Abstract: The present invention relates to polyurethane foams having a polymeric foam structure including a plurality of closed cells therein; and an HFO or HCFO blowing agent, including HCFO-1233zd or HFO-1234ze. In certain aspects, the present invention relates to foam premixes, and the resulting foam structures, that include HCFO-1233zd as blowing agent used alone, or in certain aspects, in a blend with a co-blowing agent such as methyl formate.

Abstract: Provided are a thermal insulating foam comprising thermal polymer having a plurality of closed cells and a gaseous composition contained in a plurality of said closed cells, said gaseous composition comprising trans-1-chloro-3,3,3-trifluoropropene and a second component selected from the group consisting of cyclopentane, isopentane, n-pentane and combinations of two or more of these, a pour-in-place foam panel and a thermal insulating article thereof. Also provided is a polyol premix for forming the polyurethane or polyisocyanurate pure-in-place foam panel comprising a blowing agent composition comprising trans-1-chloro-3,3,3-trifluoropropene and a second component selected from the group consisting of cyclopentane, isopentane, n-pentane and combinations of two or more of these.

Abstract: A composition comprising HFC-245fa, cyclopentane, and a third solvent component, wherein the composition is in a homogenous one-phase solution state at temperatures less than the boiling temperature of the composition, and uses thereof, including as blowing agents.

Abstract: Polyurethane foams having a polymeric foam structure including a plurality of closed cells therein; and an HFO or HCFO blowing agent, including HCFO-1233zd or HFO-1234ze. In certain aspects, foam premixes, and the resulting foam structures, that include HCFO-1233zd as blowing agent used alone, or in certain aspects, in blend with a co-blowing agent such as methyl formate are disclosed.