Abstract: A method for treating arsenic-containing flue gas is disclosed. In the method, the arsenic-containing flue gas is subjected to a dry pre-dedusting treatment, and the dedusted flue gas is pre-cooled and then introduced into a vortex quenching system. The arsenic-containing flue gas is divided into high-temperature flue gas and low-temperature flue gas through the vortex quenching system. The outlet temperature of the low-temperature flue gas is dropped below the desublimation temperature of gaseous arsenic trioxide. The low-temperature flue gas is subjected to a gas-solid separation to obtain solid arsenic trioxide and treated flue gas.

Abstract: The present disclosure provides a method for wet removal of sulfur dioxide by silicate bacteria-enhanced pulp. The method includes: treatment of ore waste residue, activation and domestication of silicate bacteria, preparation of pulp, removal of sulfur dioxide, and resource utilization of a desulfurization product. The present disclosure combines flue gas desulfurization with resource utilization of the ore waste residue, and improves a desulfurization efficiency of the method by the pulp and a utilization rate of ore waste residue resources through silicate bacteria. The present disclosure has a high desulfurization efficiency, simple production process, and low cost, and realizes the recycling of resources such as the ore waste residue, the sulfur dioxide, and silicon. The present disclosure has obvious economic and environmental benefits and broad prospects for use.

Abstract: A gas-solid separating method and a gas-solid separating system for simple substance sulphur in sulphur-containing exhaust are provided. The gas-solid separating method for simple substance sulphur in sulphur-containing exhaust comprises the following steps: first, cooling sulphur-containing exhaust at an extremely high speed; then, separating dust; finally, recycling a heavy liquid phase solvent and simple substance sulphur. The system comprises a quick cooling system, a low-temperature washing and purifying system, a light liquid phase and heavy liquid phase separating system, a washing liquid recycling system and a simple substance sulphur recycling system.

Abstract: A method for treating arsenic-containing flue gas is disclosed. In the method, the arsenic-containing flue gas is subjected to a dry pre-dedusting treatment, and the dedusted flue gas is pre-cooled and then introduced into a vortex quenching system. The arsenic-containing flue gas is divided into high-temperature flue gas and low-temperature flue gas through the vortex quenching system. The outlet temperature of the low-temperature flue gas is dropped below the desublimation temperature of gaseous arsenic trioxide. The low-temperature flue gas is subjected to a gas-solid separation to obtain solid arsenic trioxide and treated flue gas.

Abstract: The present invention discloses a method for ammonium-enhanced flue gas desulfurization (FGD) by using red mud slurry. The method specifically includes: crushing red mud, sieving the crushed red mud, slurrying the red mud, conducting aeration treatment, adding an ammonium salt and/or ammonia, and conducting natural sedimentation to obtain pretreated red mud slurry and pretreated red mud liquor; adding an ammonium salt and/or ammonia to the slurry, adding water and conducting uniform mixing, conducting pre-FGD, conducting deep desulfurization on treated flue gas by using the pretreated red mud liquor, and directly discharging desulfurized flue gas; and charging the pretreated red mud slurry and the pretreated red mud liquor obtained after the treatment to a replacement tank below, adding lime milk to the replacement tank, conducting stirring and natural sedimentation, conducting soilization on subnatant thick red mud slurry, and refluxing the supernatant to a red mud aeration tank.

Abstract: Disclosed is a method for degrading antibiotics by aqueous phase transfer catalysis using an anionic liquid and hydrogen peroxide, including: adding hydrogen peroxide to a wastewater containing the antibiotics to obtain a first mixture, and adjusting a pH of the first mixture to 3-4 to form an aqueous phase, and adding a catalyst to a water-insoluble ionic liquid to obtain a second mixture, and stirring the second mixture to form an ionic liquid phase, wherein the catalyst is selected from the group consisting of ferrocene, iron dodecyl sulfonate, ferrous dodecyl sulfonate, and copper dodecyl sulfonate; and mixing the aqueous phase and the ionic liquid phase in a volume ratio of (8-11):1 to obtain a mixed phase, and stirring the mixed phase to degrade the antibiotics.

Abstract: The present invention discloses a method for aluminum-enhanced dealkalization of red mud and separation and recovery of aluminum and iron. The method includes: dissolving red mud in water, introducing excessive SO2, introducing O2 for aeration, and refluxing part of alkaline leachate after filtering; when pH of a red mud mixture decreases to below 3, washing and filtering the red mud mixture, adding NaOH to acidic leachate to adjust its pH to a strongly alkaline level, aging and filtering the leachate, treating filter residue to recover Fe2O3, and refluxing part of alkaline leachate after filtering to the red mud mixture; and adjusting pH of the remaining alkaline leachate after filtering to a weakly acidic level, and conducting filtering to recover aluminum.

Abstract: A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.

Abstract: A method for production of ammonium phosphate from phosphate rock slurry. The method includes: introducing flue gas containing SO2 into a phosphate rock slurry, to yield an absorption solution; evaporating waste ammonia water containing 10-20 wt. % ammonia to yield ammonia gas; introducing the ammonia gas into the absorption solution at a temperature of 110-135° C. until a neutralization degree of the absorption solution reaches 1.5-1.6, thus yielding an ammonium phosphate solution and calcium sulfate; separating the calcium sulfate from the ammonium phosphate solution; and introducing the ammonium phosphate solution to a granulator for granulation to yield ammonium phosphate granules; drying and sieving the ammonium phosphate granules, thereby yielding ammonium phosphate.

Abstract: The present invention discloses a method and system for thermal desorption treatment of organic-contaminated soil and treatment of desorbed waste gas. The system includes a thermal incinerator, a desorption flue gas temperature regulating device, a thermal desorption reactor, a dust collector, a heat exchange/steam separator, an absorption reactor, a star-shaped unloader, and a soil cooler. An absorbent containing organic pollutants is used as a fuel, and subjected to thermal incineration to achieve the decomposition and harmless treatment of the organic pollutants; and high temperature flue gas generated by the incineration is used as a heat carrier for thermal desorption remediation of the organic-contaminated soil; and by means of the high solubility capability of fuel oil to organic matter, the fuel oil is used as an absorbent to absorb and purify the organic pollutants in desorbed waste gas, so that the gas is purified gas and up-to-standard discharge is achieved.

Abstract: The invention discloses a method for simultaneously removing SO2 and NOx in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60° C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NOx into ammonium nitrate, and the removal efficiency of the NOx and the SO2 is high.

Abstract: The present invention discloses a gas-solid separating method and a gas-solid separating system for simple substance sulphur in sulphur-containing exhaust. The gas-solid separating method for simple substance sulphur in sulphur-containing exhaust comprises the following steps: first, cooling sulphur-containing exhaust at an extremely high speed; then, separating dust; finally, recycling a heavy liquid phase solvent and simple substance sulphur; according to the method disclosed by the present invention, the separating efficiency of the simple substance sulphur is up to 90 percent or above; moreover, the exhaust is further purified, and an environment pollution accident is avoided; in a separating process of the simple substance sulphur, the heavy liquid phase solvent of the simple substance sulphur evaporates to form a gas phase solvent which can be recycled as the liquid phase solvent for reusing through cooling, so that the sulphur removing cost is reduced.

Abstract: The present invention discloses a method for ammonium-enhanced flue gas desulfurization (FGD) by using red mud slurry. The method specifically includes: crushing red mud, sieving the crushed red mud, slurrying the red mud, conducting aeration treatment, adding an ammonium salt and/or ammonia, and conducting natural sedimentation to obtain pretreated red mud slurry and pretreated red mud liquor; adding an ammonium salt and/or ammonia to the slurry, adding water and conducting uniform mixing, conducting pre-FGD, conducting deep desulfurization on treated flue gas by using the pretreated red mud liquor, and directly discharging desulfurized flue gas; and charging the pretreated red mud slurry and the pretreated red mud liquor obtained after the treatment to a replacement tank below, adding lime milk to the replacement tank, conducting stirring and natural sedimentation, conducting soilization on subnatant thick red mud slurry, and refluxing the supernatant to a red mud aeration tank.

Abstract: The present invention discloses a method for aluminum-enhanced dealkalization of red mud and separation and recovery of aluminum and iron. The method includes: dissolving red mud in water, introducing excessive SO2, introducing O2 for aeration, and refluxing part of alkaline leachate after filtering; when pH of a red mud mixture decreases to below 3, washing and filtering the red mud mixture, adding NaOH to acidic leachate to adjust its pH to a strongly alkaline level, aging and filtering the leachate, treating filter residue to recover Fe2O3, and refluxing part of alkaline leachate after filtering to the red mud mixture; and adjusting pH of the remaining alkaline leachate after filtering to a weakly acidic level, and conducting filtering to recover aluminum.

Abstract: The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4.?, so that NOx and SO2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.

Abstract: The invention discloses a method for simultaneously removing SO2 and NOx in flue gas: uniformly mixing a water-soluble ruthenium salt with ammonia water to obtain an aqueous solution of a ruthenium-amine complex; subjecting the flue gas and the aqueous solution of the ruthenium-amine complex to a countercurrent contact reaction under the temperature of 5-60° C., pH of 7.5-12 to obtain a solution A and purified gas; discharging the solution A of the step (2) into a crystallization tank to crystallize and separate an ammonium salt to obtain a solution B, returning the solution B to replace the aqueous solution of the ruthenium-amine complex. The invention utilizes the ruthenium-amine complex having a strong capability of complexing with NO as well as residual oxygen in the flue gas to carry out liquid phase catalytic oxidation to convert the NOx into ammonium nitrate, the removal efficiency of the NOx and the SO2 is high.

Abstract: The present disclosure relates to a method for thermal desorption treatment of organic-contaminated soil. The method includes: subjecting thermal desorption flue gas with a temperature of 120-700° C. and the organic-contaminated soil to a countercurrent contact reaction for 5-30 min to obtain desorption waste gas comprising an organic pollutant and thermally desorbed soil; drying biomass to a water content of ?12%, and crushing to a length of ?20 cm to obtain a biomass segment; uniformly mixing the thermally desorbed soil with the biomass segment to obtain a mixture A, carrying out low-temperature pyrolytic carbonization of the biomass in the mixture A at a temperature of 250-450° C., heating the soil to obtain remedied soil including organic carbon and pyrolysis gas from the low-temperature pyrolytic carbonization. The disclosure mixes the thermally desorbed soil with the biomass for pyrolytic carbonization, greatly improving the content of an organic matter, recovering a soil function.

Abstract: The invention is a device and method for purifying sulfur dioxide and nitrogen oxide in flue gas with an electrolysis-chemical advanced oxidation enhanced ammonia method. The device includes a thermal activation reactor, ammonium hydroxide storage tank, absorption tower, electrolytic bath and crystallization separator. The method takes raw material part of an ammonium sulfate solution that is a reaction product of ammonia and sulfur oxide in flue gas, and an ammonium persulfate solution prepared by electrolysis of an electrolytic bath as an oxidant to enhance the efficiency of purifying sulfur dioxide and nitrogen oxide in the flue gas with an ammonia method. A thermal activation reactor activates an ammonium persulfate containing solution to generate a strong oxidizing SO4??, so that NOx and SO2 in the flue gas may be more efficiently converted into a product having higher solubleness for enhanced removal of sulfur dioxide and nitrogen oxide in the flue gas.

Abstract: The present invention discloses a method and system for thermal desorption treatment of organic-contaminated soil and treatment of desorbed waste gas. The system includes a thermal incinerator, a desorption flue gas temperature regulating device, a thermal desorption reactor, a dust collector, a heat exchange/steam separator, an absorption reactor, a star-shaped unloader, and a soil cooler. An absorbent containing organic pollutants is used as a fuel, and subjected to thermal incineration to achieve the decomposition and harmless treatment of the organic pollutants; and high temperature flue gas generated by the incineration is used as a heat carrier for thermal desorption remediation of the organic-contaminated soil; and by means of the high solubility capability of fuel oil to organic matter, the fuel oil is used as an absorbent to absorb and purify the organic pollutants in desorbed waste gas, so that the gas is purified gas and up-to-standard discharge is achieved.

Abstract: Disclosed is a process for purifying tail gases from an ore-smelting electrical furnace by catalytic oxidization, which comprises: impregnating a catalyst carrier in an impregnating solution, then aging, calcinating, and finally drying, so as to prepare a catalyst of high efficiency; then washing the tail gases from an ore-smelting electrical furnace with an aqueous alkali-containing solution, pre-heating the alkali-washed tail gas; and adjusting the oxygen volume content in the tail gases, charging the tail gases at a certain speed, purifying the gases by a catalytic oxidization fixed bed containing the catalyst of high efficiency, cooling the purified gas, so as to obtain the feed gases for C1 chemistry.