Patents by Inventor Seiichiro Ima
Seiichiro Ima has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 6667375Abstract: An ethylene-&agr;-olefin copolymer obtained by a gas phase polymerization method in the presence of a catalyst, wherein the copolymer satisfies the following conditions (A-1) to (A-4): (A-1) Melt flow rate (MFR): 0.3 to 5.0 g/10 minutes (A-2) Melt flow rate ratio (MFRR): 20 or more (A-3) Density (d): 0.910 to 0.930 g/cm3 (A-4) Coldxylene-soluble portion (CXS)(wt %) is in the range defined by the formula (1): 1.5×10−4×d−125×MFR0.5+0.3≧CXS formula (1).Type: GrantFiled: August 29, 2000Date of Patent: December 23, 2003Assignee: Sumitomo Chemical Company, LimitedInventors: Tadahiro Mitsuno, Seiichiro Ima, Hiroyuki Shiraishi
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Patent number: 6451936Abstract: A polypropylene random copolymer obtained by copolymerizing propylene and an &agr;-olefin or propylene, ethylene, and &agr;-olefin using a Ziegler-Natta catalyst substantially in the absence of solvent, wherein propylene content is from 92.3 to 75.0% by weight, the ethylene content (E) is from 0 to 2.7% by weight, and the &agr;-olefin content is from 5.0 to 25.0% by weight, and wherein the content (C) of 20° C. xylene-soluble components in the random copolymer satisfies following formulae (1) to (3); in the copolymer wherein the ethylene content (E) is less than 1.5% by weight, C≦12.0 (weight %) (1) in the copolymer wherein the ethylene content (E) is from 1.5% by weight to 1.8% by weight, C≦42.0−20.0×E (weight %) (2) and in the copolymer wherein the ethylene content (E) is from 1.8% by weight to 2.7% by weight, C≦6.0 (weight %) (3).Type: GrantFiled: June 5, 1995Date of Patent: September 17, 2002Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Sadatoshi, Seiichiro Ima, Kazuki Wakamatsu, Jiro Mori, Eisuke Shiratani
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Patent number: 6057413Abstract: A propylene-ethylene random copolymer prepared by copolymerizing propylene with ethylene in the substantial absence of a liquid medium with a catalyst system comprising:(A) a solid catalyst component containing magnesium, titanium, a halogen and a first electron donor as an essential component,(B) an organoaluminum compound and(C) a second electron donor compound, wherein an ethylene content (E) of the copolymer is from 3.5 to 7.0% by weight, and wherein a content of a xylene-soluble portion at 20.degree. C. (D) of the copolymer satisfies the relationship D.ltoreq.E+2.0 (% by weight). Films of the copolymer have an excellent appearance (little bleed whitening) and an excellent balance between low-temperature heat-sealing property and rigidity.Type: GrantFiled: September 3, 1996Date of Patent: May 2, 2000Assignee: Sumitomo Chemical Company, LimitedInventors: Seiichiro Ima, Kazuki Wakamatsu, Shigeki Kishiro
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Patent number: 5726269Abstract: A film having a low dependency of film transparency on film-forming conditions and film thickness, and having superior transparency and rigidity without compromising the original properties of polypropylene film. The film is produced from a polypropylene prepared from a propylene polymer having (1) a stereoirregularity index mmrr/mmmm of a part insoluble in xylene at 20.degree. C. within the range of 0.0095 to 0.0200; (2) a melting temperature within the range of 145.degree. to 160.degree. C.; (3) a part soluble in xylene at 20.degree. C. of 3.5% by weight or less, the polypropylene having: (4) a melt flow rate at 230.degree. C. within the range of 5 to 15 g/10 min.; and (5) a swelling ratio within the range of 1.20 to 1.35.Type: GrantFiled: January 26, 1996Date of Patent: March 10, 1998Assignee: Sumitomo Chemical Company, Ltd.Inventors: Seiichiro Ima, Eisuke Shiratani, Shigeki Kishiro
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Patent number: 5654372Abstract: A polypropylene composition comprising a melt-kneaded polyprolylene composition obtained, using Zieglar-Natta catalyst, by polymerizing a monomer comprising propylene to form a polymer comprising polypropylene (component A) in amount of from 60 to 80% by weight to the total polymer amount in substantially the absence of an inert solvent in a 1st step and then polymerizing a mixture of ethylene content of from 20 to 50% by weight (component B) in a vapor phase to form an ethylene-propylene copolymer (component B) in amount of from 20 to 40% by weight to the total polymer amount in a 2nd step, said polypropylene composition being such that the intrinsic viscosity of component B ([.eta.]B) is at least 2.0 dl/g and the ratio ([.eta.]B/[.eta.]A) of the intrinsic viscosity of the component B to the intrinsic viscosity of the component A ([.eta.]A) is 1.8 or less and the melt flow rate of the polypropylene composition after melt-kneaded being 0.5 to 10 g/10 minutes.Type: GrantFiled: March 8, 1996Date of Patent: August 5, 1997Assignee: Sumitomo Chemical Company LimitedInventors: Hajime Sadatoshi, Seiichiro Ima, Kazuki Wakamatsu, Jiro Mori, Eisuke Shiratani
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Patent number: 5641828Abstract: A polypropylene composition comprising 100 parts by weight of a crystalline propylene polymer having a molecular weight distribution (Mw/Mn) of less than 5.0 and from 0.0001 to 1.0 part by weight of a crystal nucleating agent, the composition having a crystallization temperature at least 1.5.degree. C. higher than the crystallization temperature of the crystalline propylene polymer.Type: GrantFiled: September 15, 1995Date of Patent: June 24, 1997Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Sadatoshi, Seiichiro Ima, Hiroyuki Tanimura
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Patent number: 5340878Abstract: A polypropylene composition comprising 100 parts by weight of a crystalline propylene polymer having a melt flow rate of at least 3.0 g/10 minutes and a molecular weight distribution of less than 5.0 and from 0.01 to less than 4.0 parts by weight of a crystalline ethylene polymer having a melt flow rate of from 0.5 to 300 g/10 minutes, a density of at least 0.910 g/cm.sup.3, and a crystallization temperature of at least 85.degree. C. and which is at least 1.degree. C. higher than the crystallization temperature of the crystalline propylene polymer.Type: GrantFiled: June 22, 1993Date of Patent: August 23, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Sadatoshi, Seiichiro Ima, Eisuke Shiratani
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Patent number: 5115027Abstract: The polypropylene stretched film of the present invention is prepared by stretching a composition comprising a crystalline propylene polymer and 0.1 ppm by weight to 10% by weight of a nucleating agent, the composition having a melting point of 160.degree. C. or more, a crystallization temperature of 128.degree. C. or more and a 20.degree. C. xylene soluble portion of 3.0% by weight or less. The film has a high rigidity and a beautiful appearance as well as the characteristic properties inherent to crystalline propylene polymers. The film can be suitably used for food packaging and textile packaging.Type: GrantFiled: June 5, 1991Date of Patent: May 19, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Tadatoshi Ogawa, Seiichiro Ima, Kazuki Wakamatsu
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Patent number: 5032645Abstract: The polypropylene stretched film of the present invention is prepared by stretching a composition comprising a crystalline propylene polymer and 0.1 ppm by weight to 10% by weight of a nucleating agent, the composition having a melting point of 160.degree. C. or more, a crystallization temperature of 128.degree. C. or more and a 20.degree. C. xylene soluble portion of 3.0% by weight or less. The film has a high rigidity and a beautiful appearance as well as the characteristic properties inherent to crystalline propylene polymers. The film can be suitably used for food packaging and textile packaging.Type: GrantFiled: November 8, 1989Date of Patent: July 16, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Tadatoshi Ogawa, Seiichiro Ima, Kazuki Wakamatsu
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Patent number: 5019442Abstract: The overlay film of the invention is obtained by forming a substrate layer composed of a resin composition comprising an ethylene copolymer such as ethylene-methacrylic acid ester copolymer and the like and a crystalline polyolefin having a melting point of 110.degree. C. or higher on at least one side of the base layer composed of a crystalline polyolefin and the like by any method such as co-extrusion-laminating and the like followed by cooling. The overlay film is excellent in physical properties such as the anti-blocking property and the like and gives a metal-deposited film with brilliant appearance exhibiting high adhesive strength to the metal layer by vapor-deposition treatment. The metal-deposited film is serviceable for extensive uses including wrapping materials.Type: GrantFiled: July 25, 1989Date of Patent: May 28, 1991Assignee: Sumitomo Chemical Company, LimitedInventors: Tadatoshi Ogawa, Seiichiro Ima
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Patent number: 4927872Abstract: A monolayer polypropylene film obtained by melt extrusion from a composition comprising 100 parts by weight of a crystalline polypropylene and, incorporated therein, a slipping agent {A} having a melting point of 100.degree. to 125.degree. C. and a slipping agent {B} having a melting point of 70.degree. to 90.degree. C. in a total amount of 0.05 to 1.0 part by weight, the initial coefficient of friction of said film being 0.7 or below and the coefficient of friction after heating at 60.degree. C. being 1.0 or below; and a multilayer film composed of said polypropylene film layer having said composition and said characteristics and a substrate material layer.Type: GrantFiled: April 3, 1989Date of Patent: May 22, 1990Assignee: Sumitomo Chemical Company, LimitedInventors: Masahiro Kakugo, Seiichiro Ima
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Patent number: 4839234Abstract: A monolayer polypropylene film obtained by melt extrusion from a composition comprising 100 parts by weight of a crystalline polypropylene and, incorporated therein, a slipping agent [A] having a melting point of 100.degree. to 125.degree. C. and a slipping agent [B] having a melting point of 70.degree. to 90.degree. C. in a total amount of 0.05 to 1.0 part by weight, the initial coefficient of friction of said film being 0.7 or below and the coefficient of friction after heating at 60.degree. C. being 1.0 or below; and a multilayer film composed of said polypropylene film layer having said composition and said characteristics and a substrate material layer.Type: GrantFiled: May 4, 1987Date of Patent: June 13, 1989Assignee: Sumitomo Chemical Company, LimitedInventors: Masahiro Kakugo, Seiichiro Ima
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Patent number: 4786562Abstract: A polypropylene multi-layer film which comprises a crystalline polypropylene substrate layer having laminated to at least one side thereof a sheet of a resin composition comprising:(A) 10-90% by weight of a propylene random copolymer satisfying that(i) the comonomer content is 4-15% by weight,(ii) the Vicat softening point is 122.degree. C. or less, and(iii) the cold xylene-soluble portion content is 15% by weight or less,(B) 10-90% by weight of a copolymer of propylene and an .alpha.-olefin having four or more carbon atoms or a copolymer of propylene, an .alpha.-olefin having four or more carbon atoms and ethylene satisfying that:(i) the content of the .alpha.-olefin having four or more carbon atoms is 8-35 mole %,(ii) the ethylene content is 5 mole % or less,(iii) the cold xylene-soluble portion content is 15-70% by weight, and(iv) the .DELTA.haze is 5% or less, and(C) 0-15% by weight of a highly crystalline polypropylene having a melting point of 150.degree. C. or more.Type: GrantFiled: July 2, 1987Date of Patent: November 22, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Masahiro Kakugo, Tadatoshi Ogawa, Seiichiro Ima, Teruaki Yoshida
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Patent number: 4769284Abstract: A polypropylene multi-layer film which comprises a substrate layer formed of crystalline polypropylene and a composition laminated on at least one side of said substrate layer, said composition comprising 70 to 95% by weight of (A) a crystalline propylene-ethylene copolymer having an ethylene content of 1.5 to 6.0% by weight and/or a crystalline propylene-.alpha.-olefin copolymer having a propylene content of 80 to 98% by weight, a butene-1 content of 2 to 20% by weight, and an ethylene content of 0 to 5% by weight, and 5 to 30% by weight of (B) a crystalline propylene-butene-1 copolymer which is a copolymer obtained by decomposing a crystalline propylene-butene-1 copolymer having a butene-1 content of 25 to 45% by weight, an intrinsic viscosity of 2.5 dl/g or more as determined in tetralin at 135.degree. C., and a proportion of 35% by weight or more of a polymer component soluble in xylene at 20.degree. C., and containing 1.Type: GrantFiled: April 23, 1986Date of Patent: September 6, 1988Assignee: Sumitomo Chemical Company, LimitedInventors: Masahiro Kakugo, Seiichiro Ima, Tatsuya Miyatake, Hiroyuki Harada
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Patent number: 4603174Abstract: A stretched polypropylene film having excellent see-through characteristics, which is prepared by stretching in at least one direction a polypropylene resin sheet containing 0.05 ppm to 10,000 ppm by weight of a 3-position branched .alpha.-olefin unit and/or a vinyl cycloalkane unit, each having at least 6 carbon atoms.Type: GrantFiled: December 27, 1984Date of Patent: July 29, 1986Assignee: Sumitomo Chemical Company, LimitedInventors: Tadayuki Okada, Masahiro Kakugo, Yoshiharu Fukui, Kizuku Wakatsuki, Seiichiro Ima, Junichi Kimura
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Patent number: 4584239Abstract: A stretched multilayer polypropylene film is described, comprising a stretched crystalline polypropylene layer and a layer of a composition (Composition B) laminated on at least one side of said polypropylene layer, wherein the composition B comprises a homo- or copolymer composed mainly of ethylene, propylene or butene-1 and having a melting point of 150.degree. C. or less, and a vinylcycloalkane polymer in an amount of 0.05 wt ppm to 10 wt % calculated as a vinylcycloalkane unit. This multilayer film is greatly improved in optical properties such as excellent see-through properties without deteriorating its good heat sealability. Thus it is very useful for wrapping.Type: GrantFiled: July 11, 1985Date of Patent: April 22, 1986Assignee: Sumitomo Chemical Company, LimitedInventors: Masahiro Kakugo, Yoshiharu Fukui, Kizuku Wakatsuki, Seiichiro Ima, Junichi Kimura
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Patent number: 4433110Abstract: A propylene block copolymer produced by polymerizing propylene, ethylene and an .alpha.-olefin having 4 to 8 carbon atoms in two stages with a Zieglar-Natta catalyst by a process which comprises (A) supplying propylene and ethylene in the first stage and propylene and the .alpha.-olefin in the second stage, or (B) supplying propylene and the .alpha.-olefin in the first stage and propylene and ethylene in the second stage, to the polymerization system, wherein the amounts of propylene and ethylene supplied in the first stage of (A) or in the second stage of (B) are 90 to 99 wt % and 10 to 1 wt % based on the total amount of propylene and ethylene supplied in the first stage of (A) or in the second stage of (B), respectively, the amounts of propylene and the .alpha.-olefin supplied in the second stage of (A) or in the first stage of (B) are 60 to 98 wt % and 40 to 2 wt % based on the total amount of propylene and the .alpha.Type: GrantFiled: April 17, 1981Date of Patent: February 21, 1984Assignee: Sumitomo Chemical Company, LimitedInventors: Kazuo Baba, Shyozo Kawamata, Yoshiharu Fukui, Seiichiro Ima, Tatsuya Miyatake
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Patent number: 4414373Abstract: In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 --O--R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.Type: GrantFiled: July 16, 1982Date of Patent: November 8, 1983Assignee: Sumitomo Chemical Co., Ltd.Inventors: Akinobu Shiga, Kiyoshi Matsuyama, Masahiro Kakugo, Yukio Naito, Seiichiro Ima, Katsuyoshi Yamashita
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Patent number: 4355144Abstract: In a process for producing polypropylene comprising polymerizing propylene in the presence of hydrogen and a catalyst system comprising (A) titanium trichloride obtained by reducing titanium tetrachloride with an organoaluminum compound and reacting the reduced solid with an ether represented by the formula:R.sup.1 -O-R.sup.2wherein R.sup.1 and R.sup.2 are defined hereinbefore, and a halogen compound selected from the group consisting of (i) halogen or interhalogen compounds of the formula, X.sup.1 X.sup.2.sub.a (wherein X.sup.1, X.sup.2 and a are defined hereinbefore), (ii) titanium halides, and (iii) organic halogen compounds, simultaneously or successively and (B) an organoaluminum compound, the improvement which comprises supplying ethylene together with propylene to the polymerization system such that the ethylene concentration in the vapor phase of the system based on the total amount of propylene, ethylene and hydrogen in the vapor phase of the system is 0.15 to 1.Type: GrantFiled: April 24, 1981Date of Patent: October 19, 1982Assignee: Sumitomo Chemical Company LimitedInventors: Akinobu Shiga, Kiyoshi Matsuyama, Masahiro Kakugo, Yukio Naito, Seiichiro Ima, Katsuyoshi Yamashita
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Patent number: RE32542Abstract: A molded product of polypropylene having an isotactic pentad fraction of the boiling heptane insoluble portion of at least about 0.955 and a boiling heptane solubles content of about 2.0 to 9.0% by weight. The molded products include a stretched film, insulating materials for electrical equipment, etc.Type: GrantFiled: November 5, 1986Date of Patent: November 10, 1987Assignee: Sumitomo Chemical Company, LimitedInventors: Akinobu Shiga, Kiyoshi Matsuyama, Masahiro Kakugo, Yukio Naito, Seiichiro Ima