Abstract: A coated substrate is disclosed. The coated substrate includes a substrate; an undercoating layer comprising at least one layer selected from a mixture of silica and zirconia; a mixture of silica and alumina; or a mixture of silica, alumina and titania overlaying at least a portion of the substrate; and a functional coating overlaying at least a portion of the undercoating. The coated substrates of the invention exhibit improved properties such as increased durability, photocatalytic activity, etc. as a result of the undercoating layer.

Abstract: A method for forming a coated substrate is disclosed. The method comprises depositing an undercoating layer and depositing a functional coating comprising a material which can be present in more than one crystal structure over the undercoating layer, wherein there is a critical deposition thickness at which the functional coating transforms from a first polycrystalline film made up predominantly of the material having a first crystal structure to a second polycrystalline film made up predominantly of the same material having a second crystal structure.

Abstract: A method for forming a coated substrate is disclosed. The method includes depositing an undercoating layer on a substrate; and depositing a functional coating on the undercoating layer, the functional coating comprising at least one material that can be present in at least two crystal structures, wherein the at least two crystal structures are present at and exposed surface of the functional coating, wherein the undercoating layer comprises at least two different materials wherein a first material at the exposed surface provides a first surface area and a second different material at the exposed surface provides a second surface area.

Abstract: A display system includes at least one light emitting material having an absorption band carried on a support, wherein the support is a laminated article having a first ply and a second ply; and a projection assembly having an electromagnetic radiation source, the projection assembly configured to direct radiation of one or more selected wavelengths within the absorption band of the light emitting material toward the light emitting material to cause at least a portion of the light emitting material to emit light. The support can be an automotive transparency, a commercial window, a residential window, a commercial sign, an advertising display, and an insulating glass unit. The light emitting material is fluorescent materials, phosphorescent materials, and mixtures thereof.