Abstract: Provided is an alkyl-modified carboxyl group-containing copolymer with which a neutralized viscous liquid can be prepared which has excellent dispersibility in water, has a viscosity that does not change greatly regardless of addition of an electrolyte, and has high transparency in the presence of an electrolyte. This alkyl-modified carboxyl group-containing copolymer contains: 100 parts by mass of a (meth)acrylic acid; 1.5-4.5 parts by mass of a (meth)acrylic acid alkyl ester, in which an alkyl group has 18-24 carbon atoms; and 0-0.1 parts by mass of a compound having two or more ethylenically unsaturated groups, wherein the copolymer contains 1.5-4.5 parts by mass of a nonionic surfactant.

Abstract: There is provided a method for producing a carboxyl group-containing polymer composition that is excellent in all of the following: dispersibility in water or the like immediately after the preparation, storage stability, and the transparency of a neutral viscous solution thereof. A method for producing a carboxyl group-containing polymer composition, the carboxyl group-containing polymer composition comprising a carboxyl group-containing polymer (A) that is a copolymer of monomers comprising an ?,?-unsaturated carboxylic acid (a-1) and a compound (a-2) having at least two ethylenically unsaturated groups per molecule; and a nonionic surfactant (B), the method comprising the step of copolymerizing the monomers, wherein in the step, the nonionic surfactant (B) is added into the system when the polymerization degree of the ?,?-unsaturated carboxylic acid (a-1) has reached 70 to 100%.

Abstract: There is provided a gel composition that can be suitably used as a thickener for cosmetic preparations and the like. A gel composition comprising a neutralized product of an alkyl-modified carboxyl group-containing polymer, which is a copolymer of monomers comprising 100 parts by mass of (meth)acrylic acid (a), 2.5 to 5 parts by mass of a (meth)acrylic acid alkyl ester (b) in which the alkyl group has 18 to 24 carbon atoms, and 0.1 part by mass or less of a compound (c) having two or more ethylenically unsaturated groups; and at least one of an anionic emulsifier and a nonionic emulsifier.

Abstract: Provided is a carboxyl group-containing polymer composition which has little odor and excellent dispersibility in water, and which additionally has excellent transparency and excellent thickening properties for alcohol gels. A carboxyl group-containing polymer composition according to the present invention contains: a carboxyl group-containing polymer (A) which is a copolymer of a monomer that contains an ?,?-unsaturated carboxylic acid (a-1) and a compound (a-2) that has at least two ethylenically unsaturated groups in each molecule; and a nonionic surfactant (B). An alcohol gel A prepared by the process described below has a viscosity of 5,000 mPa·s or more at 25° C.; and the alcohol gel A has a light transmittance of 95% or more at a wavelength of 425 nm. (Preparation of alcohol gel A) First, 0.75 part by mass of the carboxyl group-containing polymer composition, 51.70 parts by mass of an ion exchange water and 96.0 parts by mass of ethanol are uniformly mixed with each other.

Abstract: Provided is an alkyl-modified carboxyl group-containing copolymer with which a neutralized viscous liquid can be prepared which has excellent dispersibility in water, has a viscosity that does not change greatly regardless of addition of an electrolyte, and has high transparency in the presence of an electrolyte. This alkyl-modified carboxyl group-containing copolymer contains: 100 parts by mass of a (meth)acrylic acid; 1.5-4.5 parts by mass of a (meth)acrylic acid alkyl ester, in which an alkyl group has 18-24 carbon atoms; and 0-0.1 parts by mass of a compound having two or more ethylenically unsaturated groups, wherein the copolymer contains 1.5-4.5 parts by mass of a nonionic surfactant.

Abstract: There is provided a gel composition that can be suitably used as a thickener for cosmetic preparations and the like. A gel composition comprising a neutralized product of an alkyl-modified carboxyl group-containing polymer, which is a copolymer of monomers comprising 100 parts by mass of (meth)acrylic acid (a), 2.5 to 5 parts by mass of a (meth)acrylic acid alkyl ester (b) in which the alkyl group has 18 to 24 carbon atoms, and 0.1 part by mass or less of a compound (c) having two or more ethylenically unsaturated groups; and at least one of an anionic emulsifier and a nonionic emulsifier.

Abstract: There is provided a gel composition that comprises a betaine-based emulsifier and can be suitably used as a thickener for cosmetic preparations and the like. A gel composition comprising a neutralized product of an alkyl-modified carboxyl group-containing polymer, which is a copolymer of monomers comprising 100 parts by mass of (meth)acrylic acid (a), 2.5 to 5 parts by mass of a (meth)acrylic acid alkyl ester (b) in which the alkyl group has 18 to 24 carbon atoms, and 0.1 part by mass or less of a compound (c) having two or more ethylenically unsaturated groups; and a betaine-based emulsifier.

Abstract: There is provided a method for producing a carboxyl group-containing polymer composition that is excellent in all of the following: dispersibility in water or the like immediately after the preparation, storage stability, and the transparency of a neutral viscous solution thereof. A method for producing a carboxyl group-containing polymer composition, the carboxyl group-containing polymer composition comprising a carboxyl group-containing polymer (A) that is a copolymer of monomers comprising an ?,?-unsaturated carboxylic acid (a-1) and a compound (a-2) having at least two ethylenically unsaturated groups per molecule; and a nonionic surfactant (B), the method comprising the step of copolymerizing the monomers, wherein in the step, the nonionic surfactant (B) is added into the system when the polymerization degree of the ?,?-unsaturated carboxylic acid (a-1) has reached 70 to 100%.

Abstract: There is provided a carboxyl group-containing polymer composition having excellent water solubility and aqueous solution-thickening properties, having a minimal change in viscosity due to the thermal history in a drying step, and having high transparency of a neutral viscous solution obtained by mixing with water. The carboxyl group-containing polymer composition comprises (A) a carboxyl group-containing polymer obtained by copolymerization of an ?,?-unsaturated carboxylic acid (a1) and a compound (a2) having at least two or more ethylenically unsaturated groups per molecule; (B) a polyhydric alcohol fatty acid ester alkylene oxide adduct; and (C) a polyoxyalkylene modified product, which is at least one of an ether (c1) of a polyoxyalkylene with a fatty alcohol, and a polyoxyalkylene fatty acid ester (c2).

Abstract: There is provided a carboxyl group-containing polymer composition having excellent water solubility and aqueous solution-thickening properties, having a minimal change in viscosity due to the thermal history in a drying step, and having high transparency of a neutral viscous solution obtained by mixing with water. The carboxyl group-containing polymer composition comprises (A) a carboxyl group-containing polymer obtained by copolymerization of an ?,?-unsaturated carboxylic acid (a1) and a compound (a2) having at least two or more ethylenically unsaturated groups per molecule; (B) a polyhydric alcohol fatty acid ester alkylene oxide adduct; and (C) a polyoxyalkylene modified product, which is at least one of an ether (c1) of a polyoxyalkylene with a fatty alcohol, and a polyoxyalkylene fatty acid ester (c2).