Abstract: The present invention relates to a method for inhibiting high temperature of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of phosphorous acid, typically up to 1000 wppm, to the metal surface.

Abstract: The invention relates to processes for treating acidic crudes or fractions thereof to reduce or eliminate their acidity and corrosivity by addition of suitable amounts of Group IA or Group IIA oxides, hydroxides and hydrates and Group IIA metal naphthenate salts. The process has the additional benefits of reducing materials handling problems associated with treating acidic crude oils using liquid solvents and in reducing emulsion formation.

Abstract: The present invention relates to a method for inhibiting corrosion of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of certain sulfur and phosphorus-free aromatic compounds substituted with nitrogen, containing functional groups at the 5- or 3, 5-position, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of 4-sulfophthalic acid, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of an additive aromatic compound tri-substituted with acidic functionalities selected from 5-hydroxyisophthalic acid and 1,3,5-benzenetricarboxylic acid, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of triphenylstibine, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of an additive aromatic compound tri-substituted with acidic functionalities selected from 5-hydroxyisophthalic acid and 1,3,5-benzenetricarboxylic acid, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of 4-sulfophthalic acid, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting corrosion of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of certain sulfur and phosphorus-free aromatic compounds substituted with nitrogen, containing functional groups at the 5- or 3, 5-position, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature of corrosion-prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of phosphorous acid, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention relates to a method for inhibiting high temperature corrosion of corrosion prone metal surfaces by organic acid-containing petroleum streams by providing an effective corrosion-inhibiting amount of triphenylstibine, typically up to 1000 wppm, to the metal surface.

Abstract: The present invention is a process to remove a +2 ionic charged, organically bound metal from a petroleum feed. The process includes contacting feed with aqueous carbon dioxide in the essential absence for emulsion formation.

Abstract: The invention relates to a process for treating naphthenic acid containing whole crudes or fraction thereof to reduce or eliminate their acidity by contacting the acidic whole crude or fractions thereof at a suitable temperature typically of less than 200.degree. C. with a neutralizing amount typically from 0.25:1 up to 10:1 of overbased detergent. The process has the additional benefits of reducing materials handling problems associated with emulsion formation in treated crudes.

Abstract: The invention relates to processes for treating acidic crudes of fractions thereof to reduce or eliminate their acidity and corrosivity by addition of suitable amounts of Group IA of Group IIA oxides, hydroxides and hydrates. The process has the additional benefits of reducing materials handling problems associated with treating acidic crude oils using liquid solvents and in reducing emulsion formation.

Abstract: The viscosity of hydrocarbon feeds in reduced from crudes or crude by thermal treatment.

Abstract: The invention comprises a method for reducing the amount of carboxylic acids in petroleum feeds comprising the steps of (a) adding to said petroleum feed a catalytic agent comprising an oil soluble or oil dispersible compound of a metal selected from the group consisting of Group VB, VIB, VIIB and VIII metals, wherein the amount of metal in said petroleum feed is at least about 5 wppm, (b) heating said petroleum feed with said catalytic agent in a reactor at a temperature of about 400 to about 800.degree. F. (about 204.44 to about 426.67.degree. C.) and a pressure of about atmospheric to about 1000 psig (about 6996.33 kPa) in the substantial absence of hydrogen, and (c) sweeping the reactor containing said petroleum feed and said catalytic agent with an inert gas to maintain the combined water and carbon dioxide partial pressure below about 50 psia (344.75 kPa).

Abstract: The invention comprises a method for reducing the amount of carboxylic acids in petroleum feeds comprising the steps of (a) adding to said petroleum feed a catalytic agent comprising an oil soluble or oil dispersible compound of a metal selected from the group consisting of Group VB, VIB, VIIB and VIII metals, wherein the amount of metal in said petroleum feed is at least about 5 wppm, (b) heating said petroleum feed with said catalytic agent in a reactor at a temperature of about 400 to about 800.degree. F. (about 204.44 to about 426.67.degree. C.), under a hydrogen pressure of 15 psig to 1000 psig (204.75 to 6996.33 kPa), and (c) sweeping the reactor containing said petroleum feed and said catalytic agent with hydrogen-containing gas at a rate sufficient to maintain the combined water and carbon dioxide partial pressure below about 50 psia (about 344.75 kPa).

Abstract: The instant invention is directed to a process for reducing organic acids in petroleum feeds containing organic acids comprising: (a) thermally treating a petroleum feed containing organic acids in a thermal reaction zone comprising a plurality of stages in series, at a temperature and pressure sufficient to decompose at least a portion of said organic acids while sweeping said plurality of stages with an inert gas, to produce a volatile organic acid containing hydrocarbon fraction and a non-volatile hydrocarbon fraction; (b) treating said volatile hydrocarbon fraction to neutralize at least a portion of said organic acids therein and to produce a treated volatile hydrocarbon fraction; (c) collecting said non-volatile hydrocarbon fraction from said thermal reaction zone; and (d) blending said treated volatile hydrocarbon fraction of step (b) with said collected non-volatile hydrocarbon fraction.

Abstract: Petroleum acids, e.g., naphthenic acids, are removed from crudes or crude fractions by thermal treatment.