Publication number: 20220320511
Abstract: A positive electrode material for a lithium ion secondary battery containing an olivine-type phosphate-based compound represented by General Formula LixAyDzPO4 (where A is at least one selected from the group consisting of Co, Mn, Ni, Fe, Cu, and Cr, D is at least one selected from the group consisting of Mg, Ca, Sr, Ba, Ti, Zn, V, B, Al, Ga, In, Si, Ge, Sc, and Y, 0.9<x<1.1, 0<y?1.0, 0?z<1.0, 0.9<y+z<1.1) and carbon, wherein the positive electrode material includes an agglomerate wherein primary particles which consist of the olivine-type phosphate-based compound agglomerate, and the agglomerate is a dense agglomerate, wherein a volume density of the agglomerate is 70% by volume or more and 85% by volume or less of a volume density of a solid body which has the same external appearance as the agglomerate.
Type:
Application
Filed:
September 27, 2021
Publication date:
October 6, 2022
Applicant:
Sumitomo Metal Mining Co., Ltd.
Inventors:
Satoru OSHITARI, Tsutomu NOZOE
Patent number: 11228035
Abstract: A positive electrode material for a lithium ion secondary battery includes an olivine-type phosphate-based compound represented by General Formula LixAyDzPO4 and carbon, and, in transmission electron microscopic observation of a cross section of a secondary particle that is an agglomerate of primary particles of the olivine-type phosphate-based compound, a 300-point average value of filling rates of the carbon that fills insides of voids having a diameter of 5 nm or larger that are formed by the primary particles is 30 to 70%. A is any one of Co, Mn, Ni, Fe, Cu, and Cr, D is any one of Mg, Ca, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, and Y, and x, y, and z satisfy 0.9<x<1.1, 0<y?1.0, 0?z<1.0, and 0.9<y+z<1.1.
Type:
Grant
Filed:
September 24, 2020
Date of Patent:
January 18, 2022
Assignee:
SUMITOMO OSAKA CEMENT CO., LTD.
Inventors:
Satoru Oshitari, Kouji Oono, Tsutomu Nozoe
Publication number: 20210296649
Abstract: A positive electrode material for a lithium ion secondary battery includes an olivine-type phosphate-based compound represented by General Formula LixAyDzPO4 and carbon, and, in transmission electron microscopic observation of a cross section of a secondary particle that is an agglomerate of primary particles of the olivine-type phosphate-based compound, a 300-point average value of filling rates of the carbon that fills insides of voids having a diameter of 5 nm or larger that are formed by the primary particles is 30 to 70%. A is any one of Co, Mn, Ni, Fe, Cu, and Cr, D is any one of Mg, Ca, Sr, Ba, Ti, Zn, B, Al, Ga, In, Si, Ge, Sc, and Y, and x, y, and z satisfy 0.9<x<1.1, 0<y?1.0, 0?z<1.0, and 0.9<y+z<1.1.
Type:
Application
Filed:
September 24, 2020
Publication date:
September 23, 2021
Applicant:
SUMITOMO OSAKA CEMENT CO., LTD.
Inventors:
Satoru OSHITARI, Kouji OONO, Tsutomu NOZOE