Abstract: Polycyclocarbonate compounds and upgraded molecular weight polymers made from such compounds are provided. The polymers have particular utility in coating compositions, especially for use on food and beverage contact substrates that are formed into or will be formed into containers or container components.

Abstract: A coated food or beverage contact article that has been or will be ibrmed into a food or beverage container or container component, a method for making such containers or container components, coating compositions and polymers for use in such article or method. The coating composition comprises a polymer derived from or derived from or derivable from a polyphenol having two or more phenylene rings linked to or through an aliphatic or cycloaliphatic group or groups, wherein the polyphenol is a reaction product of a monophenol with a polyolefinic terpene. The polyphenol may be a diphenol and a reaction product of a monophenol with a diolefinic terpene. The terpene may be a cyclic terpene.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: A coating composition is provided that is useful in coating metal substrates such as interior and/or exterior surfaces of food or beverage cans. In preferred embodiments, the coating composition is formulated using a physical blend of a preformed resin system and an alkali-soluble resin additive.

Abstract: The disclosure provides a resin having unsaturated functionality effective for self-cross linking in compositions that are at least substantially free of external cross linkers and still achieve desired performance for internal and/or external food or beverage can coating applications. Unsaturation may be provided by reactants having a carbon-carbon double bond less reactive than a carbon-carbon double bond of maleic anhydride.

Abstract: Water-dispersible or water-dispersed polymers are made by reacting (i) an unsaturated monomer containing one or more cyclic carbonate groups, or (ii) an unsaturated or saturated oligomer or polymer containing a plurality of cyclic carbonate groups, with a tertiary amine in the presence of an acid, or with an acid in the presence of a tertiary amine, or in the presence of an acid and a tertiary amine, to provide a water-dispersible or water-dispersed monomer, oligomer or polymer. When step a) provides a monomer or oligomer, the monomer or oligomer is reacted with one or more monomers in the presence of an initiator to provide a water-dispersible or water-dispersed polymer. When step a) provides a polymer, the polymer is optionally used to support emulsion polymerization of one or more unsaturated monomers in the presence of an initiator to provide a water-dispersible or water-dispersed further polymer.

Abstract: An aqueous coating composition is provided that is preferably substantially free of bisphenol A. The coating composition is preferably a latex-based coating composition that includes a latex polymer formed from ingredients including an anionic and/or zwitterionic surfactant that includes one or more acid groups neutralized with a metallic base. The coating composition is useful in coating metal substrates such as, for example, interior and/or exterior surfaces of food or beverage containers.

Abstract: This invention provides a coating composition that contains an aromatic adhesion promoter. Containers and other articles comprising the coatings and methods of making such containers and other articles are also provided. The invention further provides compositions including the adhesion promoter, which have utility in a variety of coating end uses, including, for example, valve and pipe coatings.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes a latex copolymer and a metal drier or crosslinking agent. The latex copolymer is a reaction product of monomers that include (a) one or more styrene-mimicking monomers containing one or more cyclic groups and one or more ethylenically-unsaturated groups, at least a portion of such styrene-mimicking monomers being polycyclic monomers containing ring unsaturation, and (b) one or more other ethylenically-unsaturated monomers. Preferably, the coating composition is substantially free of each of BPA, PVC, other halogenated monomers, and optionally styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: The present disclosure provides a coating composition useful as a coating on food cans, and particularly as interior white or gold food can coatings. The coating composition includes a polyester polymer preferably having a number average molecular weight (Mn) of less than 10,000, a glass transition temperature (Tg) of more than 60° C., and a hydroxyl value greater than 10 mg KOH/g resin. The polyester preferably includes one or more cyclic groups selected from a monocyclic group having five ring members or less, a polycyclic group, or both, preferably in a backbone of the polyester polymer.

Abstract: Coated articles, methods and coating compositions containing (a) a crosslinkable carboxyl-functional acrylic polymer made by polymerizing monomers including acidic monomer, multi-ethylenically unsaturated monomer and optional styrene or substituted styrene, and (b) a nitrogen-containing carboxyl-reactive crosslinking agent such as a beta-hydroxyalkylamide or beta-hydroxyalkylurea compound. The coating composition is useful in coating metal substrates including interior or exterior surfaces of food or beverage cans. The cured coating compositions can exhibit both good flexibility and high Tg.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more mono-unsaturated monomers that are cross-linked with one or more multi-unsaturated monomers. The method also includes heating the sprayed coating composition to cure the coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: Coated articles, methods and coating compositions containing (a) a crosslinkable carboxyl-functional acrylic polymer made by polymerizing monomers including acidic monomer, multi-ethylenically unsaturated monomer and optional styrene or substituted styrene, and (b) a nitrogen-containing carboxyl-reactive crosslinking agent such as a beta-hydroxyalkylamide or beta-hydroxyalkylurea compound. The coating composition is useful in coating metal substrates including interior or exterior surfaces of food or beverage cans. The cured coating compositions can exhibit both good flexibility and high Tg.

Abstract: An article, comprising a food or beverage container, or a portion thereof, that includes a metal substrate and a coating disposed on at least a portion of the metal substrate. The coating is preferably formed from a coating composition that comprises a latex emulsion having a first-stage emulsion polymerized copolymer and a second-stage emulsion polymerized copolymer.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more mono-unsaturated monomers that are cross-linked with one or more multi-unsaturated monomers. The method also includes heating the sprayed coating composition to cure the coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes a latex copolymer and a metal drier or crosslinking agent. The latex copolymer is a reaction product of monomers that include (a) one or more styrene-offset monomers containing one or more cyclic groups and one or more ethylenically-unsaturated pendant groups, at least a portion of such styrene-offset monomers being polycyclic monomers containing ring unsaturation, and (b) one or more other ethylenically-unsaturated monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: Di(amido(alkyl)phenol) compounds and upgraded molecular weight polymers made from such compounds have particular utility in coating compositions, especially for use on food and beverage contact substrates that are formed into or will be formed into containers or container components.

Abstract: A method of forming a coating on a food or beverage container, which includes spraying a coating composition onto an interior surface of the food or beverage container, where the coating composition includes an emulsion-polymerized latex copolymer having copolymer chains of one or more ethylenically-unsaturated monomers and one or more styrene offset monomers. Preferably, the coating composition is substantially free of BPA, PVC, and styrene. The method may also include curing the sprayed coating composition, thereby providing the coating on the interior surface of the food or beverage container.

Abstract: Water-dispersible or water-dispersed polymers are made by reacting (i) an unsaturated monomer containing one or more cyclic carbonate groups, or (ii) an unsaturated or saturated oligomer or polymer containing a plurality of cyclic carbonate groups, with a tertiary amine in the presence of an acid, or with an acid in the presence of a tertiary amine, or in the presence of an acid and a tertiary amine, to provide a water-dispersible or water-dispersed monomer, oligomer or polymer. When step a) provides a monomer or oligomer, the monomer or oligomer is reacted with one or more monomers in the presence of an initiator to provide a water-dispersible or water-dispersed polymer. When step a) provides a polymer, the polymer is optionally used to support emulsion polymerization of one or more unsaturated monomers in the presence of an initiator to provide a water-dispersible or water-dispersed further polymer.