Abstract: A method for improving effectiveness of a steam generator system includes providing a steam generator system including a steam generator vessel, an air supply system and an air preheater. The air supply system is in communication with the steam generator vessel through the air preheater and the steam generator vessel is in communication with the air preheater. The air supply system provides a first amount of air to the air preheater. At least a portion of the first amount of air is provided to the steam generator vessel. A flue gas mixture is discharged from the steam generator vessel. At least a portion of the flue gas mixture flows into the air preheater. SO3 in the flue gas mixture is mitigated before the flue gas mixture enters the air preheater.