Abstract: Disclosed is a luminescent polymer applicable to various electroluminescence devices, and more specifically, a novel poly(p-phenylvinylene) derivative with cyclohexyl or phenyl substituted silyl group on the side chain thereof, represented by the following formula 1. The luminescent polymer is excellent in thermal properties and luminance efficiency, and radiates at a green light wavelength range due to electronic properties of the silyl substituent, thus serving as an electroluminescence device material. wherein R is a cyclohexyl or phenyl substituted silyl group; and m is an integer of 1-4.