Patent number: 9546319
Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor having the formula M1?x?y?zZzAaBbCcDdEeN4?nOn:ESxREy (I), with M=selected from the group consisting of Ca, Sr, and Ba; Z=selected from the group consisting of monovalent Na, K, and Rb; A=selected from the group consisting of divalent Mg, Mn, Zn, and Cd; B=selected from the group consisting of trivalent B, Al and Ga; C=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; D=selected from the group consisting of monovalent Li, and Cu; E=selected for the group consisting of P, V, Nb, and Ta; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; 0?x?0.2; 0?y?0.2; 0<x+y?0.4; 0?z<1; 0?n?0.5; 0?a?4 (such as 2?a?3); 0?b?4; 0?c?4; 0?d?4; 0?e?4; a+b+c+d+e=4; and 2a+3b+4c+d+5e=10?y?n+z.
Type:
Grant
Filed:
May 9, 2013
Date of Patent:
January 17, 2017
Assignee:
Koninklijke Philips N.V.
Inventors:
Peter Josef Schmidt, Frauke Charlotte Hintze, Philipp Alexander Hubert Pust, Volker Weiler, Cora Sieglinde Hecht, Sebastian Florian Schmiechen, Wolfgang Schnick, Detlef Uwe Wiechert
Publication number: 20160244664
Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor having the formula M1?y?zZzAaBbCcDdEeN6?nOn:ESx,REy (I), with M=selected from the group consisting of divalent Ca, Sr, and Ba; Z=selected from the group consisting of monovalent Na, K, and Rb; B=selected from the group consisting of divalent Mg, Mn, Zn, and Cd; C=selected from the group consisting of trivalent B, Al and Ga; D=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; A=selected from the group consisting of monovalent Li, and Cu; E=selected for the group consisting of P, V, Nb, and Ta; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; 0?x?0.2; 0?y?0.2; 0<x+y?0.4; 0?z<1;x+y+z<1; 0?n?0.75; 0?a?2 (such as 0?b?0.5); 0?b?2; 0?c?4; 0?d?4; 0?e?4; a+b=2; c+d+e=4; and a+2b+3c+4d+e+y?z=16?n.
Type:
Application
Filed:
September 23, 2014
Publication date:
August 25, 2016
Inventors:
Andreas Tücks, Baby-Seriyati Schreinemacher, Peter Josef Schmidt, Sebastian Florian Schmiechen, Wolfgang Schnick
Publication number: 20150123155
Abstract: The invention provides, amongst others for application in a lighting unit, a phosphor having the formula M1?x?y?zZzAaBbCcDdEeN4?nOn:ESxREy (I), with M=selected from the group consisting of Ca, Sr, and Ba; Z=selected from the group consisting of monovalent Na, K, and Rb; A=selected from the group consisting of divalent Mg, Mn, Zn, and Cd; B=selected from the group consisting of trivalent B, Al and Ga; C=selected from the group consisting of tetravalent Si, Ge, Ti, and Hf; D=selected from the group consisting of monovalent Li, and Cu; E=selected for the group consisting of P, V, Nb, and Ta; ES=selected from the group consisting of divalent Eu, Sm and Yb; RE=selected from the group consisting of trivalent Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, and Tm; 0?x?0.2; 0?y?0.2; 0<x+y?0.4; 0?z<1; 0?n?0.5; 0?a?4 (such as 2?a?3); 0?b?4; 0?c?4; 0?d?4; 0?e?4; a+b+c+d+e=4; and 2a+3b+4c+d+5e=10?y?n+z.
Type:
Application
Filed:
May 9, 2013
Publication date:
May 7, 2015
Inventors:
Peter Josef Schmidt, Frauke Charlotte Hintze, Philipp Alexander Hubert Pust, Volker Weiler, Cora Sieglinde Hecht, Sebastian Florian Schmiechen, Wolfgang Schnick, Detlef Uwe Wiechert