Abstract: A flow analysis system or flow injection analysis system, providing a high detection sensitivity even when metallic elements contained in a sample are of extreme trace in amount, wherein a sealed vessel in which a reagent solution is encapsulated is composed of a material having an oxygen permeability of 10 fmol/m2.s.Pa (2 cc/m2.d.atm) or less.

Abstract: [Problems] In a method of real-time/inline detection of an ultratrace metallic element contained in a sample liquid, to provide a means for enabling detection based on new combinations of samples and pretreatment liquids, which has not been possible heretofore at a high sensitivity. [Means for Solving] A method of real-time/inline detection of an ultratrace metallic element contained in a sample liquid, comprising a sampling step of sampling from the sample liquid, a pretreatment step of treating the sample with a pretreatment liquid, and an analyzing step of analyzing the metallic element in a treated liquid that has passed through the pretreatment step, wherein the sample, the pretreatment liquid and/or the treated liquid are cooled, if an exothermic reaction is involved in the pretreatment step.

Abstract: A flow analysis system or flow injection analysis system, providing a high detection sensitivity even when metallic elements contained in a sample are of extreme trace in amount, wherein a sealed vessel in which a reagent solution is encapsulated is composed of a material having an oxygen permeability of 10 fmol/m2·s·Pa (2 cc/m2·.d.atm) or less.