Abstract: The present invention relates to positive electrode active material powder including overlithiated manganese-based oxide particles, which are represented by the disclosed Formula 1 and are in the form of a single particle composed of one nodule or a pseudo-single particle that is a composite of 2 to 30 or less nodules, and a positive electrode and a lithium secondary battery which include the positive electrode active material powder.

Abstract: A method of manufacturing a lithium secondary battery includes (1) mixing a transition metal precursor and a lithium source material and then sintering the mixture to prepare a lithium composite transition metal oxide, (2) mixing the lithium composite transition metal oxide with a cobalt-containing raw material and heat-treating the mixture at 550° C. to 700° C. to form a cobalt coating layer on the oxide, (3) mixing the lithium composite transition metal oxide on which the cobalt coating layer is formed with a boron-containing raw material and heat-treating the mixture at 400° C. to 500° C. to prepare a positive electrode active material including a boron coating layer, (4) applying the positive electrode active material onto a positive electrode current collector to prepare a positive electrode, and (5) assembling the positive electrode, the negative electrode including a silicon-based negative electrode active material, and a separator, and injecting an electrolyte.

Abstract: A positive electrode and a lithium secondary including the same is disclosed herein. In some embodiments, the positive electrode includes a positive electrode current collector, a first positive electrode active material layer and a second positive electrode active material layer sequentially stacked on the positive electrode current collector, wherein the first positive electrode active material layer and the second positive electrode active material layer include a bimodal positive active material, the first positive electrode active material layer includes small-diameter particles in the form of single particles, and the second positive electrode active material layer includes small-diameter particles in the form of secondary particles. The positive electrode has improved capacity, efficiency, lifespan, output properties, and thermal stability.

Abstract: The present invention relates to an electrode of a double-layer structure including a different type of particulate active material having a different average particle diameter, and a secondary battery including the same, and according to the present invention, the mechanical strength and stability of the electrode increases, and the secondary battery to which they are applied exhibits excellent discharge capacity.

Abstract: A method of preparing a positive electrode active material for a secondary battery includes preparing a lithium composite transition metal oxide which includes nickel, cobalt, and manganese and contains 60 mol % or more of the nickel among all metals except lithium, adding a moisture absorbent and the lithium composite transition metal oxide into an atomic layer deposition (ALD) reactor, and adding a coating metal precursor into the atomic layer deposition (ALD) reactor and forming a metal oxide coating layer on surfaces of particles of the lithium composite transition metal oxide by atomic layer deposition (ALD).

Abstract: A positive electrode for a lithium secondary battery includes a positive electrode collector, a first positive electrode active material layer formed on the positive electrode collector and includes a first positive electrode active material, and a second positive electrode active material layer formed on the first positive electrode active material layer and includes a second positive electrode active material. The first positive electrode active material and the second positive electrode active material include a lithium nickel-cobalt-based oxide in which an amount of nickel among total metallic components excluding lithium is 80 atm % or more, the first positive electrode active material has a molar ratio of nickel to cobalt of 18 or more, and the second positive electrode active material has a molar ratio of nickel to cobalt of less than 18.

Abstract: A positive electrode active material for a lithium secondary battery comprising lithium transition metal oxide particles having a core-shell structure which includes a core portion and a shell portion disposed on a surface of the core portion. Wherein, the average crystallite size of the core portion is smaller than an average crystallite size of the shell portion and an amount of nickel among total transition metals included in the core portion and the shell portion is 80 atm % or more. A positive electrode active material, which suppresses decomposition of an electrolyte solution and occurrence of micro cracks of the positive electrode active material during charge and discharge by forming an average crystallite size of a core portion of the high-nickel positive electrode active material smaller than an average crystallite size of a shell portion, and a method of preparing the same.

Abstract: A bimodal positive electrode active material includes a first lithium transition metal oxide and a second lithium transition metal oxide having an average particle diameter (D50) smaller than that of the first lithium transition metal oxide, wherein the first lithium transition metal oxide has higher particle strength and smaller crystalline size than the second lithium transition metal oxide, and a positive electrode and a lithium secondary battery which include the positive electrode active material. A positive electrode active material may improve high-temperature life characteristics and high-temperature storage characteristics of a lithium secondary battery. A positive electrode and a lithium secondary battery which include the positive electrode active material are also provided.

Abstract: A positive electrode for a lithium secondary battery includes a positive electrode active material layer including: a first positive electrode active material represented by Formula 1 and having a crystalline size of 150 nm or more; a conductive agent including single-walled carbon nanotubes (SWCNTs); and a binder. A lithium secondary battery includes the positive electrode.

Abstract: A method of preparing a lithium secondary battery includes: (1) mixing a small particle lithium composite transition metal oxide having an average particle diameter (D50) of less than 7 ?m with a boron-containing raw material and performing a heat treatment, mixing a large particle lithium composite transition metal oxide having an average particle diameter (D50) of 8 ?m or more with a cobalt-containing raw material and a boron-containing raw material and performing a heat treatment, mixing the first positive electrode active material and the second positive electrode active material to prepare a positive electrode material having a bimodal particle diameter distribution, preparing a positive electrode by coating the positive electrode material on a positive electrode collector, and assembling the positive electrode, a negative electrode including a silicon-based negative electrode active material, and a separator.

Abstract: A positive electrode and a lithium secondary including the same is disclosed herein. In some embodiments, the positive electrode includes a positive electrode current collector, a first positive electrode active material layer and a second positive electrode active material layer sequentially stacked on the positive electrode current collector, wherein the first positive electrode active material layer and the second positive electrode active material layer include a bimodal positive active material, the first positive electrode active material layer includes small-diameter particles in the form of single particles, and the second positive electrode active material layer includes small-diameter particles in the form of secondary particles. The positive electrode has improved capacity, efficiency, lifespan, output properties, and thermal stability.

Abstract: The present disclosure relates to a positive electrode including a positive electrode active material layer formed on a positive electrode collector, wherein the positive electrode active material layer has a two-layer structure including a first positive electrode active material layer, which is formed on the positive electrode collector and includes a first positive electrode active material represented by Formula 1 and a second positive electrode active material represented by Formula 2, and a second positive electrode active material layer which is formed on the first positive electrode active material layer and includes a third positive electrode active material represented by Formula 1, wherein an average particle diameter D50 of the third positive electrode active material is the same or different from an average particle diameter D50 of the first positive electrode active material, and a lithium secondary battery including the same.

Abstract: A method of preparing a positive electrode active material for a secondary battery includes preparing a lithium composite transition metal oxide which includes nickel, cobalt, and manganese and contains 60 mol % or more of the nickel among all metals except lithium, adding a moisture absorbent and the lithium composite transition metal oxide into an atomic layer deposition (ALD) reactor, and adding a coating metal precursor into the atomic layer deposition (ALD) reactor and forming a metal oxide coating layer on surfaces of particles of the lithium composite transition metal oxide by atomic layer deposition (ALD).

Abstract: The present invention relates to an electrode of a double-layer structure including a different type of particulate active material having a different average particle diameter, and a secondary battery including the same, and according to the present invention, the mechanical strength and stability of the electrode increases, and the secondary battery to which they are applied exhibits excellent discharge capacity.