Abstract: A sorbent for use in removing sulfur contaminants from hydrocarbon feedstocks is provided, wherein the sorbent contains zinc aluminate in an amount of at least 40 wt % (calculated as ZnAl2O4); free alumina in an amount of from about 5 wt % to about 25 wt % (calculated as Al2O3); and iron oxide in an amount of from about 10 wt % to about 30 wt % (calculated as Fe2O3); wherein each of the free alumina and iron oxide are present in non-crystalline form as determined by X-ray diffraction analysis, and a method for producing the sorbent and method for using the sorbent to reduce sulfur contaminants in hydrocarbon feedstocks.

Abstract: A sorbent for use in removing sulfur contaminants from hydrocarbon feedstocks is provided, wherein the sorbent contains zinc aluminate in an amount of at least 40 wt % (calculated as ZnAl2O4); free alumina in an amount of from about 5 wt % to about 25 wt % (calculated as Al2O3); and iron oxide in an amount of from about 10 wt % to about 30 wt % (calculated as Fe2O3); wherein each of the free alumina and iron oxide are present in non-crystalline form as determined by X-ray diffraction analysis, and a method for producing the sorbent and method for using the sorbent to reduce sulfur contaminants in hydrocarbon feedstocks.

Abstract: An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors and, especially, slurry bubble column reactors.

Abstract: A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

Abstract: An attrition resistant precipitated bulk iron catalyst is prepared from iron oxide precursor and a binder by spray drying. The catalysts are preferably used in carbon monoxide hydrogenation processes such as Fischer-Tropsch synthesis. These catalysts are suitable for use in fluidized-bed reactors, transport reactors, and, especially, slurry bubble column reactors.

Abstract: A method is provided for removal of sulfur gases and recovery of elemental sulfur from sulfur gas containing supply streams, such as syngas or coal gas, by contacting the supply stream with a catalyst, that is either an activated carbon or an oxide based catalyst, and an oxidant, such as sulfur dioxide, in a reaction medium such as molten sulfur, to convert the sulfur gases in the supply stream to elemental sulfur, and recovering the elemental sulfur by separation from the reaction medium.

Abstract: The desulfurization of petroleum distillates can be carried out by cyclic low-temperature adsorption of oxidized sulfur compounds with activated carbon followed by regeneration of the activated carbon using an organic solvent. The activated carbon used in the process is commercially available and its surface area that ranges from approximately 500 to 2000 m2/g having a substantial portion of its pores in the range between 10 to 100 Angstroms.

Abstract: The desulfurization of petroleum distillates can be carried out by cyclic low-temperature adsorption of oxidized sulfur compounds with activated carbon followed by regeneration of the activated carbon using an organic solvent. The activated carbon used in the process is commercially available and its surface area that ranges from approximately 500 to 2000 m2/g having a substantial portion of its pores in the range between 10 to 100 Angstroms.

Abstract: The demercaptanizaiton of petroleum distillates can be carried out by sorption of the mercaptan with activated carbon and oxidation of the sorbed mercaptan to disulfide at between approximately 20° C. to 55° C. The activated carbon used in the process is commercially readily available. Its surface area typically ranges from between approximately 500 to 1500 m2/g and has substantial percentage of the pores in the 10 to 100 Angstrom range.

Abstract: The demercaptanizaiton of petroleum distillates can be carried out by sorption of the mercaptan with activated carbon and oxidation of the sorbed mercaptan to disulfide at between approximately 20° C. to 55° C. The activated carbon used in the process is commercially readily available. Its surface area typically ranges from between approximately 500 to 1500 m2/g and has substantial percentage of the pores in the 10 to 100 Angstrom range.

Abstract: The desulfurization of petroleum distillates can be carried out by cyclic low-temperature adsorption of oxidized sulfur compounds with activated carbon followed by regeneration of the activated carbon using an organic solvent. The activated carbon used in the process is commercially available and its surface area that ranges from approximately 500 to 2000 m2/g having a substantial portion of its pores in the range between 10 to 100 Angstroms.

Abstract: A method for producing elemental sulfur and reduced/oxidized sulfur compounds from sulfur containing gases. The method comprises mixing a primary gas stream of sulfur-containing gases with a secondary gas stream to produce a combined gas stream having a preselected stoichiometry and contacting the combined gas stream with a catalyst at a pressure of 7 to 100 atmospheres and a temperature of 540.degree. to 700.degree. C. The catalyst is selected from the group consisting of silica, titania, alumina, sodium/alumina, zinc titanate, alumina or titania promoted with transition metals nickel, cobalt, molybdenum, tungsten, alloys and mixtures thereof and mixture of such catalysts.

Abstract: The present invention provides a zinc titanate sorbent material useful in desulfurization applications. The zinc titanate material is in the form of generally spherical particles of substantially uniform chemical distribution. The sorbent material is capable of absorbing sulfur compounds from a gaseous feed in an amount of at least about 15 weight percent based on the weight of the sorbent. The sorbent material is prepared by a process including: (a) forming a zinc oxide/titanium dioxide dry blend, (b) preparing a substantially uniform aqueous slurry comprising the zinc oxide/titanium dioxide dry blend, organic binder, and at least about 1 weight percent inorganic binder based on the solids weight of the slurry, (c) spray drying the slurry to produce substantially spherical particles, and (d) calcining the particles at a temperature of between about 750.degree. C. to about 950.degree. C. The dry blend is formed by mixing between about 0.

Abstract: A method for producing elemental sulfur and reduced/oxidized sulfur compounds from sulfur containing gases. The method comprises mixing a primary gas stream of sulfur-containing gases with a secondary gas stream to produce a combined gas stream having a preselected stoichiometry and contacting the combined gas stream with a sorbent/catalyst. The sorbent/catalyst is selected form the group consisting of silica, alumina, and other Claus-type catalysts, sodium/alumina, zinc ferrite, zinc titanate, and other mixed metal oxides, and mixtures thereof.

Abstract: Highly durable and chemically reactive zinc titanate materials are prepared in a particle size range of 50 to 400 .mu.m suitable for a fluidized-bed reactor for removing reduced sulfur species in a gaseous form by granulating a mixture of fine zinc oxide and titanium oxide with inorganic and organic binders and by optional additions of small amounts of activators such as CoO and MoO.sub.3 ; and then indurating it at 800.degree. to 900.degree. C. for a time sufficient to produce attrition-resistant granules.