Abstract: The present disclosure concerns lithium zirconium phosphate (LZP) chemical oxides for coated cathode active materials, which are useful in cathodes (i.e., positive electrodes) of rechargeable lithium-batteries for reversibly storing lithium ions (Li+).

Abstract: The present disclosure concerns lithium zirconium phosphate (LZP) chemical oxides for coated cathode active materials, which are useful in cathodes (i.e., positive electrodes) of rechargeable lithium-batteries for reversibly storing lithium ions (Li+).

Abstract: An all-solid-state secondary battery including: a positive electrode active material layer including a positive electrode active material and a sacrificial positive electrode material having an oxidation-reduction potential which is less than a discharge voltage of the positive electrode active material; and a negative electrode active material layer including a negative electrode active material including an element alloyable with lithium or that forms a compound with lithium; and a solid electrolyte layer between the positive electrode active material layer and the negative electrode active material layer, wherein the sacrificial positive electrode material includes a sacrificial active material and a conductive agent.

Abstract: A composite cathode active material including: a core particle; a first coating layer; and a second coating layer; wherein the core particle includes a cathode active material, the first and second coating layers cover a surface of the core particle, the first coating layer includes a first lithium-containing compound, wherein the first lithium-containing compound includes zirconium, niobium, titanium, aluminum, or a combination thereof, the second coating layer includes a second lithium-containing compound, wherein the second lithium-containing compound includes germanium, niobium, gallium, or a combination thereof, and the first lithium-containing compound is different from the second lithium-containing compound.

Abstract: An anode for an all solid-state secondary battery, the anode including an anode collector, and coating lithium distribution layer disposed on the anode collector, wherein the lithium distribution layer includes a metal capable of forming an alloy with lithium.

Abstract: An anode for an all solid-state secondary battery, the anode including an anode collector, and coating lithium distribution layer disposed on the anode collector, wherein the lithium distribution layer includes a metal capable of forming an alloy with lithium.

Abstract: A method of preparing a sulfide solid electrolyte, the method including: first contacting a starting materials including Li2S, P2S5, and LiI in a first solvent to provide a precursor; and second contacting the precursor with a second solvent to prepare the sulfide solid electrolyte, wherein the first solvent includes a C1-C3 alkyl group or a cyclic ether compound which is unsubstituted or substituted with a C1-C3 alkoxy group, and the second solvent includes a C1-C10 hydrocarbon substituted with a C1 to C6 alkoxy group.

Abstract: A lithium secondary battery including: a positive electrode, a negative electrode, and a sulfide solid electrolyte disposed between the positive electrode and the negative electrode, wherein the positive electrode includes a positive active material particle and a coating film including an oxide including lithium (Li) and zirconium (Zr) on a surface of the positive active material particle.

Abstract: An all-solid-state secondary battery including: a positive electrode layer; a negative electrode layer; and a solid electrolyte layer between the positive electrode layer and the negative electrode layer, wherein the positive electrode layer includes a sulfur-containing positive electrode active material, a halogen-containing sulfide solid electrolyte, and a conductive carbon material, and wherein the sulfur-containing positive electrode active material includes elemental sulfur and a transition metal disulfide.

Abstract: An all-solid secondary battery includes: a cathode layer including a cathode active material; an anode layer; and a solid electrolyte layer disposed between the cathode layer and the anode layer, wherein at least one of the cathode layer, the anode layer, or the solid electrolyte layer includes a phase-transition solid electrolyte material, wherein upon heating, the phase-transition solid electrolyte material undergoes a phase transition from a first phase to a second phase, and the second phase has an ionic conductivity less than the ionic conductivity of the first phase.

Abstract: A method of preparing a sulfide solid electrolyte, the method including: first contacting a starting materials including Li2S, P2S5, and LiI in a first solvent to provide a precursor; and second contacting the precursor with a second solvent to prepare the sulfide solid electrolyte, wherein the first solvent includes a C1-C3 alkyl group or a cyclic ether compound which is unsubstituted or substituted with a C1-C3 alkoxy group, and the second solvent includes a C1-C10 hydrocarbon substituted with a C1 to C6 alkoxy group.

Abstract: An all-solid-state secondary battery including: a positive electrode active material layer including a positive electrode active material and a sacrificial positive electrode material having an oxidation-reduction potential which is less than a discharge voltage of the positive electrode active material; and a negative electrode active material layer including a negative electrode active material including an element alloyable with lithium or that forms a compound with lithium; and a solid electrolyte layer between the positive electrode active material layer and the negative electrode active material layer, wherein the sacrificial positive electrode material includes a sacrificial active material and a conductive agent.

Abstract: A positive electrode for a lithium ion secondary battery, the positive electrode including a positive electrode particle including a positive active material particle, wherein the positive electrode particle comprises a first coating layer on a surface of the positive active material particle wherein the first coating layer includes a carbonaceous material, and a second coating layer on the first coating layer, wherein the second coating layer includes a lithium-containing compound, and a sulfide solid electrolyte contacting the positive electrode particle.

Abstract: An all-solid-state secondary battery including: a positive electrode layer; a negative electrode layer; and a solid electrolyte layer between the positive electrode layer and the negative electrode layer, wherein the positive electrode layer includes a sulfur-containing positive electrode active material, a halogen-containing sulfide solid electrolyte, and a conductive carbon material, and wherein the sulfur-containing positive electrode active material includes elemental sulfur and a transition metal disulfide.

Abstract: A lithium secondary battery including: a positive electrode, a negative electrode, and a sulfide solid electrolyte disposed between the positive electrode and the negative electrode, wherein the positive electrode includes a positive active material particle and a coating film including an oxide including lithium (Li) and zirconium (Zr) on a surface of the positive active material particle.

Abstract: A lithium ion secondary battery including: a cathode including a plurality cathode active material particles; an electrolyte; and an anode, wherein a cathode active material particle of the plurality of cathode active material particles has a plate-shaped crystal structure having an aspect ratio of 2 to 1000, wherein a major surface in at least one direction of the plate-shaped crystal structure is a 111 face, wherein the cathode active material particle also has a spinel-type crystal structure, and wherein the cathode active material particle has a composition represented by the formula LiCo2-xNixO4, wherein 0<x<2.

Abstract: An electrolyte for a secondary battery, the electrolyte including: an organic solvent; and a lithium ion conductive solid electrolyte represented by the formula LiaPbSc wherein 3<a<5, 1<b<3, and 6<c<8, and wherein at least a portion of the solid electrolyte is dissolved in the organic solvent.

Abstract: A lithium secondary battery including: a positive electrode, a negative electrode, and a sulfide solid electrolyte disposed between the positive electrode and the negative electrode, wherein the positive electrode includes a positive active material particle and a coating film including an oxide including lithium (Li) and zirconium (Zr) on a surface of the positive active material particle.

Abstract: An anode for an all solid-state secondary battery, the anode including an anode collector, and coating lithium distribution layer disposed on the anode collector, wherein the lithium distribution layer includes a metal capable of forming an alloy with lithium.

Abstract: A lithium ion secondary battery includes: a positive electrode; a negative electrode wherein least one of the positive electrode and the negative electrode includes an electrode active material composite including an electrode active material particle, and a needle-shaped crystal of a first sulfide solid electrolyte in contact with the electrode active material particle, wherein the needle-shaped crystal has an aspect ratio of greater than 2; and a second sulfide solid electrolyte between the positive electrode and the negative electrode and in contact with the electrode active material composite.