Abstract: Provided are methods for forming graphene or functionalized graphene thin films. Also provided are graphene and functionalized graphene thin films formed by the methods. For example, electrophoretic deposition methods and stamping methods are used. Defect-free thin films can be formed. Patterned films can be formed. The methods can provide conformal coatings on non-planar substrates.

Abstract: A vessel for transporting a material that is solid or semi-solid at ambient temperature, includes a body having an interior surface comprising textured metal, and a superoleophobic coating on the interior surface for inhibiting the material from adhering to the interior surface, the superoleophobic coating including a nanotextured coating disposed on the textured metal and functionalized with a fluorinated compound. The superoleophobic coating facilitates flow of the material along the interior surface.

Abstract: VO2 and V2O5 nano- or micro-materials. The VO2 nano-materials and micro-materials have an M1 phase structure and oxygen stoichiometry that deviates 2% or less from theoretical stoichiometry. The VO2 nano-materials and micro-materials may doped with cation dopants and/or anion dopants. The VO2 and V2O5 nano- or micro-materials can be made by hydrothermal methods starting with V3O7.H2O nano- or micro-material. The VO2 and V2O5 nano- or micro-materials can be used as, for example, thermochromic window coatings.

Abstract: Composite nano- and micromaterials and methods of making and using same. The composite materials comprise crystalline materials (e.g., binary and ternary vanadium oxides) in an amorphous or crystalline material (e.g., oxide, sulfide, and selenide materials). The materials can be made using sol-gel processes. The composite materials can be present as a film on a substrate. The films can be formed using preformed composite materials or the composite material can be formed in situ in the film forming process. For example, films of the materials can be used in fenestration units, such as insulating glass units deployed within windows.

Abstract: A method for positioning carbon nanotubes on a substrate, the substrate including a first electrode and a second electrode thereon, the second electrode being positioned oppositely from the first electrode; the method includes: applying a first AC voltage across the first and second electrodes; providing a first resistance in series with the first AC voltage; and introducing a solution including at least one carbon nanotube; wherein, when the first AC voltage is applied through the first resistance across the first and second electrodes, the at least one carbon nanotube attaches to the first and second electrodes. Another aspect of the invention includes providing a metallic area between the first and second electrodes.

Abstract: Provided are methods for forming graphene or functionalized graphene thin films. Also provided are graphene and functionalized graphene thin films formed by the methods. For example, electrophoretic deposition methods and stamping methods are used. Defect-free thin films can be formed. Patterned films can be formed. The methods can provide conformal coatings on non-planar substrates.

Abstract: Doped nanoparticles, methods of making such nanoparticles, and uses of such nanoparticles. The nanoparticles exhibit a metal-insulator phase transition at a temperature of ?200° C. to 350° C. The nanoparticles have a broad range of sizes and various morphologies. The nanoparticles can be used in coatings and in device structures.

Abstract: The invention provides a method of functionalizing the sidewalls of a plurality of carbon nanotubes with oxygen moieties, the method comprising: exposing a carbon nanotube dispersion to an ozone/oxygen mixture to form a plurality of ozonized carbon nanotubes; and contacting the plurality of ozonized carbon nanotubes with a cleaving agent to form a plurality of sidewall-functionalized carbon nanotubes.

Abstract: The invention provides a method of functionalizing the sidewalls of a plurality of carbon nanotubes with oxygen moieties, the method comprising: exposing a carbon nanotube dispersion to an ozone/oxygen mixture to form a plurality of ozonized carbon nanotubes; and contacting the plurality of ozonized carbon nanotubes with a cleaving agent to form a plurality of sidewall-functionalized carbon nanotubes.

Abstract: The invention provides an adduct comprising a carbon nanotube and a transitional metal coordination complex, wherein the metal of the complex is attached by a covalent linkage to at least one oxygen moiety on the nanotube.

Abstract: The invention provides an adduct comprising a carbon nanotube and a transitional metal coordination complex, wherein the metal of the complex is attached by a covalent linkage to at least one oxygen moiety on the nanotube.

Abstract: The present invention provides a method of differentiating metallic carbon nanotubes from semiconducting carbon nanotubes. The method comprising providing a nanotube dispersion, wherein the nanotube dispersion comprises a plurality of carbon nanotubes, osmium tetroxide, or ruthenium tetroxide, and a solvent; and irradiating the nanotube dispersion with ultraviolet light, wherein the metallic carbon nanotubes are osmylated, or ruthenylated, thereby differentiating the metallic carbon nanotubes from the semiconducting carbon nanotubes.

Abstract: The present invention provides a fused heterostructure comprising a carbon nanotube and at least one nanocrystal, wherein the nanocrystal is attached by a covalent linkage to at least one oxygen moiety on the nanotube, and wherein there is no intermediary linker between the nanotube and the nanocrystal.

Abstract: The invention provides an adduct comprising a carbon nanotube and a transitional metal coordination complex, wherein the metal of the complex is attached by a covalent linkage to at least one oxygen moiety on the nanotube.

Abstract: The invention provides a method of functionalizing the sidewalls of a plurality of carbon nanotubes with oxygen moieties, the method comprising: exposing a carbon nanotube dispersion to an ozone/oxygen mixture to form a plurality of ozonized carbon nanotubes; and contacting the plurality of ozonized carbon nanotubes with a cleaving agent to form a plurality of sidewall-functionalized carbon nanotubes.

Abstract: The present invention provides a method of differentiating metallic carbon nanotubes from semiconducting carbon nanotubes. The method comprising providing a nanotube dispersion, wherein the nanotube dispersion comprises a plurality of carbon nanotubes, osmium tetroxide, or ruthenium tetroxide, and a solvent; and irradiating the nanotube dispersion with ultraviolet light, wherein the metallic carbon nanotubes are osmylated, or ruthenylated, thereby differentiating the metallic carbon nanotubes from the semiconducting carbon nanotubes.

Abstract: The present invention provides a fused heterostructure comprising a carbon nanotube and at least one nanocrystal, wherein the nanocrystal is attached by a covalent linkage to at least one oxygen moiety on the nanotube, and wherein there is no intermediary linker between the nanotube and the nanocrystal.

Abstract: The invention provides a method of functionalizing the sidewalls of a plurality of carbon nanotubes with oxygen moieties, the method comprising: exposing a carbon nanotube dispersion to an ozone/oxygen mixture to form a plurality of ozonized carbon nanotubes; and contacting the plurality of ozonized carbon nanotubes with a cleaving agent to form a plurality of sidewall-functionalized carbon nanotubes.

Abstract: The present invention provides a heterostructure which includes a carbon nanotube covalently linked to at least one nanocrystal. Methods for making such heterostructures, and methods for modifying the physical properties of nanotubes are also provided.

Abstract: The present invention provides a heterostructure which includes a carbon nanotube covalently linked to at least one nanocrystal. Methods for making such heterostructures, and methods for modifying the physical properties of nanotubes are also provided.