Abstract: The invention relates to a composite material with lubricating properties consisting of a solid polymeric matrix such as polystyrene or polymethyl methacrylate containing between 20 and 85% by weight of a liquid oil with lubricating properties, such as a silicone oil.The material according to the invention is obtained by polymerization of an emulsion of the said oil in a monomer such as styrene or methyl methacrylate monomer in the presence of a surface-active agent which is a two- or three-block block copolymer in which one repeat unit is compatible with the said monomer.The materials according to the invention are used to form antierosive components for ammunition intended for barrel weapon systems and in particular wads (8) for shells (1).

Abstract: The invention relates to a composite material with lubricating properties consisting of a solid polymeric matrix such as polystyrene or polymethyl methacrylate containing between 20 and 85% by weight of a liquid oil with lubricating properties, such as a silicone oil.The material according to the invention is obtained by polymerization of an emulsion of the said oil in a monomer such as styrene or methyl methacrylate monomer in the presence of a surface-active agent which is a two- or three-block block copolymer in which one repeat unit is compatible with the said monomer.The materials according to the invention are used to form antierosive components for ammunition intended for barrel weapon systems and in particular wads (8) for shells (1).

Abstract: The invention relates to a process for the preparation of conductive polymers or prepolymers and to conductive polymers or prepolymers.The process of the invention consists of reacting a polymer containing ethylenic unsaturations such as a hydroxytelechelic polybutadiene with a silane compound of formula ##STR1## in which R.sub.1 denotes a hydrocarbon group containing at least one heteroatom bearing mobile electrons, such as the oxygen of an ether group, andR.sub.2 and R.sub.3 denote a substituted or unsubstituted organic residue or a group R.sub.1.The polymer obtained is precipitated by the addition of a compound which is not a solvent for the polymer, and is separated from the reaction medium.The polymers obtained have an electrical conductivity which is multiplied by a factor of 10.sup.5 relative to the unmodified polymer.The present invention applies in particular in the field of the polymer industry.

Abstract: The invention relates to processes for the synthesis of tertiary phosphine oxides and sulfides.The process according to the invention consists, in a first step, of reacting a secondary phosphine oxide or sulfide with an optionally activated alkali metal amide, and, in a second step, of reacting the mixture obtained in the first step with an organic halide containing at least one halogenophenyl radical or one halogenomethyl group.Tertiary phosphine oxides and sulfides are complexing agents of high stability.

Abstract: The invention relates to new associations of strong bases, having the following general formula:n' RLi--n MZin which: n and n' are the numbers of mols of each compound, R is an alkyl or aryl radical, M is an alkali metal chosen from amongst lithium, sodium or potassium and Z is a hydride or an inorganic amide, the ratio n/n' being between 0.2 and 50.It is preferred to use bases in which the metal of the alkali metal amide or hydride is potassium or sodium. These associations are formed very rapidly and can be applied to anionic polymerization, in particular of conjugated dienes, in a solvent of low polarity or an apolar solvent.The polymers thus obtained contain a high percentage of 1,2 or 3,4 structures.

Abstract: The invention relates to processes for the synthesis of tertiary phosphine oxides and sulphides. The process according to the invention consists, in a first step, of reacting a secondary phosphine oxide or sulfide with an optionally activated alkali metal amide, and, in a second step, of reacting the mixture obtained in the first step with an organic halide containing at least one halogenophenyl radical or one halogenomethyl group. Tertiary phosphine oxides and sulphides are complexing agents of high stability.

Abstract: The invention relates to new associations of strong bases, having the following general formula:n'RLi--n MZin which: n and n' are the numbers of mols of each compound, R is an alkyl or aryl radical, M is an alkali metal chosen from amongst lithium, sodium or potassium and Z is a hydride or an inorganic amide, the ratio n/n' being between 0.2 and 50.It is preferred to use bases in which the metal of the alkali metal amide or hydride is potassium or sodium. These associations are formed very rapidly and can be applied to anionic polymerisation, in particular of conjugated dienes, in a solvent of low polarity or an apolar solvent.The polymers thus obtained contain a high percentage of 1,2 or 3,4 structures.