Abstract: A lithium battery comprises at least a positive electrode containing a material whose lithium insertion and deinsertion potential is lower than or equal to 3.5 Volts in relation to the potential of the Li+/Li couple, a negative electrode and a non-aqueous electrolyte disposed between the positive and negative electrodes. The electrolyte comprises at least a lithium salt dissolved in an aprotic organic solvent wherein a polymerizable additive is added, chosen from carbazol and the derivatives thereof and being used to prevent the battery from operating as soon as the voltage at the terminal connections of the battery reaches a value resulting in polymerization of the additive.

Abstract: The invention relates to a lithium battery, comprising at least one lithium intercalation compound, made up of crystallites and obtained by a production method, comprising at least the following steps: formation of a homogeneous mixture of at least one precursor for the lithium intercalation compound with a given adjunct, chemically stable with relation to crystallites and designed to limit the growth of crystallites or crystallite precursors during the formation thereof, thermal treatment of the homogeneous mixture for the synthesis of the lithium intercalation compound in the form of crystallites and to give a composite material comprising at least two phases formed respectively by the lithium intercalation compound and the adjunct and forming of the composite material to give said electrode. The invention further relates to an electrode obtained by said method and lithium battery comprising such an electrode.

Abstract: A separator for a battery in lithium. The separator is a thick membrane, of around 60 to 120 ?m in polyvinylidene fluoride copolymer, which has considerable porosity, of around 50 to 90%, with pores of size between 1 and 10 ?m. With these characteristics, it is possible to optimize the operation of a battery with an electrode in, e.g., Li4Ti5O12, in particular for rapid charges and discharges, in other words in power applications.

Abstract: The electrodes are formed by surface coating and cold compression on metal strips. They are then assembled, by hot pressing, with an electrolytic membrane. The metal strips are then removed, preferably by mechanical detachment. Current collectors are then formed on each of the electrodes by PVD type techniques that are conventional in microelectronics. The resulting thin micro-battery with high surface capacity can then be integrated in an integrated circuit, in particular by bonding by means of indium connecting balls.

Abstract: Process for the preparation of an insertion compound of an alkali metal in which the following successive stages are carried out: a) an organic complex of a transition metal or of a mixture of transition metals M in an oxidation state of greater than 2 is brought into contact with an alkali metal A in the ionic form and with an entity of formula Hb (XO4), where X is chosen from Si, S, Al, P, Ge, As or Mo and b has a value from 0 to 5, in a liquid medium in a closed chamber; the chamber is brought to a temperature T which makes possible the decomposition of the organic complex in the the said liquid medium; the temperature and the pressure in the chamber are brought back to ambient temperature and atmospheric pressure and the insertion compound for an alkali metal of formula AMXO4, in which M is in the +2 oxidation state, is recovered.

Abstract: The subject of the present invention is a lithium electrochemical generator comprising two peripheral electrodes—one positive and the other negative—each comprising an electrically conductive substrate (13, 21) and an active layer (14, 20) that includes an active material, at least one bipolar electrode comprising a positive active layer (18) on a first electrically conductive substrate and a negative active layer (16) on a second electrically conductive substrate, the said substrates being fixed together and two separators (15, 19) flanking each bipolar electrode, in which generator the electrically conductive substrates of each bipolar electrode are made of identical or different materials chosen from aluminium and its alloys and the negative active material of the bipolar electrode prevents an aluminium alloy being obtained with the electrically conductive substrates, under the operating conditions of the storage battery.

Abstract: The electrodes (1, 3) are formed by surface coating and cold compression on metal strips (2, 4). They are then assembled, by hot pressing, with an electrolytic membrane (5). The metal strips (2, 4) are then removed, preferably by mechanical detachment. Current collectors are then formed on each of the electrodes by PVD type techniques that are conventional in microelectronics. The resulting thin micro-battery with a high surface capacity can then be integrated in an integrated circuit, in particular by bonding by means of indium connecting balls.