formed. Therefore, the hybrid catalyst system can find application in various industrial fields, including chemical fuel production.

Abstract: Disclosed is a catalytic system for the reduction of carbon dioxide to carbon monoxide. The catalytic system includes an iridium (Ir) photosensitizer and a TiO2/Re(I) complex catalyst. No additional process is required to anchor the molecule-based dye compound on TiO2 in the synthesis of the catalytic system. This enables the synthesis of the catalytic system in a relatively easy manner for groups of photosensitizer candidates. In addition, the catalytic system can be utilized as a platform for more easily evaluating the abilities of photosensitizers. Furthermore, the catalytic system can find application in various fields due to its ability to selectively produce carbon monoxide gas with high efficiency.

Abstract: Disclosed is a hybrid catalyst system for the production of hydrogen/carbon monoxide syngas. The hybrid catalyst system includes a dye, a rhenium (Re) catalyst, and a cobalt (Co) catalyst grafted on a semiconductor metal oxide. The hybrid catalyst system can produce syngas without the aid of external energy and enables control over the ratio of hydrogen/carbon monoxide formed. Therefore, the hybrid catalyst system can find application in various industrial fields, including chemical fuel production.

Abstract: Disclosed herein is a method of preparing 1-octene at high activity and high selectivity while stably maintaining reaction activity by tetramerizing ethylene using a chromium-based catalyst system comprising a transition metal or a transition metal precursor, a cocatalyst, and a P—C—C—P backbone structure ligand represented by (R1)(R2)P—(R5)CHCH(R6)—P(R3)(R4).

Abstract: Disclosed herein is a method of preparing 1-octene at high activity and high selectivity while stably maintaining reaction activity by tetramerizing ethylene using a chromium-based catalyst system comprising a transition metal or a transition metal precursor, a cocatalyst, and a P—C—C—P backbone structure ligand represented by (R1)(R2)P—(R5)CHCH(R6)—P(R3)(R4).

Abstract: Provided is a method for producing a high-quality boron nitride film grown by using a borazine oligomer as a precursor through a metal catalyst effect. The method solves the problems, such as control of a gaseous precursor and vapor pressure control, occurring in CVD (Chemical vapor deposition) according to the related art, and a high-quality hexagonal boron nitride film is obtained through a simple process at low cost. In addition, the hexagonal boron nitride film may be coated onto various structures and materials. Further, selective coating is allowed so as to carry out coating in a predetermined area and scale-up is also allowed. Therefore, the method may be useful for coating applications of composite materials and various materials.

Abstract: Provided is a method for producing a high-quality boron nitride film grown by using a borazine oligomer as a precursor through a metal catalyst effect. The method solves the problems, such as control of a gaseous precursor and vapor pressure control, occurring in CVD(Chemical vapor deposition) according to the related art, and a high-quality hexagonal boron nitride film is obtained through a simple process at low cost. In addition, the hexagonal boron nitride film may be coated onto various structures and materials. Further, selective coating is allowed so as to carry out coating in a predetermined area and scale-up is also allowed. Therefore, the method may be useful for coating applications of composite materials and various materials.

Abstract: This invention relates to a chromium complex compound for selective ethylene oligomerization including a chiral ligand, and to a method of selectively preparing 1-hexene or 1-octene from ethylene using the same.

Abstract: Disclosed herein is a group IV transition metal catalyst for producing an ethylene homopolymer or an ethylene-olefin copolymers, having high catalytic activity, which includes a cyclopentadiene derivative and one or more anionic ligands having an aryl group substituted with an aryl derivative at an ortho-position thereof around a transition metal, the ligands not being crosslinked to each other, a catalyst system including the group IV transition metal catalyst and an aluminoxane cocatalyst or a boron compound cocatalyst, and a method of producing ethylene homopolymers or ethylene-olefin copolymers using the catalyst system.

Abstract: Disclosed herein is a method of preparing 1-octene at high activity and high selectivity while stably maintaining reaction activity by tetramerizing ethylene using a chromium-based catalyst system comprising a transition metal or a transition metal precursor, a cocatalyst, and a P—C—C—P backbone structure ligand represented by (R1)(R2)P—(R5)CHCH(R6)—P(R3)(R4).